Localization and delocalization in a mixed-valence dicopper helicate

Inorganic Chemistry

Volumn 46, Issue 7, 2007, Pages 2417-2426

  Jeffery, John C ^a   Riis Johannessen, Thomas ^a   Anderson, Callum J ^a   Adams, Christopher J ^a   Robinson, Adam ^a   Argent, Stephen P ^b   Ward, Michael D ^b   Rice, Craig R ^c  

^a UNIVERSITY OF BRISTOL   (United Kingdom)

^b UNIVERSITY OF SHEFFIELD   (United Kingdom)

^c UNIVERSITY OF HUDDERSFIELD   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

COPPER; LIGAND;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; ELECTROCHEMISTRY; ELECTRON SPIN RESONANCE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; X RAY CRYSTALLOGRAPHY;

COPPER; CRYSTALLOGRAPHY, X-RAY; ELECTROCHEMISTRY; ELECTRON SPIN RESONANCE SPECTROSCOPY; LIGANDS; MAGNETIC RESONANCE SPECTROSCOPY; MODELS, MOLECULAR; MOLECULAR STRUCTURE;

EID: 34247275779     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic061504m     Document Type: Article

References (72)

1. (a) Hannon, M. J.; Childs, L. J. Supramol. Chem. 2004, 16, 7.
2. (b) Albrecht, M. Chem. Rev. 2001, 101, 3457.
3. (c) Piguet, C.; Bernardinelli, G.; Hopfgartner, G. Chem. Rev. 1997, 97, 2005.
4. (d) Yeh, R. M.; Davis, A. V.; Raymond, K. N. In Comprehensive Coordination Chemistry II; McCleverty, J. A., Meyer, T. J., Eds.; Elsevier Ltd.: Oxford, U.K., 2004; Vol. 7, p 327.
5. (a) Piguet, C.; Borkovec, M.; Hamacek, J.; Zeckert, K. Coord. Chem. Rev. 2005, 249, 705.
6. (b) Hamacek, J.; Borkovec, M.; Piguet, C. Chem. Eur. J. 2005, 11, 5217.
7. (c) Hamacek, J.; Borkovec, M.; Piguet, C. Chem. Eur. J. 2005, 11, 5227.
8. (a) Lehn J.-M. Supramolecular Chemistry - Concepts and Perspectives; VCH: Weinheim, Germany, 1995.
9. (b) Lehn, J.-M. Angew. Chem., Int. Ed. Engl. 1990, 29, 1304.
10. Constable, E. C. In Comprehensive Supramolecular Chemistry; Atwood, J. L., Davies, J. E. D., Lehn, J.-M., MacNicol, D. D., Vögtle, F., Eds.: Pergamon Press: Oxford, U.K., 1996; Vol. 9, p 213.
11. (a) Potts, K. T.; Keshavarz-K, M.; Tham, F. S.; Abruña, H. D.; Arana, C. R. Inorg. Chem. 1993, 32, 4422.
12. (b) Potts, K. T.; Keshavarz-K, M.; Tham, F. S.; Abruña, H. D.; Arana, C. R. Inorg. Chem. 1993, 32, 4436.
13. (c) Potts, K. T.; Keshavarz-K, M.; Tham, F. S.; Gheysen Raiford, K. A.
14. (d) Abruña, H. D.; Arana, C. R. Inorg. Chem. 1993, 32, 4422;
15. Potts, K. T.; Keshavarz-K, M.; Tham, F. S.; Abruña, H. D.; Arana, C. R. Inorg. Chem. 1993, 32, 4450.
16. See, for example: (a) Yeh, R. M.; Raymond, K. N. Inorg. Chem. 2006, 45, 1130.
17. (b) Caulder, D. L.; Raymond, K. N. J. Chem. Soc., Dalton Trans. 1999, 1185.
18. (c) Caulder, D. L.; Raymond, K. N. Angew. Chem., Int. Ed. Engl. 1997, 36, 1440.
19. See, for example: (a) Hahn, F. E.; Isfort, C. S.; Pape, T. Angew. Chem., Int. Ed. 2004, 43, 4807.
20. (b) Hahn, F. E.; Kreickmann, T.; Pape, T. Dalton Trans. 2006, 769.
