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Volumn 45, Issue 40, 2006, Pages 6755-6759

Hydroxy-substituted oligosilane dendrimers: Controlling the electronic properties through hydrogen bonding

Author keywords

Hydrogen bonds; IR spectroscopy; Oligosilanes; Silanols; UV spectroscopy

Indexed keywords

CONFORMATIONS; ELECTRONIC PROPERTIES; HYDROGEN BONDS; INFRARED SPECTROSCOPY; SILANES; SUBSTITUTION REACTIONS;

EID: 33750158562     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200601598     Document Type: Article
Times cited : (24)

References (35)
  • 16
    • 0000803537 scopus 로고
    • see
    • For the Prelog-Seebach notation of l and u, see: D. Seebach, V. Prelog, Angew. Chem. 1982, 94, 696;
    • (1982) Angew. Chem. , vol.94 , pp. 696
    • Seebach, D.1    Prelog, V.2
  • 18
    • 33750154321 scopus 로고    scopus 로고
    • note
    • For details of X-ray structure analyses of l,l-3 and l,u-3, see Supporting Information.
  • 19
    • 33749105115 scopus 로고
    • For excellent reviews on solid-state structures of silanols see: a) P. D. Lickiss, Adv. Inorg. Chem. 1995, 42, 147;
    • (1995) Adv. Inorg. Chem. , vol.42 , pp. 147
    • Lickiss, P.D.1
  • 34
    • 0034519392 scopus 로고    scopus 로고
    • The conformations are roughly classified as syn (S, ω ≈ 0°), gauche (G, ω ≈ 60°), ortho (O, ω ≈ 90°), eclipsed (E, ω ≈ 120°), deviant (D, ω ≈ 150°) and anti (A, ω ≈ 180°); J. Michl, R. West, Acc. Chem. Res. 2000, 33, 821.
    • (2000) Acc. Chem. Res. , vol.33 , pp. 821
    • Michl, J.1    West, R.2
  • 35
    • 3242876967 scopus 로고    scopus 로고
    • see Supporting Information
    • -1 depending in the monomer structure (two isomers shown in Figure 5). Gaussian03 (RevisionA.1), M. J. Frisch et al., see Supporting Information.
    • Gaussian03 (RevisionA.1)
    • Frisch, M.J.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.