Recent advances and future aspects in the selective isomerization of high n-alkanes

Catalysis Reviews - Science and Engineering

Volumn 49, Issue 1, 2007, Pages 33-139

  Akhmedov, Vagif ^a   Al Khowaiter, Soliman ^a  

^a KING ABDULAZIZ CITY FOR SCIENCE AND TECHNOLOGY   (Saudi Arabia)

Author keywords

High n alkanes; Hydrocracking; Isomerization; Molecular sieves; Shape selectivity; Solid acids; Waxy n paraffins; Zeolite base catalysts; Zirconia based catalysts

Indexed keywords

ADSORPTION; CATALYST SELECTIVITY; HYDROCRACKING; ISOMERIZATION; ZEOLITES; ZIRCONIA;

HYDROCONVERSION; SELECTIVE ISOMERIZATION;

PARAFFINS;

EID: 33847175602     PISSN: 01614940     EISSN: 15205703     Source Type: Journal    
DOI: 10.1080/01614940601128427     Document Type: Review

References (409)

1. Roren, E. (2005) Walk the talk, day in, day out. Fundamentals of the Global Oil and Gas Industry, p. 14. The Petroleum Economist Ltd., London
2. Gary, J. H. and Handwerk, G. E. (2001) Petroleum Refining Technology and Economics, Marcel Dekker, Inc., New-York
3. Kaufmann, T. G., Kaldor, A., Stuntz, G. F., Kerby, M. C. and Ansell, L. L. (2000) Catalysis science and technology for cleaner transportation fuels. Catal. Today, 62, pp. 77-90.
4. Rossini, S. (2003) The impact of catalytic materials on fuel reformulation. Catal. Today, 77, pp. 467-484.
5. Chen, N. Y., Gorring, R. L., Ireland, H. R. and Stein, T. R. (1977) New process cuts pour points of distillates. Oil Gas J., 75, pp. 165-170.
6. Beiden, D. H. Isomerization of saturated hydrocarbons.
7. Krane, H. G. and Kane, E. W. (1957) Isomate process of the Standard Oil Co. of Indiana. Petroleum Refiner, 36:5, pp. 177-183.
8. Evans, H. D., Fountain, E. B., Reveal, W. S. and Ross, W. E. (1961) Shell's liquid phase isomerization process. Hydrocarbon Processing and Petroleum Refiner, 40, pp. 171-174.
9. Maxwell, I. E., Minderhoud, J. K., Stork, W. H.J. and Van Veen, J. A.R. (1997) Hydroconversion and Catalytic dewaxing. Handbook of Heterogeneous Catalysis, 4, pp. 2017-2038. VCH, Wiley, Weinheim
10. Schmidt, R. J., Weiszmann, J. A. and Johnson, J. A. (1985) Catalysts-key to low-cost isomerization. Oil Gas J., 27, pp. 80-85.
11. Kouwenhoven, H. W. and Laughout, W. C. Van Zijll (1971) Shell's hydroisomerization process. Chem. Eng. Progr., 67, pp. 65-70.
12. Meyers, R. A. (1997) Handbook of Petroleum Refining Processes, p. 47. McGraw-Hill, Inc., New-York
13. 2 catalyst for isomerization of light naphtha. Catal. Today, 81, pp. 57-63.
14. Weyda, H. and Kohler, E. (2003) Modern refining concepts - an update on naphtha isomerization to modern gasoline manufacture. Catal. Today, 81, pp. 51-55.
15. Marcilly, C. (2003) Present status and future trends in catalysis for refining and petrochemicals. J. Catal., 216, pp. 47-62.
16. Smith, K. W., Starr, W. C. and Chen, N. Y. (1980) New process dewaxes lube base stoks. Oil Gas J., 78, pp. 75-78.
17. Chen, N. Y., Garwood, W. E. and Dwyer, F. G. (1989) Shape selective catalysis in industrial applications. Chem. Ind. Ser., p. 303. Marcel Dekker, Inc., New York
18. Free, H. W. Homan, Schockaert, T. and Sonnemans, J. W.M. (1993) Akzo-Fina cold flow improvement process. Fuel Process. Technol., 35, pp. 111-117.
