Linear free energy relation of methanofullerene C61-substituents with cyclic voltammetry: Strong electron withdrawal anomaly

Tetrahedron

Volumn 52, Issue 14, 1996, Pages 5149-5159

  Keshavarz K, Majid ^b   Knight, Brian ^b   Haddon, Robert C ^a   Wudl, Fred ^b  

^a LUCENT TECHNOLOGIES   (United States)

^b NONE

Author keywords

[No Author keywords available]

Indexed keywords

FULLERENE DERIVATIVE; POLYCYCLIC HYDROCARBON;

ARTICLE; CYCLIC POTENTIOMETRY; DRUG ANALYSIS; ELECTROCHEMISTRY; PRIORITY JOURNAL; SPECTROPHOTOMETRY;

EID: 0029970374     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/0040-4020(96)00121-4     Document Type: Article

References (26)

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16. 3 (nonaqueous) reference electrode, and a scan rate of 100 mV/sec. 0.5 mM Ferrocene was added as an internal reference .
17. Osteryoung, J. G.; O'Dea, J. J. ; Osteryoung, J. G.; O'Dea, J. J., Ed.; Dekker: New York, 1986; Vol. 14.
18. 4, Pt disk working electrode, and Ag (wire) quasi reference electrode. 0.5 mM Ferrocene was added as an internal reference.
19. c obtained using sampled-current voltammetry in benzonitrile was linear with a slope of 54 mV (r = 0.9998), which is consistent with a one-electron process Bard, A.J.; Faulkner, L.R. Electrochemical Methods: Fundamentals and Applications; Wiley: New York, 1980, Chapter 5.
20. 60 by thin layer chromatography and UV-vis spectroscopy .
21. Gonzalez, M.; Keshavarz-k, M.; Hummelen, J. C. unpublished results 1995.
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23. Analyses of substituent effects on cyclopropane bond lengths have been given by Hoffman, R. Tet Lett. 1970, 2907; Gunther, H. Tet Lett. 1970, 5173; Haddon, R. C. Tet. Lett. 1974, 2797.
24. Analyses of substituent effects on cyclopropane bond lengths have been given by Hoffman, R. Tet Lett. 1970, 2907; Gunther, H. Tet Lett. 1970, 5173; Haddon, R. C. Tet. Lett. 1974, 2797.
25. Analyses of substituent effects on cyclopropane bond lengths have been given by Hoffman, R. Tet Lett. 1970, 2907; Gunther, H. Tet Lett. 1970, 5173; Haddon, R. C. Tet. Lett. 1974, 2797.
26. An anonymous referee suggested this possibility in the review process of a similar paper. The principle can be found in Bard, A. J.; Faulkner, L. R. Electrochemical Methods: Fundamentals and Applications; Wiley: New York, 1980, pp 453.