High-temperature phase relations and topological constraints in the quaternary system MgO-Al2O3-SiO2 -Cr2O3: An experimental study

American Mineralogist

Volumn 92, Issue 5-6, 2007, Pages 735-747

  Brigida, Cristiano ^a   Poli, Stefano ^a,b   Valle, Massimiliano ^b  

^a UNIVERSITY OF MILAN   (Italy)

^b Petroceramics Srl   (Italy)

Author keywords

Chromium; Glass; Liquidus phase diagram; Mullite; Sapphirine; Spinel

Indexed keywords

ALUMINA; ALUMINUM OXIDE; CHROMIUM; CORUNDUM; GLASS; MAGNESIA; MELTING; MIXTURES; MULLITE; OLIVINE; OXIDE MINERALS; SILICON; TEMPERATURE; TOPOLOGY;

CHEMICAL COMPOSITIONS; HIGH TEMPERATURE PHASE; LIQUIDUS; LOW-TEMPERATURE MELTING; PRIMARY CRYSTALLIZATION FIELDS; SAPPHIRINE; SPINEL; TOPOLOGICAL CONSTRAINTS;

SILICA;

ALUMINUM OXIDE; CHEMICAL COMPOSITION; CHROMIUM; EXPERIMENTAL MINERALOGY; GLASS; HIGH TEMPERATURE; MAGNESIUM; PHASE TRANSITION; PORCELLANITE; SAPPHIRINE; SPINEL;

EID: 34249870648     PISSN: 0003004X     EISSN: None     Source Type: Journal    
DOI: 10.2138/am.2007.2327     Document Type: Article

References (45)

1. 2. Journal of the American Ceramic Society, 58, 507-512.
2. Aksay, I.A., Dabbs, D.M., and Sarikaya, M. (1991) Mullite for structural, electronic and optical applications. Journal of the American Ceramic Society, 74, 2343-2358.
3. 2. Journal of the American Ceramic Society, 42, 644-645.
4. 2. Journal of the American Ceramic Society, 45, 229-242
5. Berry, A.J. and O'Neill, H.S.C. (2004) A XANES determination of the oxidation state of chromium in silicate glasses. American Mineralogist 89, 790-798.
6. Bishop, F.C. and Newton, R.C. (1975) The composition of low-pressure synthetic sapphirine. Journal of Geology 83, 511-517.
7. 2. Journal of the American Ceramic Society, 7, 238-254.
8. 3 system: I. Composition and molar volumes of minerals. European Journal of Mineralogy, 11, 599-617
9. 3, and their relevance on chromium inertization in ceramic systems. Key Engineering Materials, 206-2: 859-862
10. Cox, K.G., Bell, J.D., and Pankhurst, R.J. (1979) The interpretation of igneous rocks, 445 p. Allen & Unwin, London.
11. 2. Journal of the American Ceramic Society, 55, 525-531.
12. 3 systems. Journal of Phase Equilibria, 17, 488-494.
13. Dick, H.J.B. and Bullen, T. (1984) Chromium spinel as a petrogenetic indicator in abyssal and alpine-type peridotites and spatially associated lavas. Contributions to Mineralogy and Petrology, 86, 54-76.
14. 3 system. Geologiya i Geofizika, 38, 523-545.
15. 2. Journal of Geology 58, 135-151.
16. 3 revisited: reanalysis of Doroshev et al.'s (1997) experiments and new experiments. European Journal of Mineralogy, 15, 953-964.
17. 3 Journal of the American Ceramic Society, 51, 42-46.
18. Herd, R.K. (1973) Sapphirine and kornerupine occurrences within the Fiskenaesset complex. Rapport-Grønlands Geologiske Undersoegelse, 51, 65-71.
19. 2. Year Book, Carnegie Institute, Washington, 76, 465-472.
20. 2 systems. Journal of Phase Equilibria and Diffusion, 25, 329-345.
21. 3, system. Journal of the American Ceramic Society, 88, 1921-1928.
22. 2. Journal of the American Ceramic Society, 37, 490-496.
23. 4). Contributions to Mineralogy and Petrology, 130, 59-65.
24. Klemme, S. and O'Neill, H.S.C. (2000) The effect of Cr on the solubility of Al in orthopyroxene: experiments and thermodynamic modelling Contributions to Mineralogy and Petrology, 140, 84-98.
25. Langer, K., Platonov, A.N., Matsuk, S.S., and Andrut, M. (1994) Electronic absorption-spectra of chromium-bearing sapphirine. Physics and Chemistry of Minerals, 21 (1-2),29-35.
26. 2,-Cr-O in quilibrium with metallic Cr, and their significance for the petrochemistry of chromium. Journal of Petrology, 36, 107-132
27. 2 system. Journal of Materials Research, 20, 975-986.
28. Merlino, S. (1973) Polymorphism in sapphirine. Contributions to Mineralogy and Petrology, 41, 23-29.
29. Moore, P.B. (1968) Crystal structure of Sapphirine. Nature, 218, 81-82.
30. Moore, P.B. (1969) Crystal structure of Sapphirine. American Mineralogist, 54, 31-49.
31. 2)- Journal of the American Ceramic Society, 43, 267-273.
32. Osborn, E.F. and Muan, A. (1960) Phase equilibrium diagrams of oxide systems. Plate 3, published by the American Ceramic Society and Edward Orton Jr. Ceramic Foundation.
33. Papike, J.J., Karner, J.M., and Shearer, C.K. (2005) Comparative planetary mineralogy: Valence state partitioning of Cr, Fe, Ti, and V among crystallographic sites in olivine, pyroxene, and spinel from planetary basalts. American Mineralogist, 90, 277-290.
34. 2 system. Journal of the European Ceramics Society, 16, 101-108.
35. Rager, H., Schneider, H., and Graetsch, H. (1990) Chromium incorporation in mullite. American Mineralogist, 75, 392-397.
36. 2. The American Journal of Science, 45, 301-325
37. 2 Journal of the American Ceramic Society, 51, 585-594.
38. 2- Journal of Petrology 2, III, 324-406.
39. 2- Journal of the American Ceramic Society, 75, 1390-1398.
40. Sheng, Y.J., Hutcheon, I.D., and Wasserburg, G.J. (1991) Origin of plagioclase-olivine inclusions in carbonaceous chondrites. Geochimica et Cosmochimica Acta, 55, 581-599.
41. 2- Journal of Material Science, 11, 1459-1464.
42. 2 system: composition, polymorphism and thermal expansion. Science of Ceramics, 9, 256-263.
43. Villar, M.P., Geraldia, J.M., Molina, S.I., and Garcia, R. (2004) Microchemical analysis and microstructural development of Cr-doped mullites. Microchimica. Acta, 145, 255-260.
44. 2. Journal of the American Ceramic Society 37, 161-168.
45. 3+ in mullite transparent glass ceramics (II). Journal of Luminescence, 39, 189-203.