The use of SIMS and SEM for the characterization of individual particles with a matrix originating from a nuclear weapon

Microscopy and Microanalysis

Volumn 13, Issue 3, 2007, Pages 179-190

  Ranebo, Ylva ^a,b   Eriksson, Mats ^c   Tamborini, Gabriele ^a   Niagolova, Nedialka ^a   Bildstein, Olivier ^a   Betti, Maria ^a  

^a JOINT RESEARCH CENTRE   (Italy)

^b LUND UNIVERSITY   (Sweden)

^c MC 98000 ^*  (Monaco)

Author keywords

Environmental radioactive particles; Isotopic ratios; Plutonium; SEM; SIMS; Thule; Uranium; Weapons grade enrichment

Indexed keywords

EID: 34248576753     PISSN: 14319276     EISSN: 14358115     Source Type: Journal    
DOI: 10.1017/S1431927607070353     Document Type: Conference Paper

References (47)

1. AARKROG, A. (1971). Radioecological investigations of plutonium in an arctic marine environment. Health Phys 20, 31-47.
2. AARKROG, A., DAHLGAARD, H., HOLM, E., LIPPERT, J. & NILSSON, K. (1980). Environmental radioactivity in Greenland in 1979. RiSø-R-423, Risø National Laboratory, Roskilde, Denmark.
3. BERGER, M.J., COURSEY, J.S., ZUCKER, M.A. & CHANG, J. (2005a). ESTAR, PSTAR, and ASTAR: Computer programs for calculating stopping-power and range tables for electrons, protons, and helium ions (version 1.2.3). Gaithersburg, MD: National Institute of Standards and Technology. Available at: http://physics.nist.gov/STAR (accessed January 2007).
4. BERGER, M.J., HUBBELL, J.H., SELTZER, S.M., CHANG, J., COURSEY, J.S., SUKUMAR, R. & ZUCKER, D.S. (2005b). XCOM: Photon Cross Section Database (version 1.3). Gaithersburg, MD: National Institute of Standards and Technology. Available at: http://physics.nist.gov/xcom (accessed January 2007).
5. BETTI, M., TAMBORINI, G. & KOCH, L. (1999). Use of secondary ion mass spectrometry in nuclear forensic analysis for the characterization of plutonium and highly enriched uranium particles. Anal Chem 71, 2616-2622.
6. CIURAPINSKI, A., PARUS, J. & DONOHUE, D. (2002). Particle analysis for a strengthened safeguards system: Use of a scanning electron microscope equipped with EDXRF and WDXRF spectrometers. J Radioanal Nucl Chem 251, 345-352.
7. COAKLEY, K.J., SIMONS, D.S. & LEIFER, A.M. (2005). Secondary ion mass spectrometry measurements of isotopic ratios: Correction for time varying count rate. Int J Mass Spectrom 240, 107-120.
8. DANESI, P.R. (1998). Investigating fallout from nuclear testing-hot particles and the Cold War. IAEA Bulletin, 40/4/1998, 43-46.
9. DONOHUE, D.L. (2002). Strengthened nuclear safeguards. Anal Chem 74, 28A-35A.
10. ERDMANN, N., BETTI, M., STETZER, O., TAMBORINI, G., KRATZ, J.V., TRAUTMANN, N. & VAN GEEL, J. (2000). Production of monodisperse uranium oxide particles and their characterization by scanning electron microscopy and secondary ion mass spectrometry. Spectrochim Acta B 55, 1565-1575.
11. ERIKSSON, M. (2002). On weapons plutonium in the arctic environment (Thule, Greenland). Ph.D. thesis, Risø-R-1321, Risø National Laboratory, Roskilde, Denmark.
12. ERIKSSON, M., LJUNGGREN, K. & HINDORF, C. (2002). Plutonium hot particle separation techniques using real-time digital image systems. Nucl Instrum Methods Phys Res A 488, 375-380.