21. See, for example: (a) Ronson, T. K.; Adams, H.; Riis-Johannessen, T.; Jeffery, J. C.; Ward, M. D. New J. Chem. 2006, 30, 26.
22. (b) Ronson, T. K.; Adams, H.; Ward, M. D. Inorg. Chim. Acta 2005, 358, 1943.
23. See, for example: (a) Zeckert, K.; Hamacek, J.; Senegas, J.-M.; Dalla-Favera, N.; Floquet, S.; Bernardinelli, G.; Piguet, C. Angew. Chem., Int. Ed. 2005, 44, 1.
24. (b) Torelli, S.; Delahaye, S.; Hauser, A.; Bernardinelli, G.; Piguet, C. Chem. Eur. J. 2004, 10, 3503.
25. (c) Floquet, S.; Borkovec, M.; Bernardinelli, G.; Pinto, A.; Leuthold, L.-A.; Hopfgartner, G.; Imbert, D.; Bünzli, J.-C. G.; Piguet, C. Chem. Eur. J. 2004, 10, 1091.
26. (d) Floquet, S.; Ouali, N.; Bocquet, B.; Bernardinelli, G.; Imbert, D.; Bunzli, J.-C. G.; Hopfgartner, G.; Piguet, C. Chem., Eur. J. 2003, 9, 1860.
27. (a) Baylies, C. J.; Harding, L. P.; Jeffery, J. C.; Riis-Johannessen, T.; Rice, C. R. Angew. Chem., Int. Ed. 2004, 43, 4515.
28. (b) Baylies, C. J.; Riis-Johannessen, T.; Harding, L. P.; Jeffery, J. C.; Moon, R.; Rice, C. R.; Whitehead, M. Angew. Chem., Int. Ed. 2005, 44, 6909.
29. (c) Riis-Johannessen, T.; Jeffery, J. C.; Robson, A. P. H.; Rice, C. R.; Harding, L. P. Inorg. Chim. Acta 2005, 358, 2781.
30. (a) Rice, C. R.; Worl, S.; Jeffery, J. C.; Paul, R. L.; Ward, M. D. J. Chem. Soc., Dalton Trans. 2001, 550.
31. (b) Rice, C. R.; Wörl, S.; Jeffery, J. C.; Paul, R. L.; Ward, M. D. Chem. Commun. 2000, 1529.
32. (a) Constable, E. C.; Elder, S. M.; Healy, J.; Tocher, D. A. J. Chem. Soc., Dalton Trans. 1990, 1169.
33. (b) Maslen, E. N.; Raston, C. L.; White, A. H. J. Chem. Soc. Dalton Trans. 1975, 323.
34. (c) Henke, Von, W.; Kremer, S.; Reinen, D. Z. Anorg. Allg. Chem. 1982, 491, 124.
35. (d) Constable, E. C.; Elder, S. M.; Healy, J.; Ward, M. D.; Tocher, D. A. J. Am. Chem. Soc. 1990, 112, 4590.
36. (e) Constable, E. C.; Elder, S. M.; Tocher, D. A. Polyhedron 1992, 11, 1337.
37. (f) Constable, E. C.; Elder, S. M.; Hannon, M. J.; Martin, A.; Raithby, P. R.; Tocher, D. A. J. Chem. Soc. Dalton Trans. 1996, 2423.
38. Foley, J.; Kennefick, D.; Phelan, D.; Tyagi, S.; Hathaway, B. J. Chem. Soc. Dalton Trans. 1983, 2333.
39. Hunter, C. A.; Lawson, K. R.; Perkins, J.; Urch, C. J. Chem. Soc., Perkin Trans. 2 2001, 651.
40. Hathaway, B.; Billing, D. E. Coord. Chem. Rev. 1970, 5, 143.
41. van Koten, G.; Noltes, J. G. In Comprehensive Organometallic Chemistry; Wilkinson, G., Stone, F. G. A., Abel, E., Eds.; Pergamon Press: New York, 1982; Vol. 2. Chapter 14, p 772.
42. Ichinaga, A. K.; Kirchhoff, J. R.; McMillin, D. R.; Dietrich-Buchecker, C. O.; Marnot, P. A.; Sauvage, J.-P. Inorg. Chem. 1987, 26, 4290.
43. (a) Davis, W. D.; Zask, A.; Nakanishi, K.; Lippard, S. J. Inorg. Chem. 1985, 24, 3737.
44. (b) Gouge, E. M.; Geldard, J. F. Inorg. Chem. 1978, 17, 270..
