Synthesis and radical polymerization of 2-vinyldibenzothiophene

Journal of Polymer Science, Part A: Polymer Chemistry

Volumn 35, Issue 14, 1997, Pages 2813-2819

  Shimomura, Osamu ^a   Sato, Toshihiko ^a   Tomita, Ikuyoshi ^b   Suzuki, Masato ^b   Endo, Takeshi ^b  

^a General Sekiyu KK   (Japan)

^b TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

2 vinyldibenzothiophene; Monomer reactivity ratio; Radical copolymerization; Radical polymerization; Styrene

Indexed keywords

AROMATIC COMPOUNDS; AROMATIC POLYMERS; CATALYSIS; COPOLYMERIZATION; GLASS TRANSITION; SYNTHESIS (CHEMICAL); THERMOANALYSIS;

CROSS-COUPLING REACTION; GRIGNARD REAGENT;

FREE RADICAL POLYMERIZATION;

EID: 0031246177     PISSN: 0887624X     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1099-0518(199710)35:14<2813::AID-POLA1>3.0.CO;2-R     Document Type: Article

References (15)

1. (a) B. Chawla and F. D. Sanzo, J. Chromatogr., 589, 271 (1992);
2. (b) M. Nishioka, Energy Fuels, 2, 214 (1988).
3. H. Gilman and D. L. Esmay, J. Am. Chem. Soc., 74, 2021 (1952).
4. J. Bundt, W. Herbel, and H. Steinhart, J. High Resolut. Chromatogr., 15, 682 (1992).
5. (a) R. M. Acheson and D. R. Harrison, J. Chem. Soc. (C), 1764 (1970);
6. (b) R. M. Acheson and J. K. Stubbs, J. Chem. Soc. Perkin I, 809 (1972);
7. (c) T. Umemoto and S. Ishihara, J. Am. Chem. Soc., 115, 2156 (1993).
8. (a) R. G. Flowers and L. W. Flowers, J. Am. Chem. Soc., 71, 3102 (1949);
9. (b) R. G. Flowers and L. W. Flowers, U.S. Pat. 2499186 (1950).
10. R. G. Flowers and L. W. Flowers, U.S. Pat. 2499187 (1950).
11. N. M. Cullinane, C. G. Davies, and G. I. Davies, J. Chem. Soc., 1435 (1936).
12. (a) K. Tamao, K. Sumitani, and M. Kumada, J. Am. Chem. Soc., 94, 4374 (1972);
13. (b) M. Kumada, K. Tamao, and K. Sumitani, Org. Syn., Coll., 6, 407 (1988).
14. The molecular weight distribution of the homopolymer 2 was rather broad, probably because the polymer partially precipitated from the reaction system during the polymerization.
15. H. Sato, Y. Tanaka, and K. Hatada, Makromol. Chem., Rapid Commun., 3, 181 (1982).