메뉴 건너뛰기




Volumn 4, Issue 1, 2007, Pages 56-64

Preparation of highly stable ion exchange membranes by radiation-induced graft copolymerization of styrene and bis(vinyl phenyl)ethane into crosslinked polytetrafluoroethylene films

Author keywords

"Double" crosslinking structure; Bis(vinyl phenyl)ethane (BVPE); Chemical stability; Crosslinked polytetrafluoroethylene; Crosslinker; Proton exchange fuel cells (PEFCs); Proton exchange membrane (PEM); Radiation induced graft polymerization

Indexed keywords

CHEMICAL STABILITY; COPOLYMERIZATION; CROSSLINKING; ION EXCHANGE MEMBRANES; POLYTETRAFLUOROETHYLENES; SULFONATION;

EID: 34248557658     PISSN: 1550624X     EISSN: None     Source Type: Journal    
DOI: 10.1115/1.2393305     Document Type: Article
Times cited : (26)

References (41)
  • 2
    • 0030607287 scopus 로고    scopus 로고
    • Recent Advances in Perfluorinated Ionomer Membranes: Structure, Properties and Applications
    • Wirguin, C. H., 1996, "Recent Advances in Perfluorinated Ionomer Membranes: Structure, Properties and Applications," J. Membr. Sci., 120, pp. 1-33.
    • (1996) J. Membr. Sci , vol.120 , pp. 1-33
    • Wirguin, C.H.1
  • 3
    • 0037465492 scopus 로고    scopus 로고
    • Review and Analysis of PEM Fuel Cell Design and Manufacturing
    • Mehta, V., and Cooper, J. S., 2003, "Review and Analysis of PEM Fuel Cell Design and Manufacturing," J. Power Sources, 114, pp. 32-53.
    • (2003) J. Power Sources , vol.114 , pp. 32-53
    • Mehta, V.1    Cooper, J.S.2
  • 4
    • 0035871040 scopus 로고    scopus 로고
    • Development of Ionomer Membranes for Fuel Cells
    • Kerres, J. A., 2001, "Development of Ionomer Membranes for Fuel Cells," J. Membr. Sci., 185, pp. 3-27.
    • (2001) J. Membr. Sci , vol.185 , pp. 3-27
    • Kerres, J.A.1
  • 5
    • 0001999628 scopus 로고    scopus 로고
    • Emerging Membranes for Electrochemical Systems. I. Solid Polymer Electrolyte Membranes for Fuel Cell Systems
    • Savadogo, O., 1998, "Emerging Membranes for Electrochemical Systems. I. Solid Polymer Electrolyte Membranes for Fuel Cell Systems," J. New Mater. Electrochem. Syst., 1, pp. 47-66.
    • (1998) J. New Mater. Electrochem. Syst , vol.1 , pp. 47-66
    • Savadogo, O.1
  • 6
    • 21844464308 scopus 로고    scopus 로고
    • Solid Polymer Electrolyte Membranes for Fuel Cell Applications - A Review
    • Smitha, B., Sridhar, S., and Khan, A. A., 2005, "Solid Polymer Electrolyte Membranes for Fuel Cell Applications - A Review," J. Membr. Sci., 259, pp. 10-26.
    • (2005) J. Membr. Sci , vol.259 , pp. 10-26
    • Smitha, B.1    Sridhar, S.2    Khan, A.A.3
  • 7
    • 0347319402 scopus 로고    scopus 로고
    • Novel Sulfonated Poly(arylene ether): A Proton Conductive Polymer Electrolyte Designed for Fuel Cells
    • Miyatake, K., Chikashige, Y., and Watanabe, M., 2003, "Novel Sulfonated Poly(arylene ether): A Proton Conductive Polymer Electrolyte Designed for Fuel Cells," Macromolecules, 36, pp. 9691-9693.
