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(a) Reference 1c and references cited therein.
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For reactions of σ- or π-allyl complexes with molecular oxygen, see; a
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34147122608
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We are not certain whether this intermediate takes the form of the π-allyl or σ-allyl complex; however, we just refer to π-allyl in the text for the simplicity
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We are not certain whether this intermediate takes the form of the π-allyl or σ-allyl complex; however, we just refer to π-allyl in the text for the simplicity.
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30
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34147181073
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In our previous work ref 5, π-allylnickel intermediates formed by oxidative coupling of monosubstituted 1,2-dienes and CO2 easily underwent protonolysis by 1 M aq HCl at rt. The reactivity of π-allylnickel intermediates appears to be dependent on the substitution pattern of 1,2-dienes
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2 easily underwent protonolysis by 1 M aq HCl at rt. The reactivity of π-allylnickel intermediates appears to be dependent on the substitution pattern of 1,2-dienes.
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31
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84978052709
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Papai, I.1
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38
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34147169200
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It is necessary to heat the π-allylnickel intermediate 2 in refluxing HCl-MeOH to cause the protonolysis of this intermediate.
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It is necessary to heat the π-allylnickel intermediate 2 in refluxing HCl-MeOH to cause the protonolysis of this intermediate.
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