Separation of high-value products from ethanol extracts of corn by chromatography

Industrial Crops and Products

Volumn 26, Issue 1, 2007, Pages 44-53

  Kale, Aniket ^a   Zhu, Fangyi ^a   Cheryan, Munir ^a  

^a UNIVERSITY OF ILLINOIS AT URBANA CHAMPAIGN   (United States)

Author keywords

Corn; LH 20; Size exclusion chromatography; Xanthophylls; Zein

Indexed keywords

ETHANOL; SIZE EXCLUSION CHROMATOGRAPHY; SOLVENTS;

AQUEOUS ETHANOL; DRY GRIND ETHANOL INDUSTRY; ECONOMIC VIABILITY; HIGH VALUE PRODUCTS;

CROPS;

CAROTENOID; CHEMICAL INDUSTRY; CHROMATOGRAPHY; ETHANOL; INCOME; MAIZE; PROTEIN; SEPARATION; YIELD;

CAROTENOIDS; CORN; ETHANOL; ZEIN;

ZEA MAYS;

CHROMATOGRAPHY; PLANT EXTRACT; RAW MATERIAL; SEPARATION; ZEIN;

EID: 34247168509     PISSN: 09266690     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.indcrop.2007.01.006     Document Type: Article

References (33)

1. Amersham. Sephadex LH-20 Data File 18-1107-22 (1995), Amersham Biosciences, Uppsala, Sweden
2. Amersham. Sephadex LH-60 Data File 18-1108-79 (1995), Amersham Biosciences, Uppsala, Sweden
3. AOAC. Official method 990.03. Official Methods of Analysis of AOAC International. 17th ed. vol. I (2000) pp. 18-19 (Chapter 4)
4. Cheryan, M., 2001. Method for extracting xanthophylls from corn. US Patent 6,169,217.
5. Cheryan, M., 2002. Corn oil and protein extraction method. US Patent 6,433,146.
6. Coocni R., Burtscher E., and Bobleter O. Chromatographic behavior of aromatic compounds on Sephadex LH gels calibration of gel columns for determination of molecular weight distributions. J. Chromatogr. 198 (1980) 131-141
7. Cook, R.B., Mallee, F.M., Shulman, M.L., 1996. Purification of zein from corn gluten meal. US Patent 5,580,959.
8. Craine E.M., Freimuth D.V., Boundy J.A., and Dimler R.J. Preparation of purified zein by adsorption-desorption. Cereal Chem. 38 (1961) 399-407
9. Danzer L.A., and Rees E.D. Purification of zein on a laboratory scale by charcoal or gel filtration. Cereal Chem. 48 (1971) 118-120
10. Henke H. Preparative Gel Chromatography on Sephadex LH-20 (1994), Huthig, Heidelberg
11. Janshekar H., Haltmeier Th., and Brown C. Fungal degradation of pine and straw alkali lignins. Eur. J. Appl. Microbiol. Biotechnol. 14 (1982) 174-181
12. Kale, A., 2006. Purification of zein and xanthophylls from corn by process chromatography. Ph.D. Thesis. University of Illinois.
13. Kale A., and Cheryan M. Rapid analysis of xanthophylls in ethanol extracts of corn by HPLC. J. Liq. Chromatogr. Rel. Technol. 30 (2007) 1-12
14. Khachik, F., 2005a. Method for production of rare carotenoids from commercially available lutein. US Patent 6,911,564.
15. Khachik, F., 2005b. Process for extraction and purification of lutein, zeaxanthin and rare carotenoids from marigold flowers and plants. US Patent 6,262,284.
16. Kwiatkowski J., and Cheryan M. Recovery of corn oil from ethanol extracts of ground corn using membrane technology. JAOCS 82 (2005) 221-227
17. Landry J., Guyon P., and Moureaux T. Sur les conditions d'obtention d'une zein purifiee par chromatographie sur gels de dextranes alkyls. Compt. Rend. Acad. Sci. t.265 17 Juillet (1967) 264-267
18. Landry J., and Guyon P. Zein of maize grain. I. Isolation by gel filtration and characterization of monomeric and dimeric species. Biochimie 66 (1984) 451-460
19. McInnis, J., Tang, Q., 2003. Extraction of zein protein from gluten meal. US Patent 6,602,985.
20. Melchert H.U., Pollok D., Pabel E., Rubach K., and Stan H.J. Determination of tocopherols, tocopherol quinones and tocopherol hydroquinones by gas chromatography-mass spectrometry and pre separation with lipophilic gel chromatography. J. Chromatogr. A 976 (2002) 215-220
21. Moreau R.A., Nunez A., and Singh V. Diferuloylputrescine and p-coumaroyl-feruloylputrescine, abundant polyamine conjugates in lipid extracts of maize kernels. Lipids 36 (2001) 839-844
22. Morris, L., Unger, L.G., Wilson, A.L., 1956. Purification and recovery of zein from calcium hydroxide solutions. US Patent 2,733,234.
23. Moros E.E., Darnoko D., Cheryan M., Perkins E.G., and Jerrell J. Analysis of xanthophylls in corn by HPLC. J. Agric. Food Chem. 50 (2002) 5787-5790
24. Mosse J., and Landry J. Recent research on major maize proteins: zeins and glutelins. In: Inglett G.E. (Ed). Cereal for Food and Beverages (1980), Academic Press, NY 255-273
25. NCGA. World of Corn (2006), National Corn Growers Association, Chesterfield, MO
26. RFA. Homegrown for the Homeland: Ethanol Industry Outlook (2006), Renewable Fuels Association, Washington, DC
27. Seddon J., Ajani U.A., Sperduto R.D., Hiller R., Blair N., Burton T.C., Farber M.D., Gragoudas E.S., Halter J., Miller D.T., Yannuzzi L.A., and Willett W. Dietary carotenoids, vitamins A, C, and E, and advanced age-related macular degeneration. JAMA 272 (1994) 1413-1420
28. Sen A., Bergvinson D., Miller S.S., Atkinson J., Fulcher R.G., and Arnason J.T. Distribution and microchemical detection of phenolic acids, flavonoids, and phenolic acid amides in maize kernels. J. Agric. Food Chem. 42 (1994) 1879-1883
29. Sessa D.J., Eller F.J., Palmquist D.E., and Lawton J.W. Improved methods for decolorizing zein. Ind. Crop. Prod. 18 (2003) 55-65
30. Shukla R., and Cheryan M. Zein: the industrial protein from corn. Ind. Crop Prod. 13 (2001) 171-192
31. Shukla R., Cheryan M., and DeVor R.E. Solvent extraction of zein from dry-milled corn. Cereal Chem. 77 (2000) 724-730
32. Sommerburg O., Keunen J.E.E., Bird A.C., and Frederik K.J. Fruits and vegetables that are sources for lutein and zeaxanthin: the macular pigment in human eyes. Br. J. Ophthalmol. 82 (1998) 907-910
33. Takahashi, H., Yanai, N., 1996. Process of producing zein. US Patent 5,510,463.