19. Bull, S. and Marmin, A. (1979) Lube oil manufacture by severe hydrotreatment. Proc. of the 10th Petroleum Cong. Heyden & Sons, 4, pp. 221-228. Heyden & Sons, Bucharest, London
20. Miller, S. J. (1994) New molecular sieve process for lube dewaxing by wax isomerization. Micropor. Mater., 2, pp. 439-449.
21. Lahn, G. C., Bauman, R. F., Eisenberg, B. and Hochman, J. M. (1992) Syngas production and conversion. Europian Applied Conference of Natural gas, Eurogas- 92, Trondheim, Norway
22. Condon, F. E. (1958) Catalytic isomerization of hydrocarbons. Catalysis, 6, pp. 43-189. Reinhold, New York
23. Sie, S. T. (1997) Isomerization reactions. Handbook of Heterogeneous Catalysis, 4, pp. 1998-2017. VCH, Wiley, Weinheim
24. Yadav, G. D. and Nair, J. J. (1999) Sulfated zirconia and its modified versions as promising catalysts for industrial processes. Micropor. Mesopor. Mater., 33, pp. 1-48.
25. Ono, Y. (2003) A survey of the mechanism in catalytic isomerization of alkanes. Catal. Today, 81, pp. 3-16.
26. Deldari, H. (2005) Suitable catalysts for hydroisomerization of long-chain normal paraffins. Appl. Catal. A, 293, pp. 1-10.
27. Chica, A. and Corma, A. (1999) Hydroisomerization of pentane, hexane, and heptane for improving the octane number of gasoline. J. Catal., 187, pp. 167-176.
28. Sing, K. S.W., Everett, D. H., Haul, R. A.W., Moscou, L., Pierotti, R. A., Rouquerol, J. and Siemieniewska, T. (1985) Physisorption data for gas/solid systems for the determination of surface area and porosity. Pure Appl. Chem., 57, pp. 603-619.
29. Maxwell, I. E. (1987) Zeolite catalysis in hydroprocessing technology. Catal. Today, 1, pp. 385-413.
30. Gosling, C., Gosling, C., Gembicki, V. A., Gatan, R., Cavanna, A., Molinari, D. and Baldiraghi, F. (2004) Refining: Refinery oxidative desulphurization. Petrol. Technol. Quart., 9, pp. 27-31.
31. Corma, A. (2003) State of the art and future challenges of zeolites as catalysts. J. Catal., 216, pp. 298-312.
32. Liu, Y. and Pinnavaia, Th. J. (2003) Aluminosilicate nanoparticles for catalytic hydrocarbon cracking. J. Am. Chem. Soc., 125, pp. 2376-2377.
33. Lercher, J. A. and Jentys, A. (2002) Handbook of Porous Solids, p. 2017. Willey-VCH, Weinheim
34. Guisnet, M., Alvarez, G., Gianetto, G. and Perot, G. (1987) Hydroisomerization and hydrocracking of n-heptane on Pt zeolites. Catal. Today, 1, pp. 415-433.
35. Henriques, C., Dufresne, P., Marcilly, C. and Ribeiro, F. R. (1986) Influence of tin on the stability of Sn/Pd HY zeolites in the hydrocracking and hydroisomerization of n-heptane. Appl. Catal., 21, pp. 169-177.
36. Akhmedov, V. M. and Klabunde, K. J. (1988) High-activity Re-Pt/MO catalysts for C-C bond cleavage reactions: Preparation by solvated metal atom dispersion (SMAD). J. Mol. Catal., 45, pp. 193-206.
37. Martens, J. A., Jacobs, P. A. and Weitkamp, J. (1986) I qualitative description of the primary hydrocracking modes of long chain paraffins in open zeolites. Appl. Catal., 20, pp. 239-281.
38. Carvill, B. T., Lerner, B. A., Adelman, B. J., Tomczak, D. C. and Sachtler, W. M. (1993) Effect of reduction temperature on heptane conversion over platinum supported in H-mordenite. J. Catal., 144, pp. 1-8.
