Reverse photochromic behavior of an iron-magnesium complex

Inorganic Chemistry

Volumn 46, Issue 4, 2007, Pages 1039-1041

  Kobayashi, Minoru ^a,b   Takashima, Akito ^c   Ishii, Tomohiko ^c   Naka, Hiroshi ^d   Uchiyama, Masanobu ^e   Yamaguchi, Kentaro ^a,b  

^a TOKUSHIMA BUNRI UNIVERSITY   (Japan)

^b JAPAN SCIENCE AND TECHNOLOGY AGENCY   (Japan)

^c KAGAWA UNIVERSITY   (Japan)

^d TOHOKU UNIVERSITY   (Japan)

^e INST OF PHYS AND CHEMICAL RESEARCH   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

BROMINE; FERROUS ION; FURAN DERIVATIVE; IRON; MAGNESIUM; ORGANOMETALLIC COMPOUND;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; DIMERIZATION; MATERIALS TESTING; PHOTOCHEMISTRY; ULTRAVIOLET SPECTROPHOTOMETRY;

BROMINE; DIMERIZATION; FERROUS COMPOUNDS; FURANS; IRON; MAGNESIUM; MATERIALS TESTING; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; PHOTOCHEMISTRY; SPECTROPHOTOMETRY, ULTRAVIOLET;

EID: 33847760754     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic0616986     Document Type: Article

References (31)

1. (a) Balzani, V.; Credi, A.; Raymo, F. M.; Stoddart, J. F. Angew. Chem., Int. Ed. 2000, 39, 3348-3391.
2. (b) Raymo, F. M.; Tomasulo, M. Chem. Soc. Rev. 2005, 34, 327-336.
3. Wald, G. Science 1968, 162, 230-239.
4. Special issues on π-conjugated photochromic materials can be found in: Chem. Rev. 2000, 100.
5. Yamase, T. Chem. Rev. 1998, 98, 307-325.
6. Gutlich, P.; Garcia, Y.; Goodwin, H. A. Chem. Soc. Rev. 2000, 29, 419-427.
7. (a) Martin, R.; Fürstner, A. Angew. Chem., Int. Ed. 2004, 43, 3955-3957.
8. (b) Nakamura, M.; Matsuo, K.; Ito, S.; Nakamura, E. J. Am. Chem. Soc. 2004, 126, 3686-3687.
9. (c) Bolm, C.; Legros, J.; Paih, J.; Zani, L. Chem. Rev. 2004, 104, 6217-6254.
10. (d) Bedford, R. B.; Betham, M.; Bruce, D. W.; Danopoulos, A. A.; Frost, R. M.; Hird, M. J. Org. Chem. 2006, 71, 1104-1110.
11. (e) Fürstner, A.; Krause, H.; Lehmann, C. W. Angew. Chem., Int. Ed. 2006, 45, 440-444.
12. (a) Sobota, P.; Pluzinski, T.; Lis, T. Polyhedron 1984, 3, 45-47.
13. (b) Smith, P. D.; Martin, J. L.; Huffman, J. C.; Bansemer, R. L.; Caulton, K. G. Inorg. Chem. 1985, 24, 2997-3002.
14. (c) Hitchcock, P. B.; Lee, T. H.; Leigh, G. J. Inorg. Chim. Acta 2003, 348, 199-204.
15. The time response of UV-vis spectra, measured at intervals of 30 min after dissolution, is shown in the Supporting Information.
16. The UV irradiations were carried out using the light of a 150 W tungsten-xenon source equipped with cutoff filters to pass the 365 nm wavelength.
17. II redox wave at -0.37 and -0.35 V (vs ferrocenium/ferrocene), respectively. (See the Supporting Information for details.)
18. (a) Goodman, B. A.; Raynor, J. B. In Advances in Inorganic Chemistry and Radiochemistry; Emeleus, H. J., Sharpe, A. G., Eds.; Academic Press: New York, 1970.
19. (b) Bolton, J. R. In Biological Applications of Electron Spin Resonance; Swartz, H. M., Bolton, J. R., Borg, D. C., Eds.; John Wiley and Sons: New York, 1972.
20. The low-lying 30 excited states of 1a (theoretical model for 1) were computed using TDDFT (TD-B3LYP//UB3LYP/TZVP for iron and bromine; 6-31+G* for others). No significant oscillator strength was detected (wavelengths from 3454 to 267 nm). (See the Supporting Information for details.)
21. (a) Bel'skii, V. K.; Ishchenko, V. M.; Bulychev, B. M.; Protskii, A. N.; Soloveichik, G. L.; Ellert, O. G.; Seifulina, Z. M.; Rakitin, Yu. V.; Novotortsev, V. M. Inorg. Chim. Acta 1985, 96, 123-127.
22. (b) Turner, J. W.; Schultz, F. A. Inorg. Chem. 2001, 40, 5296-5298.
23. (c) Gibson, V. C.; O'Reilly, R. K.; Wass, D. F.; White, A. J. P.; Williams, D. J. Dalton Trans. 2003, 2824-2830.
24. (a) Toney, J.; Stucky, G. D. J. Organomet. Chem. 1971, 28, 5-20.
25. (b) Cotton, F. A.; Luck, R. L.; Son, K. Inorg. Chim. Acta 1991, 179, 11-15.
26. (c) Sobota, P.; Olejnik, Z.; Utko, J.; Lis, T. Polyhedron 1993.
27. (a) Evans, D. F. J. Chem. Soc. 1959, 2003-2005.
28. (b) Evans, D. F.; Fazakerley, G. V.; Phillips, R. F. J. Chem. Soc. 1971, 1931-1934.
29. (c) Grant, G. H. J. Chem. Educ. 1995, 72, 39-40.
30. (d) Naklicki, M. L.; White, C. A.; Plante, L. L.; Evans, C. E. B.; Crutchley, R. J. Inorg. Chem. 1998, 37, 1880-1885.
31. The nonrelativistic DV-Xα calculations were performed with a Slater exchange parameter, α, of 0.7 for all atoms and with 29000 and 9000 DV sampling points, respectively. (See the Supporting Information for details.)