Rate coefficients for reaction and for rotational energy transfer in collisions between CN in selected rotational levels (X2 ∑+2, v=2, N=0, 1, 6, 10, 15, and 20) and C2H2

Journal of Chemical Physics

Volumn 126, Issue 13, 2007, Pages

  Olkhov, Rouslan V ^a,b   Smith, Ian W M ^a  

^a UNIVERSITY OF CAMBRIDGE   (United Kingdom)

^b UNIVERSITY OF EXETER   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

FLUORESCENCE; MOLECULAR ORIENTATION; ORGANIC COMPOUNDS; PHOTOLYSIS; PULSED LASER APPLICATIONS; REACTION KINETICS;

INFRARED LASERS; PULSED LASER PHOTOLYSIS; PULSED LASER-INDUCED FLUORESCENCE (PLIF); ROTATIONAL LEVELS;

ENERGY TRANSFER;

EID: 34047273558     PISSN: 00219606     EISSN: None     Source Type: Journal    
DOI: 10.1063/1.2715594     Document Type: Article

References (57)

1. R. D. Levine, Molecular Reaction Dynamics (Cambridge University Press, Cambridge, 2003).
2. A. Gonzalez-Urena, Adv. Chem. Phys. 0065-2385 66, 213 (1987); A. Gonzalez-Urena, J. Phys. Chem. 96, 8212 (1992).
3. A. Gonzalez-Urena, Adv. Chem. Phys. 0065-2385 66, 213 (1987); A. Gonzalez-Urena, J. Phys. Chem. 96, 8212 (1992).
4. K. Liu, Int. Rev. Phys. Chem. 20, 189 (2001).
5. C. B. Moore and I. W. M. Smith, J. Phys. Chem. 0022-3654 10.1021/jp953664h 100, 12848 (1996); F. F. Crim, J. Phys. Chem. 0022-3654 10.1021/jp9604812 100, 12725 (1996); F. F. Crim, Acc. Chem. Res. 32, 877 (1999).
6. C. B. Moore and I. W. M. Smith, J. Phys. Chem. 0022-3654 10.1021/jp953664h 100, 12848 (1996); F. F. Crim, J. Phys. Chem. 0022-3654 10.1021/jp9604812 100, 12725 (1996); F. F. Crim, Acc. Chem. Res. 32, 877 (1999).
7. C. B. Moore and I. W. M. Smith, J. Phys. Chem. 0022-3654 10.1021/jp953664h 100, 12848 (1996); F. F. Crim, J. Phys. Chem. 0022-3654 10.1021/jp9604812 100, 12725 (1996); F. F. Crim, Acc. Chem. Res. 32, 877 (1999).
8. J. C. Polanyi, Acc. Chem. Res. 0001-4842 10.1021/ar50053a001 5, 161 (1972); J. C. Polanyi, Angew. Chem., Int. Ed. 26, 952 (1987).
9. J. C. Polanyi, Acc. Chem. Res. 0001-4842 10.1021/ar50053a001 5, 161 (1972); J. C. Polanyi, Angew. Chem., Int. Ed. 26, 952 (1987).
10. N. Satyhamurthy, Chem. Rev. (Washington, D.C.) 83, 601 (1983).
11. W. Grote, M. Hoffmeister, R. Schleysing, H. Zerhau-Dreihofer, and H. Loesch, in Selectivity in Chemical Reactions, edited by, J. C. Whitehead, (Kluwer, The Hague, 1988), p. 47.
12. H. H. Dispert, M. W. Gels, and P. R. Brooks, J. Chem. Phys. 70, 5317 (1970).
13. F. Heismann and H. J. Loesch, Chem. Phys. 0301-0104 10.1016/0301-0104(82) 85003-9 64, 43 (1982); M. Hoffmeister, L. Potthast, and H. J. Loesch, Chem. Phys. 78, 369 (1983).
14. F. Heismann and H. J. Loesch, Chem. Phys. 0301-0104 10.1016/0301-0104(82) 85003-9 64, 43 (1982); M. Hoffmeister, L. Potthast, and H. J. Loesch, Chem. Phys. 78, 369 (1983).
15. K. G. McKendrick, D. J. Rakestraw, and R. N. Zare, Faraday Discuss. Chem. Soc. 0301-7249 10.1039/dc9878400039 84, 39 (1987); K. G. McKendrick, D. J. Rakestraw, R. Zhang, and R. N. Zare, J. Phys. Chem. 92, 5530 (1988).
16. K. G. McKendrick, D. J. Rakestraw, and R. N. Zare, Faraday Discuss. Chem. Soc. 0301-7249 10.1039/dc9878400039 84, 39 (1987); K. G. McKendrick, D. J. Rakestraw, R. Zhang, and R. N. Zare, J. Phys. Chem. 92, 5530 (1988).
