-
1
-
-
0025445697
-
-
(a) Barbier, B.; Pinson, J.; Desarmot, G.; Sanchez, M. J. Electrochem. Soc. 1990, 137, 1757.
-
(1990)
J. Electrochem. Soc
, vol.137
, pp. 1757
-
-
Barbier, B.1
Pinson, J.2
Desarmot, G.3
Sanchez, M.4
-
2
-
-
0028422475
-
-
(b) Deinhammer, R. S.; Ho, M.; Anderegg, J. W.; Porter, M. D. Langmuir 1994, 10, 1306.
-
(1994)
Langmuir
, vol.10
, pp. 1306
-
-
Deinhammer, R.S.1
Ho, M.2
Anderegg, J.W.3
Porter, M.D.4
-
3
-
-
4644229254
-
-
(c) Adenier, A.; Chehimi, M. M.; Gallardo, I.; Pinson, J.; Vilà, N. Langmuir 2004, 20, 8243.
-
(2004)
Langmuir
, vol.20
, pp. 8243
-
-
Adenier, A.1
Chehimi, M.M.2
Gallardo, I.3
Pinson, J.4
Vilà, N.5
-
4
-
-
0344975450
-
-
Maeda, H.; Yamauchi, Y.; Ohmori, H. Curr. Top. Anal. Chem. 2001, 2, 121.
-
(2001)
Curr. Top. Anal. Chem
, vol.2
, pp. 121
-
-
Maeda, H.1
Yamauchi, Y.2
Ohmori, H.3
-
5
-
-
0001738805
-
-
(a) Delamar, M.; Hitmi, R.; Pinson, J.; Savéant, J.-M. J. Am. Chem. Soc. 1992, 114, 5883.
-
(1992)
J. Am. Chem. Soc
, vol.114
, pp. 5883
-
-
Delamar, M.1
Hitmi, R.2
Pinson, J.3
Savéant, J.-M.4
-
6
-
-
0031049710
-
-
(b) Allongue, P.; Delamar, M.; Desbat, B.; Fagebaume, O.; Hitmi, R.; Pinson, J.; Savéant, J.-M. J. Am. Chem. Soc. 1997, 119, 201.
-
(1997)
J. Am. Chem. Soc
, vol.119
, pp. 201
-
-
Allongue, P.1
Delamar, M.2
Desbat, B.3
Fagebaume, O.4
Hitmi, R.5
Pinson, J.6
Savéant, J.-M.7
-
9
-
-
0000583067
-
-
(a) Bourdillon, C.; Delamar, M.; Demaille, C.; Hitmi, R.; Moiroux, J.; Pinson, J. J. Electroanal. Chem. 1992, 336, 113.
-
(1992)
J. Electroanal. Chem
, vol.336
, pp. 113
-
-
Bourdillon, C.1
Delamar, M.2
Demaille, C.3
Hitmi, R.4
Moiroux, J.5
Pinson, J.6
-
10
-
-
0042769172
-
-
(b) Yang, X.; Hall, S. B.; Tan, S. N. Electroanalysis 2003, 15, 885.
-
(2003)
Electroanalysis
, vol.15
, pp. 885
-
-
Yang, X.1
Hall, S.B.2
Tan, S.N.3
-
11
-
-
0035976233
-
-
(a) Coulon, E.; Pinson, J.; Bourzat, J.-D.; Commerçon, A.; Pulicani, J.-P. Langmuir 2001, 17, 7102.
-
(2001)
Langmuir
, vol.17
, pp. 7102
-
-
Coulon, E.1
Pinson, J.2
Bourzat, J.-D.3
Commerçon, A.4
Pulicani, J.-P.5
-
12
-
-
0037195748
-
-
(b) Coulon, E.; Pinson, J.; Bourzat, J.-D.; Commerçon, A.; Pulicani, J.-P. J. Org. Chem. 2002, 67, 8513.
-
(2002)
J. Org. Chem
, vol.67
, pp. 8513
-
-
Coulon, E.1
Pinson, J.2
Bourzat, J.-D.3
Commerçon, A.4
Pulicani, J.-P.5
-
13
-
-
0029614825
-
-
(a) Downard, A. J.; Roddick, A. D.; Bond, A. M. Anal. Chim. Acta 1995, 317, 303.
-
(1995)
Anal. Chim. Acta
, vol.317
, pp. 303
-
-
Downard, A.J.1
Roddick, A.D.2
Bond, A.M.3
-
14
-
-
0041968743
-
-
(b) Zen, J.-M.; Kumar, A. S.; Tsai, D.-M. Electroanalysis 2003, 15, 1073.
-
(2003)
Electroanalysis
, vol.15
, pp. 1073
-
-
Zen, J.-M.1
Kumar, A.S.2
Tsai, D.-M.3
-
15
-
-
24944448629
-
-
Vase, K. H.; Holm, A. H.; Pedersen, S. U.; Daasbjerg, K. Langmuir 2005, 21, 8085.
-
(2005)
Langmuir
, vol.21
, pp. 8085
-
-
Vase, K.H.1
Holm, A.H.2
Pedersen, S.U.3
Daasbjerg, K.4
-
16
-
-
28844486190
-
-
Dirk, S. M.; Pylypenko, S.; Howell, S. W.; Fulghum, J. E.; Wheeler, D. R. Langmuir 2005, 21, 10899.
-
(2005)
Langmuir
, vol.21
, pp. 10899
-
-
Dirk, S.M.1
Pylypenko, S.2
Howell, S.W.3
Fulghum, J.E.4
Wheeler, D.R.5
-
17
-
-
0001596866
-
-
Beringer, F. M.; Falk, R. A.; Karniol, M.; Lillien, I.; Masullo, G.; Mausner, M.; Sommer, E. J. Am. Chem. Soc. 1959, 81, 342.
