Cyclodextrin effect on solvolysis of ortho benzoyl chlorides

Journal of Inclusion Phenomena and Macrocyclic Chemistry

Volumn 57, Issue 1-4, 2007, Pages 603-606

  Bascuas J ^a   Garcia Rio L ^a   Leis, J R ^a   Mendez Perez M ^a  

^a UNIVERSITY OF SANTIAGO DE COMPOSTELA   (Spain)

Author keywords

Benzoyl chloride; Cyclodextrins; Inclusion complex; Pseudophase model; Stability constant

Indexed keywords

EID: 34047180986     PISSN: 09230750     EISSN: None     Source Type: Journal    
DOI: 10.1007/s10847-006-9276-x     Document Type: Conference Paper

References (11)

1. Bender, M.L., Komiyama, M.: Cyclodextrin Chemistry, Springer-Verlag, Berlin (1978)
2. Tee, O.S.: The stabilization of transition states by cyclodextrins and other catalysts. Adv. Phys. Org. Chem. 29, 1-85 (1994)
3. Wenz, G.: Cyclodextrins as synthons for supramolecular structures and functional units. Angew. Chem. Int. Ed. Engl. 33, 803-822 (1994)
4. Connors, K.A.: The stability of cyclodextrin complexes in solution. Chem Rev. 97, 1325-1357 (1997)
5. Iglesias, E., Fernández, A.: Cyclodextrin catalysis in the basic hydrolysis of alkyl nitrites. J. Chem. Soc, Perkin Trans. 2, 1691-1700 (1998)
6. Iglesias, E.: Cyclodextrins as enzyme models in nitrosation and in acid-base-catalyzed reactions of alkyl nitrites. J. Am. Chem. Soc. 120, 13057-13069 (1998)
7. García-Río, L., Leis, J.R., Mejuto, J.C., Pérez-Juste, J.: Investigation of micellar media containing β-cyclodextrins by means of reaction kinetics: basic hydrolysis of N-methyl-N-nitroso-p-toluenesulfonamide. J. Phys. Chem. B 101, 7383-7389 (1997)
8. Song, B.D., Jencks, W.P.: Aminolysis of benzoyl fluorides in water. J. Am. Chem. Soc. 111, 8470-8484 (1989)
9. Jencks, W.P.: General acid-base catalysis of complex reactions in water. Chem. Rev. 72, 705-718 (1972)
10. More O'Ferrall, R.A.: Relations between E2 and ElcB mechanisms of β-elimination. J. Chem. Soc. B 274-277 (1970)
11. Báscuas, J., García-Río, L., Leis, J.R.: Cyclodextrin effect on solvolysis of substituted benzoyl chlorides. Org. Biomol. Chem. 2, 1186-1193 (2004)