A general synthetic route for the preparation of high-spin molecules: Replacement of bridging hydroxo ligands in molecular clusters by end-on azido ligands

Polyhedron

Volumn 26, Issue 9-11, 2007, Pages 2089-2094

  Papaefstathiou, Giannis S ^a   Boudalis, Athanassios K ^b   Stamatatos, Theocharis C ^a   Milios, Constantinos J ^c   Efthymiou, Constantinos G ^a   Raptopoulou, Catherine P ^b   Terzis, Aris ^b   Psycharis, Vassilis ^b   Sanakis, Yiannis ^b   Vicente, Ramon ^d   Escuer, Albert ^d   Tuchagues, Jean Pierre ^e   Perlepes, Spyros P ^a  

^a UNIVERSITY OF PATRAS   (Greece)

^b INSTITUTE OF MATERIALS SCIENCE   (Greece)

^c UNIVERSITY OF EDINBURGH   (United Kingdom)

^d UNIVERSITY OF BARCELONA   (Spain)

^e LCC LABORATOIRE DE CHIMIE DE COORDINATION   (France)

Author keywords

Di 2 pyridyl ketone based ligands; End on azido ligands; Enneanuclear cobalt(II) and nickel(II) clusters; Ferromagnetic exchange interactions; High spin molecules; N cyanato bridged clusters

Indexed keywords

CARBOXYLATION; COBALT COMPOUNDS; FERROMAGNETIC MATERIALS; FERROMAGNETISM; GROUND STATE; KETONES; METAL COMPLEXES; MOLECULES; NICKEL COMPOUNDS;

AZIDO LIGAND; BRIDGED CLUSTERS; CYANATO; DI-2-PYRIDYL KETONE-BASED LIGANDS; END-ON AZIDO LIGAND; ENNEANUCLEAR COBALT(II) AND NICKEL(II) CLUSTER; FERROMAGNETIC EXCHANGE INTERACTION; HIGH-SPIN MOLECULES; N-CYANATO-BRIDGED CLUSTER; SYNTHETIC ROUTES;

LIGANDS;

EID: 34249695484     PISSN: 02775387     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.poly.2006.10.009     Document Type: Article

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