SCOPUS 정보 검색 플랫폼

Synlett

Volumn , Issue 7, 2007, Pages 1051-1054

Nitration of fullerene derivatives under mild conditions

(3) Oswald, Frederic a De La Cruz, Pilar a Langa, Fernando a

a UNIVERSITY OF CASTILLA LA MANCHA (Spain)

Author keywords

Electrochemistry; Electrophilic aromatic substitution; Fullerene

Indexed keywords

FULLERENE DERIVATIVE; N (2,4 DINITROPHENYL) 2 PYRAZOLINO[60]FULLERENE DERIVATIVE; NITRONIUM TRIFLATE; ORGANOFLUORINE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CHEMICAL STRUCTURE; ELECTROCHEMISTRY; MATRIX ASSISTED LASER DESORPTION IONIZATION TIME OF FLIGHT MASS SPECTROMETRY; NITRATION; PROTON NUCLEAR MAGNETIC RESONANCE; SUBSTITUTION REACTION; SYNTHESIS;

EID: 34248146967 PISSN: 09365214 EISSN: None Source Type: Journal
DOI: 10.1055/s-2007-977425 Document Type: Article

Times cited : (6)

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- Experimental Procedure: To an anhyd CH2Cl2 solution of the corresponding fullerene derivative 2 (1 equiv) in CH 2Cl2, tetramethylammonium nitrate (2 equiv) was added under Ar. The solution was cooled to the desired temperature and triflic anhydride (2 equiv) was added. NO2OTf was formed in situ and the solution was kept at this temperature until the complete disappearance of the starting material (the reaction progression was followed by TLC, The reaction was then quenched by adding a Na2CO3 solution (pH 8, The organic layer was separated, dried and evaporated. The remaining solid was purified by column chromatography affording the desired compounds 1a-d. Compound 1a: reaction temperature: -5°C for 4 h. Column chromatography (silica gel; toluene-hexane, 1:2, yield: 90, 1H NMR (500 MHz, CDCl3, δ, 8.80 (d, J, 2.5 Hz, 1 H, 8.45 dd, J
- 4: 1140.86; found: 1141.2.

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