Synthesis and characterization of montmorillonite clays with modulable porosity induced with acids and superacids

Journal of Materials Research

Volumn 22, Issue 3, 2007, Pages 788-800

  Rodríguez, Y Marina Vargas ^a   Beltrán, Hiram I ^b   Vázquez Labastida, Eloy ^c   Linares López, Carlos ^d   Salmón, Manuel ^d  

^a UNIVERSIDAD NACIONAL AUTÓNOMA DE MÉXICO   (Mexico)

^b DEPARTAMENTO DE PROCESOS Y TECNOLOGÍA   (Mexico)

^c INSTITUTO POLITÉCNICO NACIONAL   (Mexico)

^d UNIVERSIDAD NACIONAL AUTÓNOMA DE MÉXICO   (Mexico)

Author keywords

[No Author keywords available]

Indexed keywords

ABSORPTION; ACIDS; CHARACTERIZATION; DRYING; INFRARED SPECTROMETERS; ISOTHERMS; LAMELLAR STRUCTURES; POROSITY; SYNTHESIS (CHEMICAL); X RAY DIFFRACTION ANALYSIS;

MODULABLE POROSITY; PHYSISORPTION ISOTHERMS; POROUS STRUCTURES; SUPERACIDS;

CLAY MINERALS;

EID: 33947253321     PISSN: 08842914     EISSN: None     Source Type: Journal    
DOI: 10.1557/jmr.2007.0098     Document Type: Article

References (60)

