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Volumn 23, Issue 5, 2007, Pages 2623-2630

Fluorinated polar heads can strikingly increase or invert the dipole moments at the Langmuir monolayer-water boundary: Possible effects from headgroup conformations

Author keywords

[No Author keywords available]

Indexed keywords

DIPOLE MOMENT; LIPIDS; MOLECULAR DYNAMICS; NANOSTRUCTURED MATERIALS; POLYAMIDES; X RAY DIFFRACTION ANALYSIS;

EID: 33847748665     PISSN: 07437463     EISSN: None     Source Type: Journal    
DOI: 10.1021/la063135c     Document Type: Article
Times cited : (9)

References (69)
  • 13
    • 0003218719 scopus 로고
    • Influence of charges and dipoles on macromolecular adsorption and permeability
    • DiSalvo, E. A, Simon, S. A, Eds, CRC Press: Boca Raton, FL
    • Cafiso, D. S. Influence of charges and dipoles on macromolecular adsorption and permeability. In Permeability and Stability of Lipid Bilayers; DiSalvo, E. A., Simon, S. A., Eds.; CRC Press: Boca Raton, FL, 1995.
    • (1995) Permeability and Stability of Lipid Bilayers
    • Cafiso, D.S.1
  • 19
    • 33847744083 scopus 로고    scopus 로고
    • 1,2,18 to stress that it originates from the dipoles introduced by the amphiphiles at the interface.
    • 1,2,18 to stress that it originates from the dipoles introduced by the amphiphiles at the interface.
  • 38
    • 33847706337 scopus 로고    scopus 로고
    • MNDO. MOPAC (version 5.0) QCPE, No. 455, 1989
    • (a) MNDO. MOPAC (version 5.0) QCPE, No. 455, 1989.
  • 52
    • 33847720874 scopus 로고    scopus 로고
    • m for the N-ethyl amide monolayer agrees well with ΔV= +290 mV reported years ago by Mitchell for monolayers of the methyl amide of stearic acid at pH 6.0. (Mitchell, J. S. Tabulae Biolojicae 1939, 19, 276.)
    • m for the N-ethyl amide monolayer agrees well with ΔV= +290 mV reported years ago by Mitchell for monolayers of the methyl amide of stearic acid at pH 6.0. (Mitchell, J. S. Tabulae Biolojicae 1939, 19, 276.)
  • 53
    • 33847710136 scopus 로고    scopus 로고
    • Preliminary GIXD data for fea and ea monolayers.
    • Preliminary GIXD data for fea and ea monolayers.
  • 58
    • 33646416475 scopus 로고    scopus 로고
    • and the references cited therein
    • Berkowitz, M. L.; Bostick D. L.; Pandit, S. Chem. Rev. 2006, 106, 1527-1539 (and the references cited therein).
    • (2006) Chem. Rev , vol.106 , pp. 1527-1539
    • Berkowitz, M.L.1    Bostick, D.L.2    Pandit, S.3
  • 64
    • 33847747643 scopus 로고    scopus 로고
    • This result is not as obvious as usually assumed, because the CF 3 group in the trifluoromethylalkanes decreases their lipophilicity due to the strong Cδ+-CF3δ- dipoles.57 On the other side, the CF3CH2OH is considerably more lipophilic than CH3CH2OH cf. Table 6 in ref 57
    • 2OH (cf. Table 6 in ref 57).
  • 67
    • 33847746494 scopus 로고    scopus 로고
    • ∥ is based on the atomic point charges of energetically optimized molecular geometries but also accounts for hybridization effects which sometimes yield up to 50% of the dipole moment. Details of this procedure are given in ref 25.
    • ∥ is based on the atomic point charges of energetically optimized molecular geometries but also accounts for hybridization effects which sometimes yield up to 50% of the dipole moment. Details of this procedure are given in ref 25.
  • 69
    • 33847760125 scopus 로고
    • Ebashi, S, Koch, M, Rubenstein, E, Eds, Elsevier Science Publishers: Amsterdam, Chapter 1, pp
    • Als-Nielsen, J.; Moehwald, H. Handbook on Synchrotron Radiation; Ebashi, S., Koch, M., Rubenstein, E., Eds.; Elsevier Science Publishers: Amsterdam, 1991; Vol. 4, Chapter 1, pp 26, 42.
    • (1991) Handbook on Synchrotron Radiation , vol.4
    • Als-Nielsen, J.1    Moehwald, H.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.