39. Blomsma, E., Martens, J. A. and Jacobs, P. A. (1995) Reaction mechanisms of isomerization and cracking of heptane on Pd/H-Beta zeolite. J. Catal., 155, pp. 141-147.
40. Blomsma, E., Martens, J. A. and Jacobs, P. A. (1996) Mechanisms of heptane isomerization on bifunctional Pd/H-Beta Zeolites. J. Catal., 159, pp. 323-331.
41. Remy, M. J., Stanica, D., Poncelet, G., Feijen, E. J.P., Grobet, P. J., Martens, J. A. and Jacobs, P. A. (1996) Dealuminated H-Y zeolites: relation between physicochemical properties and catalytic activity in heptane and decane isomerization. J. Phys. Chem., 100, pp. 12440-12447.
42. Chao, K. J., Wu, H. C. and Leu, L. J. (1996) Hydroisomerization of light normal paraffins over series of platinum-loaded mordenite and beta catalysts. Appl. Catal. A, 143, pp. 223-243.
43. Wang, Z. B., Kamo, A., Yoneda, T., Komatsu, T. and Yashima, T. (1997) Isomerization of n-heptane over Pt-loaded zeolite β catalysts. Appl. Catal. A, 159, pp. 119-132.
44. Van, R. Mao Le and Saberi, M. A. (2000) Catalysts for the hydroisomerization of n-heptane, prepared according to the concept of 'triangular' site configuration. Appl. Catal. A, 199, pp. 99-107.
45. Meloni, D., Martin, D. and Guisnet, M. (2001) Acidic and catalytic properties of H-MCM-22 zeolites. Appl. Catal. A, 215, pp. 67-79.
46. 7 hydrocarbons. Appl. Catal. A, 233, pp. 45-62.
47. Chao, K., Lin, C.-C., Lin, C.-H., Wu, H., Tseng, C. and Chen, S. (2000) n-Heptane hydroconversion on platinum-loaded mordenite and beta zeolites: The effect of reaction pressure. Appl. Catal. A, 203, pp. 211-220.
48. Akhmedov, V. M., Al-Khowaiter, S. H., Akhmedov, E. and Sadikhov, A. (1999) Low temperature hydrocracking of hydrocarbons on Ni-supported catalysts. Appl. Catal. A, 181, pp. 51-61.
49. Akhmedov, V. M. and Al-Khowaiter, S. H. (2000) Hydroconversion of hydrocarbons over Ru-containing supported catalysts prepared by metal vapor method. Appl. Catal. A, 197, pp. 201-212.
50. 8 alkanes over Zr-containing supported catalysts prepared by metal vapor method. Appl. Catal. A, 252, pp. 353-361.
51. Lugstein, A., Jentys, A. and Vinek, H. (1997) Hydroconversion of n-heptane over Co/Ni containing HZSM5. Appl. Catal. A, 152, pp. 93-105.
52. Lugstein, A., Jentys, A. and Vinek, H. (1998) Hydroconversion of n-heptane over bifunctional HZSM5 zeolites influence of the metal concentration and distribution on the activity and selectivity. Appl. Catal. A, 166, pp. 29-38.
53. 7 n-alkanes on unidirectional large pore zeolites: Activity, selectivity and adsorption features. Catal. Today, 65, pp. 101-110.
54. Patrigeon, A., Bennazi, E., Travers, Ch. and Bernhard, J. Y. (2001) Influence of the zeolite structure and acidity on the hydroisomerization of n-heptane. Catal. Today, 65, pp. 149-155.
55. 8 isomers on Ni-containing zeolites. Appl. Catal. A, 176, pp. 119-128.
56. Zhang, W. and Smirniotis, P. G. (1999) Effect of Zeolite structure and acidity on the product selectivity and reaction mechanism for n-octane hydroisomerization and hydrocracking. J. Catal., 182, pp. 400-416.
57. De Lucas, A., Valverde, J. L., Sánchez, P., Dorado, F. and Ramos, M. J. (2005) Hydroisomerization of n-octane over platinum catalysts with or without binder. Appl. Catal. A, 282, pp. 15-24.