1. G.W. Brindley and G. Brown: Crystal Structures of Clay Minerals and Their X-Ray Identification (London Mineralogical Society, London, UK, 1980).
2. D.E. Smith, Y. Wang, A. Chaturvedi, and H.D. Whitley: Molecular simulations of the pressure, temperature, and chemical potential dependencies of clay swelling. J. Phys. Chem. B 110, 20046 (2006).
3. X.D. Liu and X.C. Lu: A thermodynamic understanding of clay-swelling inhibition by potassium ions. Angew. Chem. Int. Ed. Engl. 45, 6300 (2006).
4. S. Karaborni, B. Smit, W. Heidug, J. Urai, and E. van Oort: The swelling of clays: Molecular simulations of the hydration of montmorillonite. Science 271, 1102 (1996).
5. D. Olsewska: Ammonia and water sorption properties of the mineral-layered nanomaterials used as the catalysts for NOx removal from exhaust gases. Catal. Today 114, 326 (2006).
6. R. Issaadi, F. Garin, and C.E. Chitour: Palladium-sulfated zirconium pillared montmorillonite: Catalytic evaluation in light naphtha hydroisomerization reaction. Catal. Today 113, 174 (2006).
7. A. Corma: From microporous to mesoporous molecular sieve materials and their use in catalysis. Chem. Rev. 97, 2373 (1997).
8. A. Galarneau, A. Barodawalla, and T.J. Pinnavaia: Porous clay heterostructures formed by gallery-templated synthesis. Nature 374, 529 (1995).
9. A. Clearfield: Role of ion-exchange in solid-state chemistry. Chem. Rev. 88, 125 (1988).
10. A. Akelah, A. Rehab, E.R. Kenawy, and M.S. Abou Zeid: Catalytic activity of polymer-montmorillonite composites in chemical reactions. J. Appl. Polym. Sci. 101, 1121 (2006).
11. A.C. Balazs, C. Singh, E. Zhulina, and Y. Lyatskaya: Modeling the phase behavior of polymer/clay nanocomposites. Accounts Chem. Res. 32, 651 (1999).
12. J.P. Ferris and G. Ertem: Oligomerization of ribonucleotides on montmorillonite: Reaction of the 5′-phosphorimidazolide of adenosine. Science 257, 1387 (1992).
13. R.Y. Kannan, H.J. Salacinski, P.E. Butler, and A.M. Seifalian: Polyhedral oligomeric silsesquioxane nanocomposites: The next generation material for biomedical applications. Acc. Chem. Res. 38, 879 (2005).
14. S.R. Chitnis and M.M. Sharma: Industrial applications of acid-treated clays as catalysts. React. Funct. Polym. 32, 93 (1997).
15. S. Mikhail, T. Zaki, and L. Khalil: Desulfurization by an economically adsorption technique. Appl. Catal. A-Gen. 227, 265 (2002).
16. B.M. Choudary, M.L. Kantam, and P.L. Santhi: New and eco-friendly options for the production of specialty and fine chemicals. Catal. Today 57, 17 (2000).
17. B. Tyagi, C.D. Chudasama, and R.V. Jasra: Determination of structural modification in acid activated montmorillonite clay by FT-IR spectroscopy. Spectroc. Acta A-Mol. Biomol. Spectr. 64, 273 (2006).
18. J. Madejova, J. Bujdak, M. Janek, and P. Komadel: Comparative FT-IR study of structural modifications during acid treatment of dioctahedral smectites and hectorite. Spectroc. Acta A-Mol. Biomol. Spectr. 54, 1397 (1998).
19. G. Jozefaciuk and G. Bowanko: Effect of acid and alkali treatments on surface areas and adsorption energies of selected minerals. Clays Clay Miner. 50, 771 (2002).
20. T. Shinoda, M. Onaka, and Y. Izumi: Proposed models of mesopore structures in sulfuric acid-treated montmorillonites and K10. Chem. Lett. (Jpn.) 24, 495 (1995).
21. T. Shinoda, M. Onaka, and Y. Izumi: The reason why K10 is an effective promoter for meso-tetraalkylporphyrin synthesis. Chem. Lett. (Jpn.) 24, 493 (1995).
22. J. Ravichandran and B. Sivasankar: Properties and catalytic activity of acid-modified montmorillonite and vermiculite. Clays Clay Miner. 45, 854 (1997).
23. C. Breen, J. Madejova, and P. Komadel: Correlation of catalytic activity with infrared, Si-29 Mas Nmr and acidity data for Hcl-treated fine fractions of montmorillonites. Appl. Clay Sci. 10, 219 (1995).
24. I. Tkac, P. Komadel, and D. Muller: Acid-treated montmorillonites: A study by Si-29 and Al-27 MAS NMR. Clay Miner. 29, 11 (1994).
25. C. Breen, J. Madejova, and P. Komadel: Characterization of moderately acid-treated, size-fractionated montmorillonites using Ir and MAS NMR-spectroscopy and thermal-a analysis. J. Mater. Chem. 5, 469 (1995).
26. H. Arriola, M. Salmon, M. Vargas, J. Soberon, N. Nava, and O.L. Ruiz: Characterization of a few Mexican clays. J. Radioanal. Nucl. Chem. 250, 165 (2001).
27. C.J. Meyers, S.D. Shah, S.C. Patel, R.M. Sneeringer, C.A. Bessel, N.R. Dollahon, R.A. Leising, and E.S. Takeuchi: Templated synthesis of carbon materials from zeolites (Y, β, and ZSM-5) and a montmorillonite clay (K10): Physical and electrochemical characterization. J. Phys. Chem. B 105, 2143 (2001).
28. R. Miranda-Ruvalcaba, G.A. Arroyo Razo, G.P. Carrillo, F.D. Reyes, A.C. Ortiz, C.A. Toledano, and M.S. Salazar: Preparative heterocyclic chemistry using tonsil a bentonitic clay: 1981 to 2003. Trends Heterocycl. Chem. 9, 195 (2003).
29. M. Salmon, E. Angeles, and R. Miranda: Bromine-bentonite earth system, promoter of phenylmethanes from toluene. J. Chem. Soc. Chem. Commun. 1188 (1990).
30. R. Miranda, R. Osnaya, R. Garduno, F. Delgado, C. Alvarez, and M. Salmon: A general alternative to obtain S.S-acetals using TAFF, a bentonitic clay, as the catalyst. Synth. Commun. 31, 1587 (2001).
31. R. Cruz-Almanza, I. Shiba-Matzumoto, A. Fuentes, M. Martinez A. Cabrera, J. Cardenas, and M. Salmon: Oligomerization of benzylic alcohols and its mechanism. J. Mol. Catal. A-Chem. 126, 161 (1997).