    • (2003) Macromolecules , vol.36 , pp. 9691-9693
    • Miyatake, K.1    Chikashige, Y.2    Watanabe, M.3
  • 8
    • 11444262069 scopus 로고    scopus 로고
    • Organic/Inorganic Hybrid Membrane: Thermally Stable Cation-Exchange Membrane Prepared by the Sol-Gel Method
    • Nagarale, R. K., Gohil, G. S., Shahi, V. K., and Rangarajan, R., 2004, "Organic/Inorganic Hybrid Membrane: Thermally Stable Cation-Exchange Membrane Prepared by the Sol-Gel Method," Macromolecules, 37, pp. 10023-10030.
    • (2004) Macromolecules , vol.37 , pp. 10023-10030
    • Nagarale, R.K.1    Gohil, G.S.2    Shahi, V.K.3    Rangarajan, R.4
  • 9
    • 0034501420 scopus 로고    scopus 로고
    • Proton-Conducting Polymer Electrolyte Membranes Based on Hydrocarbon Polymers
    • Rikukawa, M., and Sanui, K., 2000, "Proton-Conducting Polymer Electrolyte Membranes Based on Hydrocarbon Polymers," Prog. Polym. Sci., 25, pp. 1463-1502.
    • (2000) Prog. Polym. Sci , vol.25 , pp. 1463-1502
    • Rikukawa, M.1    Sanui, K.2
  • 10
    • 19344378862 scopus 로고    scopus 로고
    • Functional Fluoropolymers for Fuel Cell Membranes
    • Souzy, R., and Ameduri, B., 2005, "Functional Fluoropolymers for Fuel Cell Membranes," Prog. Polym. Sci., 30, pp. 644-687.
    • (2005) Prog. Polym. Sci , vol.30 , pp. 644-687
    • Souzy, R.1    Ameduri, B.2
  • 12
    • 0034172188 scopus 로고    scopus 로고
    • Radiation-Induced Grafting of Styrene onto Poly(tetrafluoroehtylene) (PTFE) Films. I. Effect of Grafting Conditions and Properties of the Grafted Films
    • Nasef, M. M., Saidi, H., Dessouki, A. M., and El-Nesr, E. M., 2000, "Radiation-Induced Grafting of Styrene onto Poly(tetrafluoroehtylene) (PTFE) Films. I. Effect of Grafting Conditions and Properties of the Grafted Films," Polym. Int., 49, pp. 399-406.
    • (2000) Polym. Int , vol.49 , pp. 399-406
    • Nasef, M.M.1    Saidi, H.2    Dessouki, A.M.3    El-Nesr, E.M.4
  • 13
    • 0034351049 scopus 로고    scopus 로고
    • Radiation-Induced Grafting of Styrene Onto Poly(tetrafluoroehtylene) (PTFE) Films Part II. Properties of The Grafted and Sulfonated Membranes
    • Nasef, M. M., Saidi, H., Nor, H. M., and Foo, O. M., 2000, "Radiation-Induced Grafting of Styrene Onto Poly(tetrafluoroehtylene) (PTFE) Films Part II. Properties of The Grafted and Sulfonated Membranes," Polym. Int., 49, pp. 1572-1579.
    • (2000) Polym. Int , vol.49 , pp. 1572-1579
    • Nasef, M.M.1    Saidi, H.2    Nor, H.M.3    Foo, O.M.4
  • 14
    • 0027876037 scopus 로고
    • Proton-Exchange Membranes by Radiation Grafting of Styrene onto FEP Films. I. Thermal Characteristics of Copolymer Membranes
    • Gupta, B., and Scherer, G. G., 1993, "Proton-Exchange Membranes by Radiation Grafting of Styrene onto FEP Films. I. Thermal Characteristics of Copolymer Membranes," J. Appl. Polym. Sci., 50, pp. 2129-2134.
