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Volumn , Issue 18, 2007, Pages 1810-1812

Twisted oxygen-containing oligosilanes - Unprecedented examples of σ-n mixed conjugated systems

Author keywords

[No Author keywords available]

Indexed keywords

OXYGEN; SILANE DERIVATIVE;

EID: 34247882807     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/b618438c     Document Type: Article
Times cited : (14)

References (20)
  • 8
    • 0003612385 scopus 로고    scopus 로고
    • ed. N. Auner and J. Weis, Vol. VI, VCH, Weinheim, p 337
    • C. Krempner, in Organosilicon Chemistry,, ed. N. Auner, and, J. Weis,, Vol. VI, VCH, Weinheim, 2005, p 337
    • (2005) Organosilicon Chemistry
    • Krempner In, C.1
  • 16
    • 0003670973 scopus 로고    scopus 로고
    • John Wiley & Sons: New York, pp 695 The conformations are roughly classified as syn (S, ω ∼ 0°), gauche (G, ω ∼ 60°), ortho (O, ω ∼ 90°), eclipsed (E, ω ∼ 120°), deviant (D, ω ∼ 150°) and anti (A, ω ∼ 180°);
    • P. D. Lickiss, in The Chemistry of Organo Silicon Compounds, John Wiley & Sons: New York, 2001, Vol 3, pp 695
    • (2001) The Chemistry of Organo Silicon Compounds
    • Lickiss In, P.D.1
  • 17
    • 0034519392 scopus 로고    scopus 로고
    • -1, which corresponds to the dimer in the solid state GAUSSIAN 98 (Revision A.1), Gaussian, Inc., Pittsburgh, PA, see Supporting Information
    • J. Michl R. West Acc. Chem. Res. 2000 33 821
    • (2000) Acc. Chem. Res. , vol.33 , pp. 821
    • Michl, J.1    West, R.2
  • 18
    • 34247893185 scopus 로고    scopus 로고
    • The rotational energy barrier was determined by calculations where one of the SiSiSiSi dihedral angles was varied in 10° increments, with all of the other parameter being fully optimized For compound 4, two minimum structures denoted as 4a and 4b were found (see Table 1)
    • The rotational energy barrier was determined by calculations where one of the SiSiSiSi dihedral angles was varied in 10° increments, with all of the other parameter being fully optimized


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.