58. De Lucas, A., Sánchez, P., Dorado, F., Ramos, M. J. and Valverde, J. L. (2005) Effect of the metal loading in the hydroisomerization of n-octane over beta agglomerated zeolite based catalysts. Appl. Catal. A, 294, pp. 215-225.
59. Kuznetsov, N. P. (2003) Study of n-octane hydrocracking and hydroisomerization over Pt/HY zeolites using the reactors of different configurations. J. Catal., 218, pp. 12-23.
60. Kinger, G. and Vinek, H. (2001) n-Nonane hydroconversion on Ni and Pt containing HMFI, HMOR and HBEA. Appl. Catal. A, 218, pp. 139-150.
61. Steijns, M., Froment, G., Jacobs, P., Uytterhoeven, J. and Weitkamp, J. (1981) Product distributions from n-decane and n-dodecane. Ind. Eng. Chem. Prod. Res. Dev., 20, pp. 654-660.
62. Girgis, M. J. and Tsao, Y. P. (1996) Impact of catalyst metal-acid balance in n-hexadecane hydroisomerization and hydrocracking. Ind. Eng. Chem. Res., 35, pp. 386-396.
63. Park, K. and Ihm, S. (2000) Comparison of Pt/zeolite catalysts for n-hexadecane hydroisomerization. Appl.Catal. A, 203, pp. 201-209.
64. Akhmedov, V. M. and Al-Khowaiter, S. H. (2005) Novel catalyst design for selective conversion of alkanes under mild conditions. Shaping the Energy Future: Partners in Sustainable Solutions 18th World Petroleum Congress, 18th World Petroleum Congress, Johannesburg, South Africa
65. Martens, J. A. and Jacobs, P. A. (1993) Evidence for hypocage catalysis in FAU/ EMT zeolites derived from isomerisation and hydrocracking of heptadecane. J. Mol. Catal., 78, pp. L47-L52.
66. Martens, J. A., Souverijns, W., Verrelst, W., Parton, R., Froment, G. F. and Jacobs, P. A. (1995) Selective isomerization of hydrocarbon chains on external surfaces of zeolite crystals. Angew. Chem. Int. Ed., 34, pp. 2528-2530.
67. Arroyo, J. A. Munoz, Martens, G. G., Froment, G. F., Marin, G. B., Jacobs, P. A. and Martens, J. A. (2000) Hydrocracking and isomerization of n-paraffin mixtures and a hydrotreated gasoil on Pt/ZSM-22. Appl. Catal. A, 192, pp. 9-22.
68. Souverijns, W., Martens, J. A., Froment, G. F. and Jacobs, P. A. (1998) Hydrocracking of isoheptadecanes on Pt/H-ZSM-22: An example of pore mouth catalysis. J. Catal., 174, pp. 177-184.
69. Claude, M. C. and Martens, J. A. (2000) Monomethyl-branching of long n-alkanes in the range from decane to tetracosane on Pt/H-ZSM-22 bifunctional catalyst. J. Catal., 190, pp. 39-48.
70. Claude, M. C., Vanbutsele, G. and Martens, J. A. (2001) Dimethyl branching of long n-alkanes in the range from decane to tetracosane on Pt/H-ZSM-22 bifunctional catalyst. J. Catal., 203, pp. 213-231.
71. Parulekar, V. N. and Nightower, J. W. (1987) Hydroisomerization of n-paraffins on a platinum rhenium/pillared clay mineral catalyst. Appl. Catal., 35, pp. 249-262.
72. Doblin, C., Mathews, J. F. and Turney, T. W. (1991) Hydrocracking and isomerization of n-octan and 2,2,4-trimethylpentane over a platinum/ alumina-pillared clay. Appl. Catal., 70, pp. 197-212.
73. Molina, R., Moreno, S., Vieira-Coelho, A., Martens, J. A., Jacobs, P. A. and Poncelet, G. (1994) Hydroisomerization-hydrocracking of decane over Al- and Ga-pillared clays. J. Catal., 148, pp. 304-314.