    • (1993) J. Appl. Polym. Sci , vol.50 , pp. 2129-2134
    • Gupta, B.1    Scherer, G.G.2
  • 15
    • 0028465236 scopus 로고
    • Cation Exchange Membranes by Pre-Irradiation Grafting of Styrene Into FEP Films. I. Influence of Synthesis Conditions
    • Gupta, B., Büchi, F. N., and Scherer, G. G., 1994, "Cation Exchange Membranes by Pre-Irradiation Grafting of Styrene Into FEP Films. I. Influence of Synthesis Conditions," J. Polym. Sci., Part A: Polym. Chem., 32, pp. 1931-1938.
    • (1994) J. Polym. Sci., Part A: Polym. Chem , vol.32 , pp. 1931-1938
    • Gupta, B.1    Büchi, F.N.2    Scherer, G.G.3
  • 16
    • 0029247055 scopus 로고
    • Study of Radiation-Grafted FEP-g-polystyrene Membranes as Polymer Electrolytes in Fuel Cells
    • Buchi, N., Gupta, B., Haas, O., and Scherer, G. G., 1995, "Study of Radiation-Grafted FEP-g-polystyrene Membranes as Polymer Electrolytes in Fuel Cells," Electrochim. Acta, 40, pp. 345-353.
    • (1995) Electrochim. Acta , vol.40 , pp. 345-353
    • Buchi, N.1    Gupta, B.2    Haas, O.3    Scherer, G.G.4
  • 17
    • 0001418453 scopus 로고    scopus 로고
    • Cation Exchange Membranes by Radiation-Induced Graft Copolymerization of Styrene Onto PFA Copolymer Films. I. Preparation and Characterization of the Graft Copolymer
    • Nasef, M. M., Saidi, H., Nor, H. M., Dahlan, K. Z. M., and Hashim, K., 1999, "Cation Exchange Membranes by Radiation-Induced Graft Copolymerization of Styrene Onto PFA Copolymer Films. I. Preparation and Characterization of the Graft Copolymer," J. Appl. Polym. Sci., 73, pp. 2095-2102.
    • (1999) J. Appl. Polym. Sci , vol.73 , pp. 2095-2102
    • Nasef, M.M.1    Saidi, H.2    Nor, H.M.3    Dahlan, K.Z.M.4    Hashim, K.5
  • 18
    • 0033881332 scopus 로고    scopus 로고
    • Cation Exchange Membranes by Radiation-Induced Graft Copolymerization of Styrene Onto PFA Copolymer Films. II. Characterization of Sulfonated Graft Copolymer Membranes
    • Nasef, M. M., Saidi, H., Nor, H. M., and Foo, O. M., 2000, "Cation Exchange Membranes by Radiation-Induced Graft Copolymerization of Styrene Onto PFA Copolymer Films. II. Characterization of Sulfonated Graft Copolymer Membranes," J. Appl. Polym. Sci., 76, pp. 1-11.
    • (2000) J. Appl. Polym. Sci , vol.76 , pp. 1-11
    • Nasef, M.M.1    Saidi, H.2    Nor, H.M.3    Foo, O.M.4
  • 19
    • 0026833107 scopus 로고
    • Preparation of Perfluorinated Ion Exchange Membranes and Their Application in Acid Recovery
    • Elmidaoui, A., Cherif, A. T., Brunea, J., Duclert, F., Cohen, T., and Gavach, C., 1992, "Preparation of Perfluorinated Ion Exchange Membranes and Their Application in Acid Recovery," J. Membr. Sci., 67, pp. 263-271.
