Living anionic polymerization of 2-vinyldibenzothiophene: Homopolymer and block copolymers with styrene

Journal of Polymer Science, Part A: Polymer Chemistry

Volumn 45, Issue 10, 2007, Pages 1993-2003

  Avila Ortega, A ^a   Vazquez Torres H ^a  

^a DEPARTAMENTO DE QUÍMICA   (Mexico)

Author keywords

2 Vinyldibenzothiophene; Anionic polymerization; Block copolymers; Monomer reactivity ratio; Styrene

Indexed keywords

BLOCK COPOLYMERS; COPOLYMERIZATION; HOMOPOLYMERIZATION; HYDRODYNAMICS; POLYSTYRENES; REACTION KINETICS;

HYDRODYNAMIC VOLUME; MONOMER REACTIVITY RATIO; NITROGEN ATMOSPHERE; VINYLDIBENZOTHIOPHENES (VDBT);

ANIONIC POLYMERIZATION;

EID: 34248994540     PISSN: 0887624X     EISSN: 10990518     Source Type: Journal    
DOI: 10.1002/pola.21965     Document Type: Article

References (37)

1. (a) Szwarc, M.; Levy, M.; Milkovich, R. J. Am Chem Soc 1956, 78, 2656-2657;
2. (b) Szwarc, M. Nature 1956, 178, 1168-1169.
3. (a) Szwarc, M. Carbanions, Living Polymers and Electron Transfer Processes; Interscience: New York, 1968;
4. (b) Morton, M. Anionic Polymerization: Principles and Practice; Academic Publishers: New York, 1983.
5. (a) Yade, T.; Nakano, T. J Polym Sci, Part A: Polym Chem 2006, 44, 561-572;
6. (b) Kobayashi, M.; Uchino, K.; Ishizone, T. J Polym Sci, Part A: Polym Chem 2005, 43, 4126-4135;
7. (c) Driva, P.; Iatrou, H.; Lohse, D. J.; Hadjichristidis, N. J Polym Sci, Part A: Polym Chem 2005, 43, 4070-4078.
8. (a) Williamson, D. T.; Kilian, L.; Long, T. E. J Polym Sci, Part A: Polym Chem 2005, 43, 1216-1227;
9. (b) Ito, M.; Ishizone, T. J Polym Sci, Part A: Polym Chem 2006, 44, 4832-4845;
10. (c) Quirk, R. P.; Kim, Y. J.; Guo, Y.; Wesdemiotis, C.; Arnould, M. A. J Polym Sci, Part A: Polym Chem 2006, 44, 2684-2693.
11. Hawker, C. J.; Wooley, K. L. Science 2005, 309, 1200-1204.
12. (a) Uhrig, D.; Mays, J. W. J Polym Sci, Part A: Polym Chem 2005, 43, 6179-6222;
13. (b) Hadjichristidis, N.; latrou, H.; Pispas, S.; Pitsikalis, M. J Polym Sci, Part A: Polym Chem 2000, 38, 3211-3234.
14. (a) Chawla, B.; Sanzo, F. D. J Chromatogr 1992, 589, 271-279;
15. (b) Nishioka, M. Energy Fuels 1988, 2, 214-219.
16. Clift, J.; Sides, J.; Shong, R.; Borole, A.; Kaufman, N. J Chem Technol Biotechnol 1999, 74, 1000-1004.
17. Yang, W.; Hou, Q.; Liu, C.; Niu, Y.; Huang, J.; Yang R.; Cao, Y. J Mater Chem 2003, 13, 1351-1355.
18. Gilman, H.; Esmay, D. L. J Am Chem Soc 1952, 74, 2021-2024.
19. (a) Bundt, J.; Herbei, W.; Steinhart, H. J. High Resolut Chromatogr 1992, 15, 682-685;
20. (b) Castro, B.; Whitcombe, M. J.; Vulfson, E. N.; Vazquez-Duhalt, R.; Bárzana, E. Anal Chim Acta 2001, 435, 83-90.
21. (a) Acheson, R. M.; Harrison, D. R. J Chem Soc C 1970, 1764-1784;
22. (b) Umemoto, T.; Ishihara, S. J Am Chem Soc 1993,115, 2156-2164.
23. Shimomura, O.; Sato, T.; Tomita, I.; Suzuki, M.; Takeshi, E. J Polym Sci, Part A: Polym Chem 1997, 35, 2813-2819.
24. Tamao, K.; Sumitani, K.; Kumada, M. J Am Chem Soc 1972, 94, 4374-4376;
25. (b) Kumada, M. Pure Appl Chem 1980, 52, 669-679.
26. Cullinane, N. M.; Davis, C. G.; Davies, G. I. J Chem Soc 1936, 1435-1437.
27. Gilman, H.; Bebb, R. J Am Chem Soc 1939, 61, 109-112.
28. Katritzky, A. R.; Perumal, S. J. Heterocyclic Chem 1990, 27, 1737-1740.
29. Hsieh, H. L.; Quirk, R. P. Anionic Polymerization: Principles and Practical Applications; Marcel Dekker: New York, 1996. Chapter 4, pp 76-89.
30. Note: Poly(2VDBT)/PS blends ranging from molar composition 70/30, 50/50, 30/70 were immiscible, as they showed two different Tg by temperature modulated DSC in experiments carried out in our laboratory.
31. Gitsov, I.; Fréchet, J. M. J. Macromolecules 1994, 27, 7309-7315.
32. Fox, T. G. Bull Am Phys Soc 1956, 2, 123-125.
33. (a) Tüdös, F.; Kélen, T.; Foldes-Berezsnich, T.; Turcsanyi, B. J Macromol Sci Chem A 1975, 9, 1-27;
34. (b) Yilmaz, E.; Küçükyavuz, Z. Polymer 1993, 34, 145-149;
35. (c) Wang, J. S.; Jérôme, R.; Bayard, Ph.; Baylac, L.; Patin, M.; Teyssié, Ph. Macromolecules 1994, 27, 4615-4620.
36. Joshi, R.; Joshi, S. J Macromol Sci Chem A 1971, 5, 1329-1338.
37. Odian, G. Principles of Polymerization, 2nd ed.; Wiley Interscience: New York, 1981. Chapter 6, 433 p.