74. Jimenez, C., Romero, F. J., Roldán, R., Marinas, J. M. and Gómez, J. P. (2003) Hydroisomerization of a hydrocarbon feed containing n-hexane, n-heptane and cyclohexane on zeolite-supported platinum catalysts. Appl. Catal. A, 249, pp. 175-185.
75. 7 alkanes and their mixtures over platinum containing mordenite. Appl. Catal. A, 229, pp. 93-102.
76. Steijns, M. and Froment, G. (1981) Kinetic analysis of rate data for n-decane and n-dodecane. Ind. Eng. Chem. Prod. Res. Dev., 20, pp. 660-668.
77. Denayer, J. F., Baron, G. V., Souverijns, W., Martens, J. A. and Jacobs, P. A. (1997) Hydrocracking of n-alkane mixtures on Pt/H-Y zeolite: Chain length dependence of the adsorption and the kinetic constants. Ind. Eng. Chem. Res., 36, pp. 3242-3247.
78. 9 n-alkane hydroisomerization and hydrocracking on Pt/H-Y and Pt/USY zeolites. J. Catal., 190, pp. 469-473.
79. Arribas, M. A. and Martinez, A. (2001) Simultaneous isomerization of n-heptane and saturation of benzene over Pt/Beta catalysts. Catal. Today, 65, pp. 117-122.
80. 2 and Pt/Beta catalysts for the simultaneous hydroisomerization of n-heptane and hydrogenation of benzene. J. Catal., 190, pp. 309-319.
81. 7 n-alkanes and simultaneous saturation of benzene. Appl. Catal. A, 247, pp. 113-123.
82. Gonzalez, H., Ramirez, J., Gutierrez-Alejandre, A., Castillo, P., Cortez, T. and Zarate, R. (2004) Selective hydroconversion of a model mixture and hydrotreated FCC gasoline for octane enhancement. Catal. Today, 98, pp. 181-191.
83. 9 n-Alkanes in vapor- and liquid-phase hydroconversion over bifunctional Pt-USY zeolite catalysts. J. Catal., 210, pp. 445-452.
84. Denayer, J. F.M., Ocakoglu, R. A., Huybrechts, W., De Jonckheere, B., Jacobs, P., Calero, S., Krishna, R., Smit, B., Baron, G. V. and Martens, J. A. (2003) High-pressure liquid phase hydroconversion of heptane/ nonane mixtures on Pt/H-Y zeolite catalyst. J. Catal., 220, pp. 66-73.
85. Martens, J. A. and Jacobs, P. A. (1990) Evidence for branching of long-chain n-alkanes via protonated cycloalkanes larger than cyclopropane. J. Catal., 124, pp. 357-366.
86. 12-alkylcyclohexanes on acidic catalysts. J. Am. Chem. Soc., 84, pp. 1204-1212.
87. Ernst, S. and Weitkamp, J. (1985) Isomorphic substitution in zeolites: Catalysis on Boro-, Alumo- and Galosilicates with ZSM-5 structure. Proceedings Intern. Symposium on Zeolite Catalysis Siofak, pp. 457-466. Siofak, Hungary
88. Souverijns, W., Parton, R., Martens, J. A., Froment, G. F. and Jacobs, P. A. (1996) Mechanism of the paring reaction of naphtens. Catal. Lett., 37, pp. 207-212.
89. Souverijns, W., Houvenaghel, A., Feijen, E. J.P., Martens, J. A. and Jacobs, P. A. (1998) Isomerization of 1-cyclohexyloctane on Pt/H-ZSM-22 bifunctional zeolite catalyst. J. Catal., 174, pp. 201-209.
90. Arroyo, J. A. Munoz, Thybout, J. W., Marin, G. B., Jacobs, P. A., Martens, J. A. and Baron, G. V. (2001) Reaction pathways of 1-cyclohexyloctane in admixture with dodecane on Pt/H-ZSM-22 Zeolite in three-phase hydroconversion. J. Catal., 198, pp. 29-40.
91. Corma, A., Gonzales-Alfaro, V. and Orchilles, A. V. (2001) Decalin and tetralin as probe molecules for cracking and hydrotreating the Light Cycle Oil. J. Catal., 200, pp. 34-44.
