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33947400833
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1 (wR2) = 0.0253 (0.0614) using 4773 (4981) reflections. The non-hydrogen atoms were anisotropically refined. All calculations were performed using the CrystalStructure crystallographic software package.
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1 (wR2) = 0.0253 (0.0614) using 4773 (4981) reflections. The non-hydrogen atoms were anisotropically refined. All calculations were performed using the CrystalStructure crystallographic software package.
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23
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33947368434
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2O (2) in the powder-form was prepared by exposing 1 to n-propanol vapor (11.5 Torr, 82% relative to saturated vapor) for 1 h at room temperature. Anal. Calcd for 2 (%): Cu, 15.1; W, 29.1; C, 27.1; H, 2.0; N. 22.1. Found: Cu, 15.0; W, 29.5; C, 27.3; H, 2.0; N. 22.2. A single crystal of 2 was prepared by slow diffusion method using a mixed solvent of n-propanol and water (1:1 v/v). The XRD patterns of powder-form and crystal-form are completely coincident (Figure S5).
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2O (2) in the powder-form was prepared by exposing 1 to n-propanol vapor (11.5 Torr, 82% relative to saturated vapor) for 1 h at room temperature. Anal. Calcd for 2 (%): Cu, 15.1; W, 29.1; C, 27.1; H, 2.0; N. 22.1. Found: Cu, 15.0; W, 29.5; C, 27.3; H, 2.0; N. 22.2. A single crystal of 2 was prepared by slow diffusion method using a mixed solvent of n-propanol and water (1:1 v/v). The XRD patterns of powder-form and crystal-form are completely coincident (Figure S5).
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-3, T = 90(1) K, S = 1.084. The structure was solved by direct methods and refined on F to R1 (wR2) = 0.0441 (0.1244) using 4350 (5285) reflections. Zeolitic water and n-propanol molecules were isotropically refined. All calculations were performed using the CrystalStructure crystallographic software package.
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-3, T = 90(1) K, S = 1.084. The structure was solved by direct methods and refined on F to R1 (wR2) = 0.0441 (0.1244) using 4350 (5285) reflections. Zeolitic water and n-propanol molecules were isotropically refined. All calculations were performed using the CrystalStructure crystallographic software package.
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