17. D. J. Rakestraw, K. G. McKendrick, and R. N. Zare, J. Chem. Phys. 0021-9606 10.1063/1.453328 87, 7341 (1987); R. Zhang, W. J. van der Zande, and R. N. Zare, J. Chem. Phys. 94, 2704 (1991).
18. D. J. Rakestraw, K. G. McKendrick, and R. N. Zare, J. Chem. Phys. 0021-9606 10.1063/1.453328 87, 7341 (1987); R. Zhang, W. J. van der Zande, and R. N. Zare, J. Chem. Phys. 94, 2704 (1991).
19. B. A. Blackwell, J. C. Polanyi, and J. J. Sloan, Chem. Phys. 30, 299 (1978).
20. H. Loesch, Chem. Phys. 112, 85 (1987).
21. H. Kornweitz, A. Persky, J. Schreiber, and R. D. Levine, Chem. Phys. Lett. 169, 489 (1990).
22. H. Loesch, Chem. Phys. 104, 213 (1986).
23. A. Miklavc, M. Perdih, and I. W. M. Smith, J. Chem. Phys. 112, 8813 (2000).
24. I. W. M. Smith, Angew. Chem., Int. Ed. 45, 2815 (2006).
25. CRESU is a French acronym for cinetique de reactions en ecoulement supersonique uniforme or reaction kinetics in uniform supersonic flows. The method makes use of convergent-divergent Laval nozzles to cool gas mixtures to low temperatures. It was originally developed by B. R. Rowe, and co-workers to study the kinetics of ion-molecule reactions: B. R. Rowe, G. Dupeyrat, J. B. Marquette, and P. Gaucheral, J. Chem. Phys. 0021-9606 10.1063/1.446513 80, 4915 (1984); G. Dupeyrat, J. B. Marquette, and B. R. Rowe, Phys. Fluids 0031-9171 10.1063/1.865010 28, 1273 (1985); B. R. Rowe and J. B. Marquette, Int. J. Mass Spectrom. Ion Process. 80, 239 (1987).
26. CRESU is a French acronym for cinetique de reactions en ecoulement supersonique uniforme or reaction kinetics in uniform supersonic flows. The method makes use of convergent-divergent Laval nozzles to cool gas mixtures to low temperatures. It was originally developed by B. R. Rowe, and co-workers to study the kinetics of ion-molecule reactions: B. R. Rowe, G. Dupeyrat, J. B. Marquette, and P. Gaucheral, J. Chem. Phys. 0021-9606 10.1063/1.446513 80, 4915 (1984); G. Dupeyrat, J. B. Marquette, and B. R. Rowe, Phys. Fluids 0031-9171 10.1063/1.865010 28, 1273 (1985); B. R. Rowe and J. B. Marquette, Int. J. Mass Spectrom. Ion Process. 80, 239 (1987).
27. CRESU is a French acronym for cinetique de reactions en ecoulement supersonique uniforme or reaction kinetics in uniform supersonic flows. The method makes use of convergent-divergent Laval nozzles to cool gas mixtures to low temperatures. It was originally developed by B. R. Rowe, and co-workers to study the kinetics of ion-molecule reactions: B. R. Rowe, G. Dupeyrat, J. B. Marquette, and P. Gaucheral, J. Chem. Phys. 0021-9606 10.1063/1.446513 80, 4915 (1984); G. Dupeyrat, J. B. Marquette, and B. R. Rowe, Phys. Fluids 0031-9171 10.1063/1.865010 28, 1273 (1985); B. R. Rowe and J. B. Marquette, Int. J. Mass Spectrom. Ion Process. 80, 239 (1987).
28. CRESU is a French acronym for cinetique de reactions en ecoulement supersonique uniforme or reaction kinetics in uniform supersonic flows. The method makes use of convergent-divergent Laval nozzles to cool gas mixtures to low temperatures. It was originally developed by B. R. Rowe, and co-workers to study the kinetics of ion-molecule reactions: B. R. Rowe, G. Dupeyrat, J. B. Marquette, and P. Gaucheral, J. Chem. Phys. 0021-9606 10.1063/1.446513 80, 4915 (1984); G. Dupeyrat, J. B. Marquette, and B. R. Rowe, Phys. Fluids 0031-9171 10.1063/1.865010 28, 1273 (1985); B. R. Rowe and J. B. Marquette, Int. J. Mass Spectrom. Ion Process. 80, 239 (1987).