13. ERIKSSON, M., OSÁN, J., JERNSTRÖM, J., WEGRZYNEK, D., SIMON, R., CHINEA-CANO, E., MARKOWICZ, A., BAMFORD, S., TAMBORINI, G., TÖRÖK, S., FALKENBERG, G., ALSECZ, A., DAHLGAARD, H., WOBRAUSCHEK, P., STRELI, C., ZOEGER, N. & BETTI, M. (2005). Source term identification of environmental radioactive Pu/U particles by their characterization with non-destructive spectrochemical analytical techniques. Spectrochim Acta B 60, 455-469.
14. ERIKSSON, M., WEGRYZYNEK, D., SIMON, R. & CHINEA-CANO, E. (in prep.). Microprobe XRF and combined transmission and μ-XRF tomography on mixed U/Pu particles.
15. ESAKA, F., WATANABE, K., MAGARA, M. & USUDA, S. (2004). Application of secondary ion mass spectrometry to the measurement of lead isotope ratio in individual particles. Instrum Sci Technol 32, 103-114.
16. JERNSTRÖM, J., ERIKSSON, M., OSÁN, J., TAMBORINI, G., TÖRÖK, S., SIMON, R., FALKENBERG, G., ALSECZ, A. & BETTI, M. (2004). Non-destructive characterization of low radioactive particles from Irish Sea sediment by micro X-ray synchrotron radiation techniques: Micro X-ray fluorescence (μ-XRF) and micro X-ray absorption near edge spectroscopy (μ-XANES). J Anal At Spectrom 19, 1428-1433.
17. JERNSTRÖM, J., ERIKSSON, M., SIMON, R., TAMBORINI, G., BILDSTEIN, O., CARLOS MARQUEZ., R., KEHL, S.R., HAMILTON, T.F., RANEBO, Y. & BETTI, M. (2006). Characterization and source term assessments of radioactive particles from Marshall Islands using non-destructive analytical techniques. Spectrochim Acta B 61, 971-979.
18. JIMÉNEZ-RAMOS, M.C., GARCÍA- TENORIO, R., VIOQUE, L, MANJÓN, G. & GARCÍA-LEÓN, M. (2006). Presence of plutonium contamination in soils from Palomares (Spain). Environ Pollut 142, 487-492.
19. KASHPAROV, V.A. (2003). Hot particles at Chernobyl. Environ Sci Pollut Res 1, 21-30.
20. α/X-ray activity ratio. Health Phys 46, 1213-1219.
21. LEHTO, S. (2002). Development of a SIMS method for isotopic analysis of uranium containing particles. Report on Task FIN A 1318 of the Finnish Support Programme to IAEA Safeguards, STUK-YTO-TR 188.
22. LIND, O.C. (2006). Characterisation of radioactive particles in the environment using advanced techniques. Ph.D. thesis, 2006:6, Norwegian University of Life Sciences, Aas, Norway.
23. LIND, O.C., SALBU, B., JANSSENS, K., PROOST, K. & DAHLGAARD, H. (2005). Characterization of uranium and plutonium containing particles originating from the nuclear weapons accident in Thule, Greenland, 1968. J Environ Radioact 81, 21-32.
24. LJUNGGREN, K. (2003). Beta camera-Development and biomedical applications. Ph.D. thesis, LUJI-RADFYS-AVH-6/2003, Lund University, Sweden.
25. 239Pu global fallout ratio in local sediments following the nuclear accidents at Thule (Greenland) and Palomares (Spain). Sci Total Environ 202, 147-153.
26. MORGAN, A.E. & WERNER, H.W. (1977). Quantitative SIMS studies with a uranium matrix. Surf Sci 65, 687-699.
27. NEWBURY, D.E. & MYKLEBUST, R.L. (2005). Simulation of electron-excited X-ray spectra with NIST-DIH Desktop Spectrum Analyzer (DTSA). Surf Interface Anal 37, 1045-1053.
28. NIELSEN, S.P. & ROOS, P. (2006). Thule-2003-Investigations of radioactive contamination. Risø-R-1549, Risø National Laboratory, Roskilde, Denmark.
29. NITTLER, L.R. & ALEXANDER, C.M.O'D. (2003). Automated isotopic measurements of micron-sized dust: Application to meteoritic presolar silicon carbide. Geochim Cosmochim Acta 67, 4961-4980.