    • (1992) J. Membr. Sci , vol.67 , pp. 263-271
    • Elmidaoui, A.1    Cherif, A.T.2    Brunea, J.3    Duclert, F.4    Cohen, T.5    Gavach, C.6
  • 21
    • 0034532289 scopus 로고    scopus 로고
    • The State of Water and the Nature of Ion Clusters in Crosslinked Proton Conducting Membranes of Styrene Grafted and Sulfonated Poly(vinylidene fluoride)
    • Elomaa, M., Hietala, S., Paronen, M., Walsby, N., Jokela, K., Serimaa, R., Torkkeli, M., Lehtinen, T., Sundholm, G., and Sundholm, F., 2000, "The State of Water and the Nature of Ion Clusters in Crosslinked Proton Conducting Membranes of Styrene Grafted and Sulfonated Poly(vinylidene fluoride)," J. Mater. Chem., 10, pp. 2678-2684.
    • (2000) J. Mater. Chem , vol.10 , pp. 2678-2684
    • Elomaa, M.1    Hietala, S.2    Paronen, M.3    Walsby, N.4    Jokela, K.5    Serimaa, R.6    Torkkeli, M.7    Lehtinen, T.8    Sundholm, G.9    Sundholm, F.10
  • 22
    • 0344485140 scopus 로고
    • Tracer Techniques for the Determination of Monomer Reactivity Ratios. IV. Copolymerization Characteristics of Some Divinyl Monomers
    • Wiley, R., and Mayberry, G., 1963, "Tracer Techniques for the Determination of Monomer Reactivity Ratios. IV. Copolymerization Characteristics of Some Divinyl Monomers," J. Polym. Sci., Part A: Gen. Pap., 1, pp. 217-226.
    • (1963) J. Polym. Sci., Part A: Gen. Pap , vol.1 , pp. 217-226
    • Wiley, R.1    Mayberry, G.2
  • 23
    • 0032623776 scopus 로고    scopus 로고
    • Effect of Crosslinking on the Physical Properties of Proton Conducting PVDF-g-PSSA Membranes
    • Leihtinen, T., Sundholm, G., and Sundholm, F., 1999, "Effect of Crosslinking on the Physical Properties of Proton Conducting PVDF-g-PSSA Membranes," J. Appl. Electrochem., 29, pp. 677-683.
    • (1999) J. Appl. Electrochem , vol.29 , pp. 677-683
    • Leihtinen, T.1    Sundholm, G.2    Sundholm, F.3
  • 25
    • 4444325018 scopus 로고    scopus 로고
    • Preparation of Proton Exchange Membranes Based on Crosslinked Polytetrafluoroethylene for Fuel Cell Applications
    • Yamaki, T., Kobayashi, K., Asano, M., Kubota, H., and Yoshida, M., 2004, "Preparation of Proton Exchange Membranes Based on Crosslinked Polytetrafluoroethylene for Fuel Cell Applications," Polymer, 45, pp. 6569-6573.
    • (2004) Polymer , vol.45 , pp. 6569-6573
    • Yamaki, T.1    Kobayashi, K.2    Asano, M.3    Kubota, H.4    Yoshida, M.5
  • 27
    • 1642267575 scopus 로고    scopus 로고
    • Pre-Irradiation Induced Grafting of Styrene into Crosslinked and Non-Crosslinked Polytetrafluoroethylene Films for Polymer Electrolyte Fuel Cell Applications. I: Influence of Styrene Grafting Conditions
    • Li, J., Sato, K., Ichiduri, S., Asano, S., Ikeda, S., Iida, M., Oshima, A., Tabata, Y., and Washio, M., 2004, "Pre-Irradiation Induced Grafting of Styrene into Crosslinked and Non-Crosslinked Polytetrafluoroethylene Films for Polymer Electrolyte Fuel Cell Applications. I: Influence of Styrene Grafting Conditions," Eur. Polym. J., 40, pp. 775-783.
