Application of the Anderko-Pitzer EoS to the calculation of thermodynamical properties of systems involved in the supercritical water oxidation process

Journal of Supercritical Fluids

Volumn 42, Issue 1, 2007, Pages 27-35

  Bermejo, M D ^a   Martin A ^a   Cocero, M J ^a  

^a UNIVERSITY OF VALLADOLID   (Spain)

Author keywords

Anderko Pitzer EoS; Equation of state; Simulation; Supercritical fluid; Supercritical water oxidation; VLE

Indexed keywords

CHEMICAL REACTORS; COMPUTER SIMULATION; CORRELATION METHODS; CORROSIVE EFFECTS; DEPOSITION; OXIDATION; SALTS; SPECIFIC HEAT OF LIQUIDS; SUPERCRITICAL FLUIDS; THERMODYNAMIC PROPERTIES;

EQUATION OF STATES; SALT DEPOSITION; SUPERCRITICAL WATER OXIDATION; TRANSPIRING WALL REACTOR (TWR);

WATER ANALYSIS;

EID: 34248637296     PISSN: 08968446     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.supflu.2007.01.011     Document Type: Article

References (34)

1. Bermejo M.D., Cocero M.J., and Fernández-Polanco F. A process for generating power from the oxidation of coal in supercritical water. Fuel 83 (2004) 195-204
2. Cocero M.J., Sanz T., Alonso E., and Fdez-Polanco F. Supercritical water oxidation process under energetically self-sufficient operation. J. Supercrit. Fluids 24 (2002) 37-46
3. Lavric E.D., Weyten H., De Ruyck J., Pleşu V., and Lavric V. Supercritical water oxidation improvements through chemical reactors energy integration. Appl. Thermal Eng. 26 (2006) 1385-1392
4. Lavric E.D., Weyten H., De Ruyck J., Pleşu V., and Lavric V. Delocalized organic pollutant destruction through a self-sustaining supercritical water oxidation process. Energy Convers. Manage. 46 (2005) 1345-1364
5. Bermejo M.D., Fernández-Polanco F., and Cocero M.J. Modeling of a transpiring wall reactor for the supercritical water oxidation using simple flow patterns: comparison to experimental results. Ind. Eng. Chem. Res. 44 (2005) 3835-3845
6. Ermakova A., and Anikeev V.I. Modeling of the oxidation of organic compounds in supercritical water. Theor. Foundation Chem. Eng. 38 (2004) 333-340
7. Chen P.S., Li L.X., and Earnest F. Simulation of a concentric tube reactor for supercritical water oxidation. ACS Symp. Ser. 608 (1995) 348-363
8. Dutournié P., and Mercadier J. Unsteady behavior of hydrothermal oxidation reactors: theoretical and numerical studies near the critical point. J. Supercrit. Fluids 35 (2005) 247-253
9. Muske K.R., Littell J.D., Dell'Orco P.C., Le L.A., and Flesner R.L. Hydrothermal treatment of C-N-O-H wastes: model-based reactor effluent control. Ind. Eng. Chem. Res. 40 (2001) 1397-1405
10. Vielcazals S., Mercadier J., Marias F., Mateos D., Bottreau M., Cansell F., and Marraud C. Modeling and simulation of hydrothermal oxidation of organic compounds. AIChE J. 52 (2006) 818-825
11. Oh C.H., Kochan R.J., Charlton T.R., and Bourhis A.L. Thermal-hydraulic modeling of supercritical water oxidation of phenol. Energy Fuels 10 (1996) 326-332
12. Zhou N., Krishnan A., Vogel F., and Peters W.A. A computational model for supercritical water oxidation of organic toxic wastes. Adv. Environ. Res. 4 (2000) 79-95
13. K. Lieball, Numerical investigations on a transpiring wall reactor for supercritical water oxidation, Doctoral Thesis no. 14′911 ETH Zurich, 2003.
