Mercury-catalyzed rearrangement of ketoximes into amides and lactams in acetonitrile

Journal of Organic Chemistry

Volumn 72, Issue 12, 2007, Pages 4536-4538

  Ramalingan, Chennan ^a   Park, Yong Tae ^a  

^a Kyungpook National University   (South Korea)

Author keywords

[No Author keywords available]

Indexed keywords

KETOXIMES; LACTAMS; MERCURY-CATALYZED REARRANGEMENT;

AMIDES; CATALYSIS; MERCURY COMPOUNDS;

ACETONITRILE;

ACETONITRILE; AMIDE; KETOXIME DERIVATIVE; LACTAM DERIVATIVE; MERCURY CHLORIDE; OXIME DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; BECKMANN REARRANGEMENT; CATALYSIS; CATALYST; CHEMICAL STRUCTURE; TEMPERATURE SENSITIVITY;

EID: 34250175450     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo070297k     Document Type: Article

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23. All of the oxime substrates used in this investigation (entries 1-23 in Table 3) were quantitatively synthesized by refluxing a mixture of 1 equiv of the corresponding ketones, 2.3 equiv of hydroxylamine hydrochloride, and 2.5 equiv of sodium acetate trihydrate in aqueous methanol.