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Volumn 16, Issue 13, 1997, Pages 2981-2986

Mechanistic aspects of asymmetric hydroformylation of olefins catalyzed by chiral phosphine - phosphite - rhodium(I) complexes

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Indexed keywords


EID: 0001496002     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om970134u     Document Type: Article
Times cited : (87)

References (41)
  • 1
    • 0002928156 scopus 로고
    • Falbe, J., Ed.; Springer-Verlag: Berlin, Chapter 1
    • (a) Cornils, B. In New Syntheses with Carbon Monoxide; Falbe, J., Ed.; Springer-Verlag: Berlin, 1980; Chapter 1, pp 1-225.
    • (1980) New Syntheses with Carbon Monoxide , pp. 1-225
    • Cornils, B.1
  • 16
  • 28
    • 0002112037 scopus 로고
    • It is known that the β-hydride elimination is controlled by a kinetic isotope effect, which means that elimination of Rh-H is faster than that of Rh-D: Evans, J.; Schwartz, J.; Urquhart, P. W. J. Organomet. Chem. 1974, 81, C37.
    • (1974) J. Organomet. Chem. , vol.81
    • Evans, J.1    Schwartz, J.2    Urquhart, P.W.3
  • 29
    • 85033279345 scopus 로고    scopus 로고
    • note
    • co = 0.5-5 atm).
  • 39
    • 85033281140 scopus 로고    scopus 로고
    • note
    • 19 For the present hydroformylation, the possibility of racemization can be ruled out by the high enantioselectivty of the reaction.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.