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for theoretical comparison of Pd- and Ni-catalyzed Heck reactions, see: c) B.-L. Lin, L. Liu, Y. Fu, S.-W. Luo, Q. Chen, Q.-X. Guo, Organometallics 2004, 23, 2114.
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3, diisopropylethylamine, pyridine, 2,6-lutidine, 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU), N-methylpyrrolidine, and N-methylmorpholine were examined.
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The effects of phosphorous ligands upon reductive elimination from [N(NHC)alkyl] complexes to give alkyl imidazolium salts have been studied. In contrast, our observation that the NHC was not consumed suggests that one of the other ligands (for example, H or OTf) significantly affects the properties and behavior of the metal complex; see: a) D. S. McGuinness, N. Saendig, B. F. Yates, K. J. Cavell, J. Am. Chem. Soc. 2001, 123, 4029;
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The effects of phosphorous ligands upon reductive elimination from [N(NHC)alkyl] complexes to give alkyl imidazolium salts have been studied. In contrast, our observation that the NHC was not consumed suggests that one of the other ligands (for example, H or OTf) significantly affects the properties and behavior of the metal complex; see: a) D. S. McGuinness, N. Saendig, B. F. Yates, K. J. Cavell, J. Am. Chem. Soc. 2001, 123, 4029;
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