Chemoselective derivatization of a bionanoparticle by click reaction and ATRP reaction

Chemical Communications

Volumn , Issue 14, 2007, Pages 1453-1455

  Zeng, Qingbing ^a   Li, Tao ^a   Cash, Brandon ^a   Li, Siqi ^a   Xie, Fang ^a   Wang, Qian ^a  

^a UNIVERSITY OF SOUTH CAROLINA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALKYNE; APOFERRITIN; AZIDE; COPPER; FERRITIN; LYSINE; NANOPARTICLE;

ARTICLE; ATOM TRANSFER RADICAL POLYMERIZATION; CATALYSIS; CATALYST; CHEMICAL REACTION; CYCLOADDITION; DERIVATIZATION; POLYMERIZATION;

EID: 33947645978     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/b617534a     Document Type: Article

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37. -5 mmol) and 9 (518.4 mg, 1.44 mmol) were dissolved in degassed water (200 uL). 400 uL of a catalyst stock solution (obtained by mixing 14.3 mg CuBr, 27.5 mg 2,2′-bipyridine in 4 mL degassed water) was added to start the polymerization. The reaction proceeded under nitrogen for 90 min before the mixture was exposed to air and diluted with 200 uL of water to quench the reaction. The product was purified by dialysis against nanopure water