29. For example, W. D. Geppert, D. Reigneur, T. Stoecklin, C. Naulin, M. Costes, D. Chastaing, S. D. LePicard, I. R. Sims, and I. W. M. Smith, Phys. Chem. Chem. Phys. 1463-9076 10.1039/b002583f 2, 2873 (2000); D. Chastaing, S. D. LePicard, I. R. Sims, I. W. M. Smith, W. D. Geppert, C. Naulin, and M. Costes, Chem. Phys. Lett. 331, 170 (2000).
30. For example, W. D. Geppert, D. Reigneur, T. Stoecklin, C. Naulin, M. Costes, D. Chastaing, S. D. LePicard, I. R. Sims, and I. W. M. Smith, Phys. Chem. Chem. Phys. 1463-9076 10.1039/b002583f 2, 2873 (2000); D. Chastaing, S. D. LePicard, I. R. Sims, I. W. M. Smith, W. D. Geppert, C. Naulin, and M. Costes, Chem. Phys. Lett. 331, 170 (2000).
31. D. C. Clary, Mol. Phys. 0026-8976 10.1080/00268978400102101 53, 3 (1984); D. C. Clary, Annu. Rev. Phys. Chem. 0066-426X 10.1146/annurev.physchem.41.1.61 41, 61 (1990); T. Stoecklin, C. E. Dateo, and D. C. Clary, J. Chem. Soc., Faraday Trans. 0956-5000 10.1039/ft9918701667 87, 1667 (1991); T. Stoecklin and D. C. Clary, J. Mol. Struct.: THEOCHEM 341, 53 (1995).
32. D. C. Clary, Mol. Phys. 0026-8976 10.1080/00268978400102101 53, 3 (1984); D. C. Clary, Annu. Rev. Phys. Chem. 0066-426X 10.1146/annurev.physchem.41.1.61 41, 61 (1990); T. Stoecklin, C. E. Dateo, and D. C. Clary, J. Chem. Soc., Faraday Trans. 0956-5000 10.1039/ft9918701667 87, 1667 (1991); T. Stoecklin and D. C. Clary, J. Mol. Struct.: THEOCHEM 341, 53 (1995).
33. D. C. Clary, Mol. Phys. 0026-8976 10.1080/00268978400102101 53, 3 (1984); D. C. Clary, Annu. Rev. Phys. Chem. 0066-426X 10.1146/annurev.physchem.41.1.61 41, 61 (1990); T. Stoecklin, C. E. Dateo, and D. C. Clary, J. Chem. Soc., Faraday Trans. 0956-5000 10.1039/ft9918701667 87, 1667 (1991); T. Stoecklin and D. C. Clary, J. Mol. Struct.: THEOCHEM 341, 53 (1995).
34. D. C. Clary, Mol. Phys. 0026-8976 10.1080/00268978400102101 53, 3 (1984); D. C. Clary, Annu. Rev. Phys. Chem. 0066-426X 10.1146/annurev.physchem.41.1.61 41, 61 (1990); T. Stoecklin, C. E. Dateo, and D. C. Clary, J. Chem. Soc., Faraday Trans. 0956-5000 10.1039/ft9918701667 87, 1667 (1991); T. Stoecklin and D. C. Clary, J. Mol. Struct.: THEOCHEM 341, 53 (1995).
35. E. J. Rackham, F. Huarte-Larranaga, and D. E. Manolopoulos, Chem. Phys. Lett. 0009-2614 10.1016/S0009-2614(01)00707-2 343, 356 (2001); E. J. Rackham, T. Gonzalez-Lezana, and D. E. Manolopoulos, J. Chem. Phys. 119, 12895 (2003).
36. E. J. Rackham, F. Huarte-Larranaga, and D. E. Manolopoulos, Chem. Phys. Lett. 0009-2614 10.1016/S0009-2614(01)00707-2 343, 356 (2001); E. J. Rackham, T. Gonzalez-Lezana, and D. E. Manolopoulos, J. Chem. Phys. 119, 12895 (2003).
37. C. E. Dateo and D. C. Clary, J. Chem. Phys. 0021-9606 10.1063/1.456251 90, 7216 (1989); D. C. Clary, J. Chem. Soc., Faraday Trans. 2 83, 139 (1987).
38. C. E. Dateo and D. C. Clary, J. Chem. Phys. 0021-9606 10.1063/1.456251 90, 7216 (1989); D. C. Clary, J. Chem. Soc., Faraday Trans. 2 83, 139 (1987).
