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3CN. From a comparison of the data it was concluded that the acetonitrile molecule binds significantly stronger to Zn-1 than to the reference compound, suggesting strong complexation of acetonitrile inside the cavity.
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3CN. From a comparison of the data it was concluded that the acetonitrile molecule binds significantly stronger to Zn-1 than to the reference compound, suggesting strong complexation of acetonitrile inside the cavity.
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34247871839
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Using larger amounts of tbpy might significantly affect the polarity of the system, causing a change in the affinity of the viologen moiety for the cavity of 1. A blanc experiment using H2-1 under the applied conditions, however, did not reveal any notable effect on the threading rate constant kon
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on).
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See a
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See (a) Koppelman, S. J.; vanHoeij, M.; Vink, T.; Lankhof, H.; Schiphorst, M. E.; Damas, C.; Vlot, A. J.; Wise, R.; Bouma, B. N.; Sixma, J. J. Blood 1996, 87, 2292-2300.
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Sixma, J.J.10
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19
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0031041828
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(b) Asakawa, M.; Ashton, P. R.; Ballardini, R.; Balzani, V.; Belohradsky, M.; Gandolfi, M. T.; Kocian, O.; Prodi, L.; Raymo, F. M.; Stoddart, J. F.; Venturi, M. J. Am. Chem. Soc. 1997, 119, 302-310.
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Asakawa, M.1
Ashton, P.R.2
Ballardini, R.3
Balzani, V.4
Belohradsky, M.5
Gandolfi, M.T.6
Kocian, O.7
Prodi, L.8
Raymo, F.M.9
Stoddart, J.F.10
Venturi, M.11
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