92. Landmesser, H., Kosslick, H., Kurschner, U. and Fricke, R. (1998) Acidity of substituted mesoporous molecular sieve MCM-48. J. Chem. Soc. Faraday Trans., 94, pp. 971-977.
93. Takeguchi, T., Kim, J.-B., Kang, M., Inui, T., Cheuh, W.-T. and Haller, G. I. (1998) Synthesis and characterization of alkali-free, Ga-substituted MCM-41 and its performance for n-hexane conversion. J. Catal., 175, pp. 1-6.
94. Chen, N. Y., Degnan, T. P. and Smith, C. M. (1994) Molecular Transport and Reaction in Zeolites, p. 131. VCH, New York
95. Vansant, E. F. (1990) Pore Size Engineering in Zeolites, pp. 145-171. Wiley, Chuchester, New York
96. Impens, N. R.E.N., Van Der Voort, P. and Vansant, E. F. (1999) Silylation of micro-, meso- and nonporous oxides. Micropor. Mesopor. Mater., 28, pp. 217-232.
97. Shaikh, R. A., Hegde, S. G., Behlekar, A. A. and Rao, B. S. (1999) Enhancement of acidity and paraselectivity by the silynation in pentasil zeolite. Catal. Today, 49, pp. 201-209.
98. Van Mao, R. Le, Ramsaran, A., Xiao, S., Yao, J. and Semmer, V. (1995) Enhanced catalytic performances by desilication and subsequent steam treatment of ZSM5 zeolite. J. Mater. Chem., 5, pp. 533-538.
99. Van Mao, R. Le (1999) Hybrid catalyst containing a microporous zeolite and a mesoporous cocatalyst forming a pore continuum for a better desorption of reaction products. Micropor. and Mesopor. Mater., 28, pp. 9-17.
100. Almanza, L. O., Narbeshuber, T., Araujo, P., Naccache, C. and Taarit, Y. B. (1999) On the influence of the mordenite acidity in the hydroconversion of linear alkanes over Pt-mordenite catalysts. Appl. Catal. A, 178, pp. 39-47.
101. Iglesia, E., Soled, S. L. and Kramer, G. M. (1993) Isomerization of alkanes on sulfated Zirconia. J. Catal., 144, pp. 238-253.
102. Saberi, M. A. and Van Mao, R. Le (2003) Comparative study of the kinetic behavior of the bifunctional and trifunctional catalysts in the hydroisomerization of n-heptane. Appl. Catal. A, 242, pp. 139-150.
103. Saberi, M. A., Van Mao, R. Le, Martin, M. and Mak, A. W.H. (2001) Effect of Zn loading of the Pt-Zn-HY trifunctional catalysts on the hydroisomerization of n-heptane. Appl. Catal. A, 214, pp. 229-236.
104. Meriaudeau, P., Tuan, V. A., Sapaly, G., Nghiem, V. T. and Nuccache, C. (1997) SAPO-11, SAPO-31, and SAPO-41 molecular cieves: Synthesis, characterization, and catalytic properties in n-octane hydroisomerization. J. Catal., 169, pp. 55-66.
105. 8 paraffins over Pt-Pd/SAPO-11, Pt-Pd/SAPO-41 bifunctional catalysts. Catal. Today, 49, pp. 285-292.
106. Jahn, E., Muller, D. and Becker, K. (1990) Characterization of the local environment of Si atoms incorporated into AlPO4-11 by means of 27Al, 31P and 29Si MAS n.m.r. spectroscopy. Zeolites, 10, pp. 151-156.
107. Zibrowius, B., Loffler, E. and Hunger, M. (1992) Multinuclear MAS n.m.r. and i.r. spectroscopic study of silicon incorporation into SAPO-5, SAPO-31, and SAPO-34 molecular sieves. Zeolites, 12, pp. 167-174.
108. Campelo, J. M., Lafont, F., Marinas, J. M. and Cordoba, U. (1995) Hydroisomerization and hydrocracking of n-heptane on Pt/SAPO-5 and Pt/ SAPO-11 catalysts. J. Catal., 156, pp. 11-18.