39. Y. Georgievskii and S. J. Klippenstein, J. Chem. Phys. 0021-9606 10.1063/1.1899603 122, 194103 (2005); E. E. Greenwald, S. W. North, Y. Georgievskii, and S. J. Klippenstein, J. Phys. Chem. A 109, 6031 (2005).
40. Y. Georgievskii and S. J. Klippenstein, J. Chem. Phys. 0021-9606 10.1063/1.1899603 122, 194103 (2005); E. E. Greenwald, S. W. North, Y. Georgievskii, and S. J. Klippenstein, J. Phys. Chem. A 109, 6031 (2005).
41. (a) R. Fei, H. M. Lambert, T. Carrington, S. V. Filseth, C. M. Sadowski, and C. H. Dugan, J. Chem. Phys. 0021-9606 10.1063/1.466649 100, 1190 (1994); (b) R. Fei, D. E. Adelman, T. Carrington, C. H. Dugan, and S. V. Filseth, Chem. Phys. Lett. 232, 546 (1995).
42. (a) R. Fei, H. M. Lambert, T. Carrington, S. V. Filseth, C. M. Sadowski, and C. H. Dugan, J. Chem. Phys. 0021-9606 10.1063/1.466649 100, 1190 (1994); (b) R. Fei, D. E. Adelman, T. Carrington, C. H. Dugan, and S. V. Filseth, Chem. Phys. Lett. 232, 546 (1995).
43. (a) K. M. Hickson, C. M. Sadowski, and I. W. M. Smith, Chem. Phys. Lett. 0009-2614 372, 443 (2003); (b) R. V. Olkhov and I. W. M. Smith, Phys. Chem. Chem. Phys. 8, 5643 (2006).
44. (a) K. M. Hickson, C. M. Sadowski, and I. W. M. Smith, Chem. Phys. Lett. 0009-2614 372, 443 (2003); (b) R. V. Olkhov and I. W. M. Smith, Phys. Chem. Chem. Phys. 8, 5643 (2006).
45. I. Nadler, J. Pfab, G. Radhakrishnan, H. Reisler, and C. Wittig, J. Chem. Phys. 0021-9606 10.1063/1.445996 79, 2088 (1983); I. Nadler, J. Pfab, H. Reisler, and C. Wittig, J. Chem. Phys. 81, 553 (1984).
46. I. Nadler, J. Pfab, G. Radhakrishnan, H. Reisler, and C. Wittig, J. Chem. Phys. 0021-9606 10.1063/1.445996 79, 2088 (1983); I. Nadler, J. Pfab, H. Reisler, and C. Wittig, J. Chem. Phys. 81, 553 (1984).
47. I. Nadler, M. Noble, H. Reisler, and C. Wittig, J. Chem. Phys. 82, 2608 (1985).
48. R. Dickinson, G. W. Kirby, J. G. Sweeny, and J. K. Tyler, J. Chem. Soc., Faraday Trans. 2 0300-9238 10.1039/f29787401393 74, 1393 (1978); B. Bak, F. M. Nicolaisen, O. J. Nielsen, and S. Skaarup, J. Mol. Struct. 51, 17 (1979).
49. R. Dickinson, G. W. Kirby, J. G. Sweeny, and J. K. Tyler, J. Chem. Soc., Faraday Trans. 2 0300-9238 10.1039/f29787401393 74, 1393 (1978); B. Bak, F. M. Nicolaisen, O. J. Nielsen, and S. Skaarup, J. Mol. Struct. 51, 17 (1979).
50. L. Herbert, I. W. M. Smith, and R. D. Spencer-Smith, Int. J. Chem. Kinet. 0538-8066 10.1002/kin.550240904 24, 791 (1992); I. R. Sims, J.-L. Queffelec, D. Travers, B. R. Rowe, L. B. Herbert, J. Karthauser, and I. W. M. Smith, Chem. Phys. Lett. 211, 461 (1993).
51. L. Herbert, I. W. M. Smith, and R. D. Spencer-Smith, Int. J. Chem. Kinet. 0538-8066 10.1002/kin.550240904 24, 791 (1992); I. R. Sims, J.-L. Queffelec, D. Travers, B. R. Rowe, L. B. Herbert, J. Karthauser, and I. W. M. Smith, Chem. Phys. Lett. 211, 461 (1993).
52. I. W. M. Smith, J. Chem. Soc., Faraday Trans. 93, 3741 (1997).
53. M. Rubinson and J. I. Steinfeld, Chem. Phys. 4, 467 (1974).
54. M. Quack and J. Troe, Ber. Bunsenges. Phys. Chem. 0005-9021 78, 240 (1974);
55. M. Quack and J. Troe, Ber. Bunsenges. Phys. Chem. 0005-9021 79, 170 (1975);
56. M. Quack and J. Troe, Ber. Bunsenges. Phys. Chem. 0005-9021 79, 469 (1975);
57. M. Quack and J. Troe, Adv. Chem. Phys. 101, 819 (1997).