Annealing effect of sulfonated polysulfone ionomer membranes on proton conductivity and methanol transport

Journal of Membrane Science

Volumn 247, Issue 1-2, 2005, Pages 103-110

  Park, Ho Bum ^a   Shin, Hyun Soo ^b   Lee, Young Moo ^a   Rhim, Ji Won ^b  

^a Hanyang University   (South Korea)

^b Hannam University   (South Korea)

Author keywords

Annealing; Ionomer membrane; Methanol permeability; Proton conductivity; Sulfonated polysulfone

Indexed keywords

IONOMER MEMBRANES; METHANOL PERMEABILITY; PROTON CONDUCTIVITY;

ANNEALING; GLASS TRANSITION; HEAT TREATMENT; INORGANIC ACIDS; ION EXCHANGE; ION EXCHANGE MEMBRANES; IONOMERS; MECHANICAL PERMEABILITY; METHANOL; PROTONS; SULFONATION;

POLYMERIC MEMBRANES;

CHLOROTRIMETHYLSILANE; METHANOL; POLYSULFONE;

ANNEALING; ION EXCHANGE; MEMBRANE TECHNOLOGY; METHANOL; PERMEABILITY; POLYSULFONE;

ARTICLE; HEAT TREATMENT; ION EXCHANGE; PRIORITY JOURNAL; PROTON TRANSPORT; SULFONATION; THERMAL ANALYSIS; TRANSITION TEMPERATURE; WATER CONTENT; WATER TRANSPORT;

EID: 11044238017     PISSN: 03767388     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.memsci.2004.09.023     Document Type: Article

References (31)

