Asymmetric nucleophilic glyoxylation through a metalated α-aminonitrile derivative in Michael additions to nitroalkenes

Angewandte Chemie - International Edition

Volumn 46, Issue 13, 2007, Pages 2314-2316

  Enders, Dieter ^a   Bonten, Maurice Hubert ^a   Raabe, Gerhard ^a  

^a RWTH AACHEN UNIVERSITY   (Germany)

Author keywords

Aminonitriles; Asymmetric synthesis; Keto esters; Michael addition; Umpolung

Indexed keywords

AMINO ACIDS; DERIVATIVES; ENANTIOMERS; KETONES; NUCLEOPHILES; REACTION KINETICS;

ASYMMETRIC; MICHAEL ADDITION; NITROALKENES; UMPOLUNG;

OLEFINS;

ALKENE; GLYOXYLIC ACID DERIVATIVE; NITRILE; NITRO DERIVATIVE; ORGANOMETALLIC COMPOUND;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; CONFORMATION;

ALKENES; GLYOXYLATES; MOLECULAR CONFORMATION; MOLECULAR STRUCTURE; NITRILES; NITRO COMPOUNDS; ORGANOMETALLIC COMPOUNDS;

EID: 34250374484     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200604802     Document Type: Article

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