A highly stereocontrolled formal total synthesis of (±)- and of (-)-grandisol by 1,4-conjugated addition of organocopper reagents to cyclobutylidene derivatives

Tetrahedron

Volumn 63, Issue 23, 2007, Pages 4968-4974

  Bernard, Angela M ^a   Frongia, Angelo ^a   Ollivier, Jean ^b   Piras, Pier Paolo ^a   Secci, Francesco ^a   Spiga, Marco ^a  

^a UNIVERSITY OF CAGLIARI   (Italy)

^b UNIVERSITÉ PARIS SACLAY   (France)

Author keywords

Carbocycles; Cuprates; Diastereoselectivity; Pheromones

Indexed keywords

2 BUTANONE; BUTANOL; COPPER; CYCLOBUTANONE; CYCLOBUTYLIDENE DERIVATIVE; CYCLOPROPANE; GRANDISOL; LITHIUM DERIVATIVE; LITHIUM DIMETHYLCUPRATE; PHEROMONE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL STRUCTURE; ENANTIOSELECTIVITY; PRIORITY JOURNAL; PROTON NUCLEAR MAGNETIC RESONANCE; SYNTHESIS;

EID: 34247564606     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tet.2007.03.134     Document Type: Article

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