    • (2004) Eur. Polym. J , vol.40 , pp. 775-783
    • Li, J.1    Sato, K.2    Ichiduri, S.3    Asano, S.4    Ikeda, S.5    Iida, M.6    Oshima, A.7    Tabata, Y.8    Washio, M.9
  • 28
    • 12244266504 scopus 로고    scopus 로고
    • Pre-Irradiation Induced Grafting of Styrene Into Crosslinked and Non-Crosslinked Polytetrafluoroethylene Films for Polymer Electrolyte Fuel Cell Applications. II: Characterization of the Styrene Grafted Films
    • Li, J., Sato, K., Ichiduri, S., Asano, S., Ikeda, S., Iida, M., Oshima, A., Tabata, Y., and Washio, M., 2005, "Pre-Irradiation Induced Grafting of Styrene Into Crosslinked and Non-Crosslinked Polytetrafluoroethylene Films for Polymer Electrolyte Fuel Cell Applications. II: Characterization of the Styrene Grafted Films," Eur. Polym. J., 41, pp. 547-555.
    • (2005) Eur. Polym. J , vol.41 , pp. 547-555
    • Li, J.1    Sato, K.2    Ichiduri, S.3    Asano, S.4    Ikeda, S.5    Iida, M.6    Oshima, A.7    Tabata, Y.8    Washio, M.9
  • 30
    • 21644445316 scopus 로고    scopus 로고
    • Radiation-Induced Grafting of Styrene Into Radiation-Modified Fluoropolymer Films
    • Lappan, U., Geißler, U., and Uhlmann, S., 2005, "Radiation-Induced Grafting of Styrene Into Radiation-Modified Fluoropolymer Films," Nucl. Instrum. Methods Phys. Res. B, 236, pp. 413-419.
    • (2005) Nucl. Instrum. Methods Phys. Res. B , vol.236 , pp. 413-419
    • Lappan, U.1    Geißler, U.2    Uhlmann, S.3
  • 31
    • 19344377968 scopus 로고    scopus 로고
    • Preparation of Sulfonated CPTFE-graft-Poly(alkyl vinyl ether) Membranes for Polymer Electrolyte Membrane Fuel Cells by Radiation Processing
    • Chen, J., Asano, M., Yamaki, T., and Yoshida, M., 2005, "Preparation of Sulfonated CPTFE-graft-Poly(alkyl vinyl ether) Membranes for Polymer Electrolyte Membrane Fuel Cells by Radiation Processing," J. Membr. Sci., 256, pp. 38-45.
    • (2005) J. Membr. Sci , vol.256 , pp. 38-45
    • Chen, J.1    Asano, M.2    Yamaki, T.3    Yoshida, M.4
  • 32
    • 0001262434 scopus 로고
    • Melting and Crystallization Behavior of Poly(tetrafluoroethylene). New Method for Molecular Weight Measurement of Poly(tetrafluoroethylene) Using a Differential Scanning Calorimeter
    • Suwa, T., Takehisa, M., and Machi, S., 1973, "Melting and Crystallization Behavior of Poly(tetrafluoroethylene). New Method for Molecular Weight Measurement of Poly(tetrafluoroethylene) Using a Differential Scanning Calorimeter," J. Appl. Polym. Sci., 17, pp. 3253-3257.
    • (1973) J. Appl. Polym. Sci , vol.17 , pp. 3253-3257
    • Suwa, T.1    Takehisa, M.2    Machi, S.3
  • 33
    • 0028485788 scopus 로고
    • High-Yield Synthesis and Characterization of 1,2-Bis(p-vinylphenyl)ethane
    • Li, W.-H., Li., K., Stöver, H., and Hamielec, A. E., 1994, "High-Yield Synthesis and Characterization of 1,2-Bis(p-vinylphenyl)ethane" J. Polym. Sci., Part A: Polym. Chem., 32, pp. 2023-2027.
    • (1994) J. Polym. Sci., Part A: Polym. Chem , vol.32 , pp. 2023-2027
    • Li, W.-H.1    Li, K.2    Stöver, H.3    Hamielec, A.E.4
  • 34
    • 0028445272 scopus 로고
    • Radiation Crosslinking of Polytetrafluoroethylene
    • Sun, J., Zhang, Y., and Zhong, X., 1994, "Radiation Crosslinking of Polytetrafluoroethylene," Polymer, 35, pp. 2881-2883.
