Hybrid resins from polyisocyanate/vinyl ester/water glass systems: Structure and properties

European Polymer Journal

Volumn 43, Issue 4, 2007, Pages 1245-1257

  Grishchuk, S ^a   Castella N ^a   Karger Kocsis, J ^a  

^a INSTITUT FÜR VERBUNDWERKSTOFFE GMBH   (Germany)

Author keywords

AFM (atomic force microscopy); Fracture mechanics; Morphology; Network formation; Polyisocyanate; polysilicate; Polyurea; Vinyl ester resin; Water glass

Indexed keywords

ATOMIC FORCE MICROSCOPY; ESTERS; GLASS; POLYSILICON; SCANNING ELECTRON MICROSCOPY; VINYL RESINS;

NETWORK FORMATION; POLYISOCYANATE; POLYMERIC METHYLENE DIPHENYL ISOCYANATE (PMDI); VINYL ESTER RESIN; WATER GLASSES;

HYBRID MATERIALS;

EID: 33947588671     PISSN: 00143057     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.eurpolymj.2007.01.010     Document Type: Article

References (20)

1. In: Nalwa H.S. (Ed). Handbook of organic-inorganic hybrid materials and nanocomposites (2003), American Scientific Publishers, Los Angeles (CA, USA)
2. Utracki L.A. Clay-containing polymeric nanocomposites (2004), Rapra Technology, Shawbury (UK)
3. Kickelbick G. Concepts for the incorporation of inorganic building blocks into organic polymers on a nanoscale. Prog Polym Sci 28 (2003) 83-114
4. In: Stoye D. (Ed). Paints, coatings and solvents (1993), VCH, Weinheim (GER) 94-96
5. US Patent 5 622 999 (to Polinvent Ltd.); 1997.
6. Hungarian Patent Application P 04 01799 (to Polinvent Ltd.); 2004.
7. Jost N., and Karger-Kocsis J. On the curing of a vinylester-urethane hybrid resin. Polymer 43 (2002) 1383-1389
8. Gryshchuk O., Jost N., and Karger-Kocsis J. Toughening of vinylester-urethane hybrid resins by functional liquid nitrile rubbers and hyperbranched polymers. Polymer 43 (2002) 4763-4768
9. Gryshchuk O., Jost N., and Karger-Kocsis J. Toughening of vinylester-urethane hybrid resins through functionalized polymers. J Appl Polym Sci 84 (2002) 672-680
10. Gawdzik B., and Matynia T. Synthesis and modification of epoxy-based divinyl ester resin. J Appl Polym Sci 81 (2001) 2062-2067
11. Karger-Kocsis J., and Gryshchuk O. Morphology and fracture properties of modified bisphenol A and novolac type vinyl ester resins. Appl Polym Sci 100 (2006) 4012-4022
12. Karger-Kocsis J., Gryshchuk O., and Schmitt S. Vinylester/epoxy-based thermosets of interpenetrating network structure: an atomic force microscopic study. J Mater Sci 38 (2003) 413-420
13. Gryshchuk O., and Karger-Kocsis J. Influence of the type of epoxy hardener on the structure and properties of interpenetrated vinyl ester/epoxy resins. J Polym Sci Part A: Chem 42 (2004) 5471-5481
14. Ziaee S., and Palmese G.R. Effects of temperature on cure kinetics and mechanical properties of vinyl-ester resins. J Polym Sci Part B: Phys 37 (1999) 725-744
15. Rey L., Duchet J., Galy J., Sautereau H., Vouagner D., and Carrion L. Structural heterogeneities and mechanical properties of vinyl/dimethacrylate networks synthesized by thermal free radical polymerization. Polymer 43 (2002) 4375-4384
16. Mosiewicki M.A., Schroeder W.F., Leite F.L., Hermann P.S.P., Curvelo A.A.S., Aranguren M.I., et al. AFM fracture surface study of vinylester and unsaturated polyester based thermosets. J Mater Sci 41 (2006) 6154-6158
17. Karger-Kocsis J., Erdélyi S., and Nagy G. Polyurea/vinylester hybrid thermoset resins with in situ produced silicate filler: preparation and static mechanical properties. J Appl Polym Sci 103 (2007) 853-859
18. Erdélyi S., Karger-Kocsis J., and Nagy G. Polyurea resins with in situ produced silicate filler from water glass: static and dynamic mechanical properties. J Marcomol Sci Part B: Phys 46 (2007) 21-31
19. Sperling L.H. Interpenetrating polymer network and related materials (1981), Plenum, New York
20. Czél G., and Czigány T. Development and analysis of new filament wound composite pipes made of glass fiber reinforced 3P resins. Macromol Symp 239 (2006) 232-244