32. A. Cabrera, J. Peon, L. Velasco, R. Miranda, A. Salmon, and M. Salmon: Clay-mediated cyclooligomerization of olefin oxides: A one-pot route to crown-ethers. J. Mol. Catal. A-Chem. 104, L5 (1995).
33. M. Vargas, E. Vazquez-Labastida, L. Bautista, J. Cardenas, and M. Salmon: Catalytic synthesis of 1,3,5-triphenylbenzenes, β-methylchalcones and 2,4,6-triphenyl pyrylium salts, promoted by a super acid trifluoromethene sulfonic clay from acetophenones. J. Mexican Chem. Soc. 50, 26 (2006).
34. M. Salmon, G. Penieres, R. Miranda, and C. Alvarez: The action of bentonitic earth on natural product epoxides. J. Heterocycl. Chem. 18, 1475 (1981).
35. M. Salmon, R. Miranda, and E. Angeles: Oxidative cleavage of aldo and keto oximes with chromyl chloride adsorbed on silica and bentonite earth. Synth. Commun. 16, 1827 (1986).
36. M. Salmon, M. PerezLuna, C. LopezFranco, E. Hernandez, R.A. AlvarezRamirez, A. LopezOrtega, and J.M. Dominguez: Catalytic conversion of propylene oxide on a super acid sulfonic clay (SASC) system. J. Mol. Catal. A-Chem. 122, 169 (1997).
37. K.S.W. Sing, D.H. Everett, R.A.W. Haul, L. Moscou, R.A. Pierotti, J. Rouquerol, and T. Siemieniewska: Reporting physisorption data for gas solid systems with special reference to the determination of surface-area and porosity (Recommendations 1984). Pure Appl. Chem. 57, 603 (1985).
38. M.L. Occelli, J.P. Olivier, J.A. Perdigon-Melon, and A. Auroux: Surface area, pore volume distribution, and acidity in mesoporous expanded clay catalysts from hybrid density-functional theory (DFT) and adsorption microcalorimetry methods. Langmuir 18, 9816 (2002).
39. G. Leofanti, M. Padovan, G. Tozzola, and B. Venturelli: Surface area and pore texture of catalysts. Catal. Today 41, 207 (1998).
40. E. Tombacz, M. Szekeres, L. Baranyi, and E. Micheli: Surface modification of clay minerals by organic polyions. Colloid Surf. A-Physicochem. Eng. Asp. 141, 379 (1998).
41. K. Landskron and G.A. Ozin: Periodic mesoporous dendrisilicas. Science 306, 1529 (2004).
42. R.A. Pai, R. Humayun, M.T. Schulberg, A. Sengupta, J.N. Sun, and J.J. Watkins: Mesoporous silicates prepared using preorganized templates in supercritical fluids. Science 303, 507 (2004).
43. D.R. Rolison: Catalytic nanoarchitectures: The importance of nothing and the unimportance of periodicity. Science 299, 1698 (2003).
44. W.T. Tsai, C.W. Lai, and K.J. Hsien: Characterization and adsorption properties of diatomaceous earth modified by hydrofluoric acid etching. J. Colloid Interface Sci. 297, 749 (2006).
45. S.J. Chipera and D.L. Bish: Thermal evolution of fluorine from smectite and kaolinite. Clays Clay Miner. 50, 38 (2002).
46. S.J. Chipera and D.L. Bish: Baseline studies of The Clay Minerals Society Source Clays: Powder x-ray diffraction analyses. Clays Clay Miner. 49, 398 (2001).
47. R. Miranda, A. Escobar, F. Delgado, M. Salmon, and A. Cabrera: Catalytic promotion of piperonyl alcohol to trimethylendioxyor-thocyclophane by bentonitic earth, or by hydrochloric acid. J. Mol. Catal. A-Chem. 150, 299 (1999).
48. J. Madejova and P. Komadel: Baseline studies of The Clay Minerals Society Source Clays: Infrared methods. Clays Clay Miner. 49, 410 (2001).
49. E.L. Crepaldi, P.C. Pavan, J. Tronto, and J.B.A. Valim: Chemical, structural, and thermal properties of Zn(II)-Cr(III) layered double hydroxides intercalated with sulfated and sulfonated surfactants. J. Colloid Interface Sci. 248, 429 (2002).
50. C.A. Weiss, S.P. Altaner, and R.J. Kirkpatrick: High-resolution Si-29 NMR-spectroscopy of 2-1 layer silicates: Correlations among chemical-shift, structural distortions, and chemical variations. Am. Miner. 72, 935 (1987).
51. E. Lippmaa, M. Magi, A. Samoson, G. Engelhardt, and A.R. Grimmer: Structural studies of silicates by solid-state high-resolution Si-29 NMR. J. Am. Chem. Soc. 102, 4889 (1980).
52. J.F. Stebbins: NMR evidence for 5-coordinated silicon in a silicate glass at atmospheric-pressure. Nature 351, 638 (1991).
53. J.F. Stebbins: Identification of multiple structural species in silicate-glasses by Si-29 NMR. Nature 330, 465 (1987).
54. D. Mueller, D. Hoebbel, and W. Gessner: Al-27 NMR-studies of aluminosilicate solutions: Influences of the 2nd coordination sphere on the shielding of aluminum. Chem. Phys. Lett. 84, 25 (1981).
55. T. Ohkubo, K. Kanehashi, K. Saito, and Y. Ikeda: Observation of two 4-coordinated Al sites in montmorillonite using high magnetic field strength Al-27 MQMAS NMR. Clays Clay Miner. 51, 513 (2003).
56. P.F. Barron, P. Slade, and R.L. Frost: Ordering of aluminum in tetrahedral sites in mixed-layer 2-1 phyllosilicates by solid-state high-resolution NMR. J. Phys. Chem. 89, 3880 (1985).
57. P.F. Barron, P. Slade, and R.L. Frost: Solid-state Si-29 spin-lattice relaxation in several 2-1 phyllosilicate minerals. J. Phys. Chem. 89, 3305 (1985).
58. R.F. Mortlock, A.T. Bell, and C.J. Radke: P-31 and Al-27 NMR investigations of highly acidic, aqueous-solutions containing aluminum and phosphorus. J. Phys. Chem. 97, 767 (1993).
59. H.M. Kao and Y.C. Chen: Al-27 and F-19 solid-state NMR studies of zeolite H-β dealuminated with ammonium hexafluorosilicate. J. Phys. Chem. B 107, 3367 (2003).
60. M.E. Smith: Application of Al-27 NMR techniques to structure determination in solids. Appl. Magn. Reson. 4, 1 (1993).