14. Fauvel E., Joussot-Dubien C., Pomier E., Guichardon P., Charbit G., Charbit F., and Sarrade S. Modeling of a porous reactor for supercritical water oxidation by a residence time distribution study. Ind. Eng. Chem. Res. 42 (2003) 2122-2130
15. Cocero M.J., and Martínez J.L. Cool wall reactor for supercritical water oxidation: modelling and operation results. J. Supercrit. Fluids 31 (2004) 41-55
16. Magoulas C., and Tassios D. Thermophysical properties of n-alkanes from C1 to C20 and their prediction for higher ones. Fluid Phase Equilib. 56 (1990) 119-140
17. Bermejo M.D., Fdez-Polanco F., and Cocero M.J. Transpiring wall reactor for the supercritical water oxidation process: operational results, modeling and scaling. In: Perrut M. (Ed). Proceedings of the 10th European Meeting on Supercritical Fluids. Reactions, Materials and Natural Products Processing. Colmar, France, 12-14 December (2005)
18. 2O above 573 K. Geochim. Cosmochim. Acta 57 (1993) 1657-1680
19. 2O above 573 K: EoS representation. Geochim. Cosmochim. Acta 57 (1993) 4885-4897
20. 2 by an equation of state. AIChE J. 42 (1996) 585-594
21. 2 system: prediction of phase equilibria and volumetric properties. Geochim. Cosmochim. Acta 59 (1995) 2869-2882
22. 4: phase equilibria and volumetric properties above 573 K. Geochim. Cosmochim. Acta 67 (2003) 671-680
23. 2 systems K. Geochim. Cosmochim. Acta 70 (2006) 3765-3777
24. Kosinski J.J., and Anderko A. Equation of state for high-temperature aqueous electrolyte and nonelectrolyte systems. Fluid Phase Equlib. 183-184 (2001) 75-86
25. 2 solubility in water at high pressure. Fluid Phase Equilib. 238 (2005) 220-228
26. Bermejo M.D., Martín A., Florusse L.J., Peters C.J., and Cocero M.J. Bubble points of the systems isopropanol-water, isopropanol-water-sodium acetate and isopropanol-water-sodium oleate at high pressure. Fluid Phase Equilib. 244 (2006) 78-85
27. Bermejo M.D., Fdez-Polanco F., and Cocero M.J. Experimental study of the operational parameters of a transpiring wall reactor for supercritical water oxidation results. J. Supercrit. Fluids 39 (2006) 70-79
28. Bermejo M.D., Fdez-Polanco F., and Cocero M.J. Effect of the transpiring wall on the behavior of a supercritical water oxidation reactor: modeling and experimental results. Ind. Eng. Chem. Res. 45 (2006) 3438-3446
29. Schmidt R., and Wagner W. A new form of the equation of state for pure substances and its application to oxygen. Fluid Phase Equlib. 19 (1985) 175-200
30. Span R., Lemmon E., Jacobsen R.T., Wagner W., and Yokozeki A. A reference equation of state for the thermodynamic properties of nitrogen for temperatures from 63.151 to 1000 K and pressures to 2200 MPa. J. Phys. Chem. Ref. Data 29 (2000) 1361-1433
31. Japas M.L., and Franck E.U. High pressure phase equilibrium and PVT-data of the water-oxygen system including water-air to 673 K and 250 MPa. Berichte der Bunsen-Gesellschaft-Phys. Chem. Chem. Phys. 89 (1985) 1268-1275
32. Japas M.L., and Franck E.U. High pressure phase equilibrium and PVT-data of the water-nitrogen system to 673 K and 250 MPa. Berichte der Bunsen-Gesellschaft-Phys. Chem. Chem. Phys. 89 (1985) 793-800
33. Hill P.G. A unified fundamental EOS for the thermodynamic properties of water. J. Phys. Chem. Ref. Data 19 (1990) 1223-1274
34. Li L., Chen P., and Gloyna E.F. Generalized kinetic model for wet oxidation of organic compounds. AIChE J. 37 (1991) 1687-1693