45. (c) Yokoi, H.; Addison, A. W. Inorg. Chem. 1977, 16, 1341.
46. Robin, M. B.; Day, P. Adv. Inorg. Chem. Radiochem. 1967, 10, 247.
47. (a) Hush, N. S. Prog. Inorg. Chem. 1967, 8, 391.
48. (b) Creutz, C. Prog. Inorg. Chem. 1983, 30, 1.
49. (a) Barr, M. E.; Smith, P. H.; Antholine, W. E.; Spencer, B. J. Chem. Soc., Chem. Commun. 1993, 1649.
50. (b) Harding, C.; McKee, V.; Nelson, J. J. Am. Chem. Soc. 1991, 113, 9684.
51. (c) Franzen, S.; Miskowski, V. M.; Shreve, A. P.; Wallace-Williams, S. E.; Woodruff, W. H.; Ondrias, M. R.; Barr, M. E.; Moore, L.; Boxer, S. G. Inorg. Chem. 2001, 40, 6375.
52. (d) Al-Obaidi, A.; Baranovic, G.; Coyle, J.; Coates, C. G.; McGarvey, J. J.; McKee, V.; Nelson, J. Inorg. Chem. 1998, 37, 3567.
53. (e) LeCloux, D. D.; Davydov, R.; Lippard, S. J. Inorg. Chem. 1998, 37, 6814.
54. (f) Harding, C.; Nelson, J.; Symons, M. C. R.; Wyatt, J. J. Chem. Soc. Chem. Commun. 1994, 2499.
55. (g) Farrar, J. A.; McKee, V.; Al-Obaidi, A. H. R.; McGarvey, J. J.; Nelson, J.; Thomson, A. J. Inorg. Chem. 1995, 37, 3567.
56. (h) Farrar, J. A.; Grinter, R.; Neese, F.; Nelson, J.; Thomson, A. J. J. Chem. Soc., Dalton Trans. 1997, 4083.
57. Falvello, L. R. J. Chem. Soc. Dalton Trans. 1997, 4463.
58. Dunitz, J. D.; Schomaker, V.; Trueblood, K. N. J. Chem. Phys. 1988, 92, 856.
59. Hathaway, B. J. Struct. Bonding (Berlin) 1984, 57, 55.
60. See, for example: (a) Gagné, R. R.; Koval, C. A.; Smith, T. J.; Cimolino, M. C. J. Am. Chem. Soc. 1979, 101, 4571.
61. (b) Long, R. C.; Hendrickson, D. N. J. Am. Chem. Soc. 1983, 105, 1513.
62. Jones, P. L.; Jeffery, J. C.; Maher, J. P.; McCleverty, J. A.; Rieger, P. H.; Ward, M. D. Inorg. Chem. 1997, 36, 3088.
63. (a) Bruker WINEPR System, version 2.11: Bruker-Franzen Analytik GmbH, 1990-1996.
64. (b) WINEPR SimFonia, version 1.25; Bruker Analytische Messtechnik GmbH, 1994-1996.
65. SMART Diffractometer Control Software; Bruker Analytical X-ray Instruments Inc.: Madison, WI, 1998.
66. SAINT Integration Software; Siemens Analytical X-ray Instruments Inc.: Madison, WI, 1994.
67. SHELXTL Program System, version 5.1; Bruker Analytical X-ray Instruments Inc.: Madison, WI, 1998.
68. Sheldrick, G. M. SADABS: A Program for Absorption Correction with the Siemens SMART System; University of Göttingen: Göttingen, Germany, 1996.
69. Spek, A. L. Acta. Crystallogr. 1990, A46, C-34.
70. PLATON - A Multipurpose Crystallographic Tool; Utrecht University: Utrecht, The Netherlands, 2003.
71. For synthesis, see: Baxter, P. N. W.; Connor, J. A.; Schweizer, W. B.; Wallis, J. D. J. Chem. Soc., Dalton Trans. 1992, 3015.
72. We note that an almost identical Cu⋯Cu separation of 2.92 Å was observed by Thummel et al. in the dicopper(I) helicate of a tetradentate bis-1,10-phenanthroline ligand. See: Riesgo, E. C.; Hu, Y.-Z.; Thummel, R. P. Inorg. Chem. 2003, 42, 6648.