109. Campelo, J. M., Lafont, F. and Marinas, J. M. (1998) Hydroconversion of n-dodecane over Pt/SAPO-11 catalyst. Appl. Catal. A, 170, pp. 139-144.
110. Parlitz, B., Schreier, E., Zubowa, H. L., Eclelt, R., Lieske, E., Lischke, G. and Fricke, R. (1995) Isomerization of n-heptane over Pd-loaded silico-alumino-phosphate molecular sieves. J. Catal., 155, pp. 1-11.
111. Chaar, M. A. and Butt, J. B. (1994) Conversion of n-heptane over Pt- and Pd/SAPO-11 catalysts. Appl. Catal. A, 114, pp. 287-293.
112. Sinha, A. K. and Sivasankar, S. (1999) Hydroisomerization of n-hexane over Pt-SAPO-11 and Pt-SAPO-31 molecular sieves. Catal. Today, 49, pp. 293-302.
113. Hochtl, M., Jentus, A. and Vinek, H. (2001) Alkane conversion over Pd/ SAPO molecular sieves: Influence of acidity, metal concentration and structure. Catal. Today, 65, pp. 171-177.
114. Hochtl, M., Jentus, A. and Vinek, H. (2000) Hydroisomerization of heptane isomers over Pd/SAPO molecular sieves. J. Catal., 190, pp. 419-432.
115. Martens, J. A., Tielen, M. and Jacobs, P. A. (1989) Relation between parafin isomerisation capability and pore architecture of large-pore bifunctional zeolites. Stud. Surf. Sci. Catal., 46, pp. 49-59.
116. Flanigen, E. M., Patton, R. L. and Wilson, S. T. (1987) Innovation in Zeolite Materials Science, 37, p. 13. Studies in Surface Science and Catalysis, Elsevier, Amsterdam
117. Hochtl, M., Jentus, A. and Vinek, H. (1999) Hydroisomerization of n-heptane over Pd-loadd SAPO-11 molecular sieves. Micropor. Mesopor. Mater., 31, pp. 271-285.
118. Lorenco, J. P., Ribeiro, M. F., Borges, C., Rocha, J., Onida, B., Garrone, E. and Gabelica, Z. (2000) Synthesis and characterization of new CoAPSO-40 and ZnAPSO-40 molecular sieves. Microp. Mesop. Mater., 38, pp. 267-278.
119. Lischke, G., Parlitz, B., Lohse, U., Schreier, E. and Fricke, R. (1998) Acidity and catalytic properties of MeAPO-5 molecular sieves. Appl. Catal. A, 166, pp. 351-361.
120. Hasha, D., Saddlrriaga, L., Hataway, P. E., Cox, D. F. and Davis, M. E. (1988) Studies of silicoaluminophosphates with the sodalite structure. J. Am. Chem. Soc., 110, pp. 2127-2135.
121. Sinha, A. K., Sivasankar, S. and Ratnasamy, P. (1998) Hydroisomerization of n-alkanes over Pt-SAPO-11 and Pt-SAPO-31 synthesized from aqueous and nonaqueous Media. Ind. Eng. Chem. Res., 37, pp. 2208-2214.
122. Liu, Y., Liu, C., Tian, Z. and Lin, L. (2004) Sn-modified Pt/SAPO-11 catalysts for selective hydroisomerization of n-paraffins. Energy & Fuels, 18, pp. 1266-1271.
123. 4 framework with AEL structure. Microp. Mesop. Mater., 22, pp. 435-449.
124. 2 O-CTAB-butanol system. Appl. Catal. A, 253, pp. 461-467.
125. Geng, C-H., Zhang, F., Gao, Z. X., Zhao, L. F. and Zhou, J. L. (2004) Hydroisomerization of n-Tetradecane over Pt/SAPO-11 catalyst. Catal. Today, 93, pp. 485-491.
126. Corma, A., Miguel, P. J. and Ochhilles, A. V. (1994) Influence of hydrocarbon chain length and zeolite structure on the catalyst activity and deactivation for n-alkanes cracking. Appl. Catal. A, 117, pp. 29-40.