    • (1994) Polymer , vol.35 , pp. 2881-2883
    • Sun, J.1    Zhang, Y.2    Zhong, X.3
  • 35
    • 0028626279 scopus 로고
    • Modification of Polytetrafluoroethylene by Radiation - 1. Improvement in High Temperature Properties and Radiation Stability
    • Sun, J., Zhang, Y., Zhong, X., and Zhu, X., 1994, "Modification of Polytetrafluoroethylene by Radiation - 1. Improvement in High Temperature Properties and Radiation Stability," Radiat. Phys. Chem., 44, pp. 655-659.
    • (1994) Radiat. Phys. Chem , vol.44 , pp. 655-659
    • Sun, J.1    Zhang, Y.2    Zhong, X.3    Zhu, X.4
  • 36
    • 33751296893 scopus 로고
    • Determination of Water Diffusion Coefficients in Perfluorosulfonate Ionomeric Membranes
    • Zawodzinski, T. A., Jr., Neeman, M., Sillerud, L. O., and Gottesfeld, S., 1991, "Determination of Water Diffusion Coefficients in Perfluorosulfonate Ionomeric Membranes," J. Phys. Chem., 95, pp. 6040-6044.
    • (1991) J. Phys. Chem , vol.95 , pp. 6040-6044
    • Zawodzinski Jr., T.A.1    Neeman, M.2    Sillerud, L.O.3    Gottesfeld, S.4
  • 37
    • 0001386867 scopus 로고
    • Polyelectrolytes Prepared from Perfluoroalkylaryl Macromolecules
    • Hodgdon, R. B., Jr., 1968, "Polyelectrolytes Prepared from Perfluoroalkylaryl Macromolecules," Syst. Control Lett., 6, pp. 171-191.
    • (1968) Syst. Control Lett , vol.6 , pp. 171-191
    • Hodgdon Jr., R.B.1
  • 38
    • 0031472559 scopus 로고    scopus 로고
    • ESR Study on Free Radicals Trapped in Crosslinked Polytetrafluoroethylene (PTFE)
    • Oshima, A., Seguchi, T., and Tabata, Y, 1997, "ESR Study on Free Radicals Trapped in Crosslinked Polytetrafluoroethylene (PTFE)," Radiat. Phys. Chem., 50, pp. 601-606.
    • (1997) Radiat. Phys. Chem , vol.50 , pp. 601-606
    • Oshima, A.1    Seguchi, T.2    Tabata, Y.3
  • 39
    • 0032927107 scopus 로고    scopus 로고
    • EPR Investigation of HOï Radical Initiated Degradation Reactions of Sulfonated Aromatics as Model Compounds for Fuel Cell Proton Conducting Membranes
    • Hübner, G., and Roduner, E., 1999, "EPR Investigation of HOï Radical Initiated Degradation Reactions of Sulfonated Aromatics as Model Compounds for Fuel Cell Proton Conducting Membranes," J. Mater. Chem., 9, pp. 409-418.
    • (1999) J. Mater. Chem , vol.9 , pp. 409-418
    • Hübner, G.1    Roduner, E.2
  • 40
    • 0033898727 scopus 로고    scopus 로고
    • Degradation of a Fuel Cell Membrane, as Revealed by Micro-Raman Spectroscopy
    • Mattsson, B., Ericson, H., Torell, L. M., and Sundholm, F., 2000, "Degradation of a Fuel Cell Membrane, as Revealed by Micro-Raman Spectroscopy," Electrochim. Acta, 45, pp. 1405-1408.
    • (2000) Electrochim. Acta , vol.45 , pp. 1405-1408
    • Mattsson, B.1    Ericson, H.2    Torell, L.M.3    Sundholm, F.4


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.