30. PENG, L.-M., CHEN, Q., LIANG, X.L., CAO, S., WANG, J.Y., KLEINDIEK, S. & TAI, S.W. (2004). Performing probe experiments in the SEM. Micron 35, 495-502.
31. PÖLLÄNEN, R., KETTERER, M.E., LEHTO, S., HOKKANEN, M., IKÄ-HEIMONEN, T.K., SIISKONEN, T., MORING, M., RUBIO MONTERO, M.P. & MARTÍN SÁNCHEZ, A. (2006). Multi-technique characterization of a nuclear bomb particle from the Palomares accident. J Environ Radioact 90, 15-28.
32. POTTER, P.E., RAY, I., TAMBORINI, G., THIELE, H., WALKER, C. & WISS, T. (2005). On the constitution of some Dounreay radioactive particles. In Proceedings of the Conference on Managing Historic Hot Particle Liabilities in the Marine Environment, Nairn, Scotland.
33. th Regional Workshop on Electron Probe Microanalysis Today, Karlsruhe, Germany.
34. SALDI;, B., LIND, O.C. & SKIPPERUD, L. (2004). Radionuclide spcciation and its relevance in environmental impact assessments. J Environ Radioact 74, 233-242.
35. SANDALLS, F.J., SEGAL, M.G. & VICTOROVA, N. (1993). Hot particles from Chernobyl: A review. J Environ Radioact 18, 5-22.
36. SHEVCHENKO, S.V. (2004). On the uncertainty in activity measurements for samples containing "hot particles". Appl Radiat Isot 61, 1303-1306.
37. SIMONS, D.S. (1986). Single particle standards for isotopic measurements of uranium by secondary ion mass spectrometry. J Trace Microprobe Tech 4, 185-195.
38. SIMONS, D.S. (1991). SIMS analysis of fused day microspheres containing plutonium. In Proceedings of the 8th International Conference on Secondary Ion Mass Spectrometry (SIMS VIII), Benninghoven, A., Janssen, K.T.F., Tumpner, J. & Werner, H.W. (Eds.), pp. 715-718. New York: Wiley.
39. STOFFEL(S), J.J., BRIANT, J.K. & SIMONS, D.S. (1994). A particulate isotopic standard of uranium and plutonium in an aluminosilicate matrix. J Am Soc Mass Spectrom 5, 852-858.
40. STÜRUP, S., DAHLGAARD, H. & NIELSEN, S.C., (1998). High resolution inductively coupled plasma mass spectrometry for the trace determination of plutonium isotopes and isotope ratios in environmental samples. J Anal At Spectrom 13, 1321-1326.
41. TAMBORINI, G., BETTI, M., FORCINA, V., HIERNAUT, T., GIOVANNONE, B. & KOCH, L. (1998). Application of secondary ion mass spectrometry to the identification of single particles of uranium and their isotopic measurement. Spectrochim Acta B 53, 1289-1302.
42. TRAXLMAYR, U., RIEDLING, K. & ZINNER, E. (1984). On the deadtime correction of ion counting systems during gated raster SIMS measurements. Int J Mass Spectrom Ion Proc 61, 261-276.
43. VEKEMANS, B., JANSSENS, K., VINCZE, L., ADAMS, F. & VAN ESPEN, P. (1994). Analysis of X-ray spectra by iterative least squares (AXIL): New developments. X-ray Spectrom 23, 278-285.
44. WALLENIUS, M., MAYER, K. & RAY, I. (2006). Nuclear forensic investigations: Two case studies. Forensic Sci Int 156, 55-62.
45. WALLENIUS, M., TAMBORINI, G. & KOCH, L. (2001). The "age" of plutonium particles. Radiochim Acta 89, 55-58.
46. WHITTALL,A.J., MCDONALD, P., JACKSON, D. & TOSSELL, P.J. (2000). Alpha-emitting "hot particles" in the vicinity of BNFL Sellafield, Cumbria. J Radiat Prot 20, 433-442.
47. ZHELTONOZHSKY, V., MUCK, K. & BONDARKOV, M. (2000). Classification of hot particles from the Chernobyl accident and nuclear weapons detonations by non-destructive methods. J Environ Radioact 57, 151-166.