-
(1959)
J. Am. Chem. Soc
, vol.81
, pp. 342
-
-
Beringer, F.M.1
Falk, R.A.2
Karniol, M.3
Lillien, I.4
Masullo, G.5
Mausner, M.6
Sommer, E.7
-
18
-
-
34147193922
-
-
Origin 6.1, Originlab Corporation.
-
Origin 6.1, Originlab Corporation.
-
-
-
-
19
-
-
34147209688
-
-
An appropriate definition of the grafting efficiency should include the ratio of the surface coverage, Γ, and the consumed faradaic charge, Q. Because a precise experimental determination of Γ and Q can be quite tedious, it is, in most cases, convenient to obtain a rough estimate of the relative grafting efficiency simply from a comparison of the peak currents obtained on the first sweep in cyclic voltammetry or from the number of cycles required to completely passivate the electrode surface
-
An appropriate definition of the grafting efficiency should include the ratio of the surface coverage, Γ, and the consumed faradaic charge, Q. Because a precise experimental determination of Γ and Q can be quite tedious, it is, in most cases, convenient to obtain a rough estimate of the relative grafting efficiency simply from a comparison of the peak currents obtained on the first sweep in cyclic voltammetry or from the number of cycles required to completely passivate the electrode surface.
-
-
-
-
20
-
-
34147192646
-
-
p,c and the substituent parameter, σ.
-
p,c and the substituent parameter, σ.
-
-
-
-
21
-
-
23144457013
-
-
(a) Laforgue, A.; Addou, T.; Bélanger, D. Langmuir 2005, 21, 6855.
-
(2005)
Langmuir
, vol.21
, pp. 6855
-
-
Laforgue, A.1
Addou, T.2
Bélanger, D.3
-
24
-
-
34147221391
-
-
Although employment of low concentrations seems to prevent the grafting process, this is not necessarily true. In fact, a partial grafting is not expected to affect the electrochemical response, as long as the diffusion layer thickness is larger than the distance between the underivatized regions of the surface. Under such conditions, the grafted electrode will still behave as a normal disk electrode characterized by its original electrode area and with a square root dependency of the peak current on the sweep rate. On the other hand, a more extensive electrode derivatization will make the surface resemble an array of ultramicroelectrodes, now giving rise to sigmoidal-shaped voltammograms under steady-state conditions. Overall, the dependency of ip,c on v can therefore turn out to be a rather complex function, depending on the progress of the electrode derivatization
-
p,c on v can therefore turn out to be a rather complex function, depending on the progress of the electrode derivatization.
-
-
-
-
25
-
-
34147197316
-
-
The comparison is based on the assumption that both the transfer and diffusion coefficients of the various iodonium and diazonium salts are the same. However, this may turn out to be not completely true,16b considering that the smaller size of the diazonium salts would be expected to result in a relatively larger diffusion coefficient
-
16b considering that the smaller size of the diazonium salts would be expected to result in a relatively larger diffusion coefficient.
-
-
-
-
29
-
-
34147193601
-
-
In preparation
-
Vase, K. H.; Rasmussen, S. W.; Dittmer, J.; Lund, H.; Pedersen, S. U.; Daasbjerg, K. In preparation.
-
-
-
Vase, K.H.1
Rasmussen, S.W.2
Dittmer, J.3
Lund, H.4
Pedersen, S.U.5
Daasbjerg, K.6
-
30
-
-
0031375021
-
-
Saby, C.; Ortiz, B.; Champagne, G. Y.; Bélanger, D. Langmuir 1997, 13, 6805.
-
(1997)
Langmuir
, vol.13
, pp. 6805
-
-
Saby, C.1
Ortiz, B.2
Champagne, G.Y.3
Bélanger, D.4
-
31
-
-
34147212533
-
-
As pointed out by the reviewers, the N/C ratio is a function of the XPS take-off angle and is effected by the underlying carbon framework. However, even if the actual N/C ratio should be significantly higher, the results can still be used for relative comparisons
-
As pointed out by the reviewers, the N/C ratio is a function of the XPS take-off angle and is effected by the underlying carbon framework. However, even if the actual N/C ratio should be significantly higher, the results can still be used for relative comparisons.
-
-
-
-
32
-
-
11844273845
-
-
Combellas, C.; Kanoufi, F.; Pinson, J.; Podvodica, F. I. Langmuir 2005, 21, 280.
-
(2005)
Langmuir
, vol.21
, pp. 280
-
-
Combellas, C.1
Kanoufi, F.2
Pinson, J.3
Podvodica, F.I.4
-
34
-
-
0032155330
-
-
(b) Ortiz, B.; Saby, C.; Champagne, G. Y.; Bélanger, D. J. Electroanal. Chem. 1998, 455, 75.
-
(1998)
J. Electroanal. Chem
, vol.455
, pp. 75
-
-
Ortiz, B.1
Saby, C.2
Champagne, G.Y.3
Bélanger, D.4
-
36
-
-
0034271248
-
-
Liu, J.; Cheng, L.; Liu, B.; Dong, S. Langmuir 2000, 16, 7471.
-
(2000)
Langmuir
, vol.16
, pp. 7471
-
-
Liu, J.1
Cheng, L.2
Liu, B.3
Dong, S.4
-
37
-
-
34147196227
-
-
We cannot exclude that the small content of iodine detected by XPS in these specific cases could originate from the formation of an intermediate iodanyl radical during the grafting mechanism or from the trapping of other iodine-containing species inside the forming films. Another possible source is Bu4NI leaking slowly from the reference electrode
-
4NI leaking slowly from the reference electrode.
-
-
-
|