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Volumn , Issue 4, 2007, Pages 543-546

Cyanation of aryl chlorides with potassium hexacyanoferrate(II) catalyzed by cyclopalladated ferrocenylimine tricyclohexylphosphine complexes

Author keywords

Aryl chloride; Catalysis; Coupling; Cyanation; Cyclopalladium

Indexed keywords

4 CHLOROTOLUENE; ARYL CHLORIDE DERIVATIVE; CHLORINE DERIVATIVE; FERROCENYLIMINE TRICYCLOHEXYLPHOSPHINE COMPLEX; FERROCYANIDE; PALLADIUM COMPLEX; PHOSPHINE DERIVATIVE; POTASSIUM; TOLUENE DERIVATIVE; UNCLASSIFIED DRUG;

EID: 33947235315     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2007-970741     Document Type: Article
Times cited : (36)

References (21)
  • 19
    • 33947250374 scopus 로고    scopus 로고
    • General Procedure. A reaction vessel was charged with 1 mmol Na2CO3, 0.22 mmol K4[Fe(CN)6] ·3H2O and 2% mol catalyst 2a. The vessel was then evacuated and backfilled with N2 four times. Then, 1 mmol aryl chloride in 1 mL NMP was added to the vessel. The mixture was heated at 140°C for 16-24 h. The suspension was cooled down to r.t, diluted with 5 mL CH2Cl2 and washed with 5 mL H2O. The aqueous layer was extracted twice with CH2Cl2 (3 mL) and the combined organic layers were dried over MgSO4. After evaporation of the solvents the residue was subjected to TLC (hexane-EtOAc, All prepared compounds were known and identified by 1H NMR, 13C NMR and MS. Selected Data. Compound 4c: 1H NMR (400 MHz, CDCl3, δ, 2.53 (s, 6 H, 7.11 (d, J, 7.7 Hz, 2 H, 7.34 dd, J
    • +.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.