Radical cyclization of 4-aryl-1-iodobutene derivatives to form dihydronaphthalene scaffold

Tetrahedron Letters

Volumn 48, Issue 17, 2007, Pages 3105-3108

  Gowrisankar, Saravanan ^a   Lee, Hyun Seung ^a   Kim, Jae Nyoung ^a  

^a Chonnam National University   (South Korea)

Author keywords

Allyltributylstannane; Baylis Hillman adducts; Dihydronaphthalene; n Bu3SnH; Radical cyclization

Indexed keywords

BUTANE; IODINE DERIVATIVE; NAPHTHALENE DERIVATIVE; SCAFFOLD PROTEIN; VINYL DERIVATIVE;

ARTICLE; BAYLIS HILLMAN REACTION; CHEMICAL REACTION; CHEMICAL STRUCTURE; CYCLIZATION; SYNTHESIS;

EID: 33947623734     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2007.02.132     Document Type: Article

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25. 3, 75 MHz) δ 14.00 (2C), 38.46, 39.74, 44.62, 51.81, 52.24, 59.63, 61.77, 61.87, 121.73, 125.84, 126.83, 126.97, 127.55, 132.97, 133.61, 142.26, 170.97, ...
26. 3, 300 MHz) δ 2.85 (d, J = 15.3 Hz, 1H), 3.41 (d, J = 15.3 Hz, 1H), 3.60 (s, 3H), 3.76 (d, J = 8.7 Hz, 1H), 4.45 (d, J = 8.7 Hz, 1H), 4.54 (dd, J = 13.8 and 1.8 Hz, 1H), 4.76 (dd, J = 13.8 and 1.8 Hz, 1H), 6.45 (t, J = 1.8 Hz, 1H), 7.06-7.17 (m, 4H).