Mechanism of olefin hydrosilylation catalyzed by [RuCl(NCCH3)5]+: A DFT study

Journal of Organometallic Chemistry

Volumn 692, Issue 11, 2007, Pages 2282-2290

  Tuttle, Tell ^a   Wang, Dongqi ^a   Thiel, Walter ^a   Köhler, Jutta ^b   Hofmann, Marco ^b   Weis, Johann ^b  

^a MAX PLANCK INSTITUT FÜR KOHLENFORSCHUNG   (Germany)

^b Consortium für Elektrochemische Industrie GmbH ^*  (Germany)

Author keywords

Bond metathesis; B3LYP; Chalk Harrod mechanism; Density functional theory; Glaser Tilley mechanism; Hydrosilylation; Ruthenium

Indexed keywords

ACETONITRILE; CATALYSIS; CHEMICAL BONDS; DENSITY FUNCTIONAL THEORY; ENTHALPY; OLEFINS;

CHALK HARROD MECHANISM; GLASER TILLEY MECHANISM; METHYLDIMETHOXYSILANES; OLEFIN HYDROSILYLATION;

HYDROSILYLATION;

EID: 34047161455     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2007.01.060     Document Type: Article

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