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See the Supporting Information for a careful discussion of details for the structure determination and spectral assignments of 5
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See the Supporting Information for a careful discussion of details for the structure determination and spectral assignments of 5.
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A reviewer noted that the alkyne-arene conjugation is broken in 6, aiding the formation of 5 for thermodynamic reasons.
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A reviewer noted that the alkyne-arene conjugation is broken in 6, aiding the formation of 5 for thermodynamic reasons.
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The computations were performed on the parent systems lacking the alkyne substituents
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The computations were performed on the parent systems lacking the alkyne substituents.
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Nuckolls has recently published the crystal structure of a planar antiaromatic diazapentacene: Miao, Q.; Nguyen, T. Q.; Someya, T.; Blanchet, G. B.; Nuckolls, C. J. Am. Chem. Soc. 2003, 125, 10284-10287.
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Nuckolls has recently published the crystal structure of a planar antiaromatic diazapentacene: Miao, Q.; Nguyen, T. Q.; Someya, T.; Blanchet, G. B.; Nuckolls, C. J. Am. Chem. Soc. 2003, 125, 10284-10287.
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