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Volumn 72, Issue 10, 2007, Pages 3816-3822

Titanocene(II)-promoted stereoselective alkenylation utilizing (Z)-alkenyl sulfones

Author keywords

[No Author keywords available]

Indexed keywords

ALKENYL METHYL SULFONES; ALKENYLATION; ALKYNES; DIENES;

EID: 34248597171     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo070149u     Document Type: Article
Times cited : (14)

References (85)
  • 1
    • 20544450502 scopus 로고    scopus 로고
    • 2nd ed, de Meijere, A, Diederich F, Eds, Wiley-VCH: Weinheim
    • Metal-Catalyzed Cross-Coupling Reactions, 2nd ed.; de Meijere, A.; Diederich F., Eds.; Wiley-VCH: Weinheim, 2004.
    • (2004) Metal-Catalyzed Cross-Coupling Reactions
  • 27
    • 34248552036 scopus 로고    scopus 로고
    • For the preliminary results of alkenylation using (Z)-4-phenylbuten-1-yl phenyl sulfone, see ref 7
    • For the preliminary results of alkenylation using (Z)-4-phenylbuten-1-yl phenyl sulfone, see ref 7.
  • 37
    • 0242467768 scopus 로고    scopus 로고
    • For recent examples, see a
    • For recent examples, see (a) Ikeda, S. Angew. Chem., Int. Ed. 2003, 42, 5120.
    • (2003) Angew. Chem., Int. Ed , vol.42 , pp. 5120
    • Ikeda, S.1
  • 63
    • 0034802561 scopus 로고    scopus 로고
    • For the reactions via titanacycles, see: a
    • For the reactions via titanacycles, see: (a) Suzuki, D.; Urabe, H.; Sato, F. J. Am. Chem. Soc. 2001, 123, 7925.
    • (2001) J. Am. Chem. Soc , vol.123 , pp. 7925
    • Suzuki, D.1    Urabe, H.2    Sato, F.3
  • 68
    • 0034709381 scopus 로고    scopus 로고
    • For the reactions via zirconacycles, see: f
    • For the reactions via zirconacycles, see: (f) Takahashi, T.; Tsai, F.; Kotora, M. J. Am. Chem. Soc. 2000, 122, 4994.
    • (2000) J. Am. Chem. Soc , vol.122 , pp. 4994
    • Takahashi, T.1    Tsai, F.2    Kotora, M.3
  • 82
    • 34248510177 scopus 로고    scopus 로고
    • The reaction of 2d with 1 at 25°C for 2 h formed 12 in a lower yield (36%) and also formed a substantial amount (27%) of a stereoisomeric mixture of 1,1,8,8-tetraphenylocta-3,5-diene (15, Supporting Information), which would be produced by titanocene(II)-promoted self-coupling of 2d.
    • The reaction of 2d with 1 at 25°C for 2 h formed 12 in a lower yield (36%) and also formed a substantial amount (27%) of a stereoisomeric mixture of 1,1,8,8-tetraphenylocta-3,5-diene (15, Supporting Information), which would be produced by titanocene(II)-promoted self-coupling of 2d.
  • 84
    • 34248534635 scopus 로고    scopus 로고
    • The terminal olefin 12 was produced in a 10% yield by this reaction.
    • The terminal olefin 12 was produced in a 10% yield by this reaction.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.