Baker's yeast mediated reduction of substituted acenaphthenequinones: Regio- and enantioselective preparation of mono-hydroxyacenaphthenones

Chinese Chemical Letters

Volumn 18, Issue 6, 2007, Pages 681-684

  Wang, Xing Yong ^a,b   Cui, Jing Nan ^a   Ren, Wei Min ^a   Li, Feng ^a   Lu, Chun Liang ^a   Qian, Xu Hong ^c  

^a DALIAN UNIVERSITY OF TECHNOLOGY   (China)

^b CHINA UNIVERSITY OF MINING AND TECHNOLOGY   (China)

^c EAST CHINA UNIVERSITY OF SCIENCE AND TECHNOLOGY   (China)

Author keywords

Baker's yeast; Chiral hydroxyacenaphthenone; Reduction; Regio and enantioselectivity

Indexed keywords

EID: 34249818156     PISSN: 10018417     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cclet.2007.04.022     Document Type: Article

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13. 4. After filtration and removal of organic solvent under reduced pressure, the crude mixture was purified by flash chromatography (silica gel, dichloromethane:methanol = 30:1, v/v) to afford the pure 2-hydroxyacenaphthenone or 6-substituted-2-hydroxyacenaphthenones.
14. 3) of the (R)-MTPA ester.