1. 3 doped polyimide-diaminobenzenesulfonic acid copolymer J. Membr. Sci. 67 1993 165 169
2. D.R. Rosseinsky, and R.J. Mortimer Electrochromic systems and the prospects for devices Adv. Mater. 13 2001 783 793
3. M.-E. Avramescu, Z. Borneman, and M. Wessling Mixed-matrix membrane adsorbers for protein separation J. Chromatogr. A 1006 2003 171 183
4. C. Weidlich, K.-M. Mangold, and K. Jüttner Conducting polymers as ion-exchangers for water purification Electrochim. Acta 47 2001 741 745
5. M. Ertas, A. Cirpan, and L. Toppare Synthesis and characterization of conducting copolymers of succinic acid bis-(4-pyrrol-1-yl-phenyl) ester and their electrochromic properties Synth. Met. 143 2004 49 58
6. H.B. Park, and Y.M. Lee Polymer electrolyte membrane fuel cell J. Korean Ind. Eng. Chem. 13 2002 1 11
7. T. Norby The promise of protonics Nature 410 2001 877 878
8. K.D. Kreuer Proton conductivity: materials and applications Chem. Mater. 8 1996 610
9. A.J. Appleby Recent developments and application of the polymer fuel cell Philos. Trans. R. Soc. Lond. A 354 1996 1681
10. C. Genies, R. Mercier, B. Sillion, N. Cornet, G. Gebel, and M. Pineri Soluble sulfonated naphthalenic polyimides as materials for proton exchange membranes Polymer 42 2001 359 373
11. N. Cornet, O. Diat, G. Gebel, F. Jousse, D. Marsacq, R. Mercier, and M. Pineri Sulfonated polyimide membranes: a new type of ion-conducting membrane for electrochemical applications J. N. Mat. Electrochem. Syst. 3 2000 33 42
12. H. Kim, and M. Litt Synthesis and characterization of sulfonated polyimides for fuel cell applications Polym. Prepr. (Am. Chem. Soc. Div. Polym. Chem.) 42 2001 486 487
13. X. Guo, J. Fang, S. Harada, T. Watari, K. Tanaka, H. Kita, and K. Okamoto Novel sulfonated polyimides as polyeletrolytes for fuel cell application. 1. Synthesis, proton conductivity, and water stability of polyimides from 4,4′-diaminodiphenyl ether-2,2′-disulfonic acid Macromoleucles 35 2002 9022 9028
14. R. Wycisk, and P.N. Pintauro Sulfonated polyphosphazene ion-exchange membranes J. Membr. Sci. 119 1996 155 160
15. Q. Guo, P.N. Pintauro, H. Tang, and S. O'Connor Sulfonated and cross-linked polyphosphazenes-based proton-exchange membranes J. Membr. Sci. 154 1999 175 181
16. M. Gil, X. Ji, X. Li, H. Na, J.E. Hampsey, and Y. Lu Direct synthesis of sulfonated aromatic poly(ether ether ketone) proton exchange membranes for fuel cell applications J. Membr. Sci. 234 2004 75 81
17. E. Drioli, A. Regina, M. Casciola, A. Oliveti, F. Trotta, and T. Massari Sulfonated PEEK-WC membranes for possible fuel cell applications J. Membr. Sci. 228 2004 139 148
18. L. Li, J. Zhang, and Y. Wang Sulfonated poly(ether ether ketone) membranes for direct methanol fuel cell J. Membr. Sci. 226 2003 159 167
19. R. Nolte, K. Ledjeff, M. Bauer, and R. Mulhaupt Partially sulfonated (polyarylene ether sulfone) - versatile proton conducting membrane for modern E-conversion technology J. Membr. Sci. 83 1993 211 220
20. B. Lafitte, L.E. Karlsson, and P. Jannasch Sulfonation of polysulfones for proton-conducting fuel cell membranes Macromol. Rapid. Commun. 23 2002 896 900
21. P. Genova-Dimitrova, B. Baradie, D. Foscallo, C. Poinsignon, and J.Y. Sanchez Ionomeric membranes for proton exchange membrane fuel cell (PEMFC): sulfonated polysulfone associated with phosphatoantimonic acid J. Membr. Sci. 185 2001 59 71
22. F. Lufrano, G. Squadrito, A. Patti, and E. Passalacqua Sulfonated polysulfone as promising membrane for polymer electrolyte fuel cells J. Appl. Polym. Sci. 77 2000 1250 1257
23. ® via metalation-sulfination-oxidation J. Polym. Sci. A. Polym. Chem. 34 1996 2421 2438
24. J. Kerres, W. Zhang, and W. Cui New sulfonated engineering polymers via the metalation route. II. sulfonated/sulfonated poly(ether sulfone) PSU Udel and its crosslinking J. Polym. Sci. A Polym. Chem. 36 1998 1441 1448
25. F. Lufrano, I. Gatto, P. Staiti, V. Antonucci, and E. Passalacqua Sulfonated polysulfone ionomer membranes for fuel cells Solid State Ionics 145 2001 47 51
26. J. Kerres, A. Ullrich, F. Meier, and T. Häring Synthesis and characterization of novel acid-base polymer blends for application in membrane fuel cells Solid State Ionics 125 1999 243 249
27. J. Kerres, W. Cui, R. Disson, and W. Neubrand Development and characterization of crosslinked ionomer membranes based upon sulfonated and sulfonated PSU crosslinked PSU blend membranes by disproportionation of sulfinic acid groups J. Membr. Sci. 139 1998 211 225
28. A.F. Ismail, and W. Lorna Suppression of plasticization in polysulfone membranes for gas separations by heat-treatment technique Sep. Purif. Technol. 30 2003 37 46
29. H.S. Chao, D.R. Kelsey, Process for preparing sulfonated poly(arylether)resins, US patent number 4,625,000 (November 25, 1986).
30. A. Noshay, and L.M. Robeson Sulfonated polysulfone J. Appl. Polym. Sci. 20 1976 1885 1903
31. Casting solvent interactions with sulfonated poly(ether ether ketone) during proton exchange membrane fabrication, J. Membr. Sci. 219 (2003) 113-121.