127. Wang, I. and Chang, Y. (1994) Effect of chain-leng of n-alkanes to their hydroconversion activity on zeolites. Stud. Surf. Sci. Catal., 92, pp. 155-161.
128. Walendziewski, J. and Pniak, B. (2003) Synthesis, physicochemical properties and hydroisomerization activity of SAPO-11 based catalysts. Appl. Catal. A, 250, pp. 39-47.
129. Galperin, L. B. (2001) Hydroisomerization of n-decane in the presence of sulfur and nitrogen compounds. Appl. Catal. A, 209, pp. 257-268.
130. Galperin, L. B., Bradley, S. A. and Mezza, T. M. Hydroisomerization of n-decane in the presence of sulfur: Effect of metal-acid balance and metal location. Appl. Catal. A, 219, pp. 79-88.
131. Martens, J. A. and Jacobs, P. A. (1989) Investigation of the pore architecture of CSZ-1 zeolites with the decane test reaction. Zeolites, 9, pp. 423-427.
132. Smith, F. A. and Bortz, R. W. (1990) Application varies for dewaxing process over 10-year span. Oil Gas J., 13, pp. 51-54.
133. Campelo, J. M., Lafont, F. and Marinas, J. M. (1995) Catalytic properties of the silicoaluminophosphates SAPO-5 and SAPO-11 in n-octane and isooctane hydroconversion. J. Chem. Soc. Faraday Trans., 91, p. 4171.
134. Parton, R., Uytterhoeven, L., Martens, J. A., Jacobs, P. A. and Froment, G. F. (1991) Synergism of ZSM-22 and Y zeolites in the bifunctional conversion of n-alkanes. Appl. Catal. A, 76, pp. 131-142.
135. Corma, A., Martinez, A., Pergher, S., Peratello, S., Perego, C. and Bellusi, G. Hydrocracking-hydroisomerization of n-decane on amorphous silica-alumina with uniform pore diameter. Appl. Catal. A, 152, pp. 107-125.
136. Taylor, R. J. and Petty, R. U. (1994) Selective hydroisomerization of long chain normal Paraffins. Appl. Catal. A, 119, pp. 121-138.
137. Kresge, C. Y., Leonowicz, M. E., Roth, W. J., Vartuli, J. C. and Beck, J. S. (1992) Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism. Nature, 359, pp. 710-712.
138. Schuth, F., Ciesla, U., Schacht, S., Thiema, M., Huo, Q. and Stucky, G. (1999) Ordered mesoporous silicas and zirconias: Control on length scales between nanometer and micrometer. Mater. Res. Bulletin, 34, pp. 483-494.
139. He, X. and Antonelli, D. (2002) Recent advances in synthesis and applications of transition metal containing mesoporous molecular sieves. Angew. Chem. Int. Ed., 41, pp. 214-221.
140. Yan, H., Blanford, C. F., Holland, B. T., Smyrl, W. H. and Stein, A. (2000) General synthesis of periodic macroporous solids by templated salt precipitation and chemical conversion. Chem. Mater., 12, pp. 1134-1141.
141. Al-Daous, M. A. and Stein, A. (2003) Preparation and catalytic evaluation of macroporous crystalline sulfated zirconium dioxide templated with colloidal crystals. Chem. Mater., 15, pp. 2638-2645.
142. Yang, P., Shao, D., Margolese, D. I., Chmelka, B. F. and Stucky, G. D. (1999) Block copolymer templating syntheses of mesoporous metal oxides with large ordering lengths and semicrystalline framework. Chem. Mater., 11, pp. 2813-2822.
143. 4- adamantane clusters. J. Am. Chem. Soc., 124, pp. 2604-2613.
144. Trikalitis, P. N., Rangan, K. K., Bakas, T. and Kanatzidis, M. G. (2002) Single-crystal mesostructured semiconductors with cubic symmetry and ion-exchange properties. J. Am. Chem. Soc., 124, pp. 12255-12260.
145. Riley, A. E., Mitchell, G. W., Kountentis, P. A., Bendicov, M., Kaszynki, P., Wudl, F. and Tolbert, S. H. (2003) Liquid-crystalline phase behavior in a zwitterionic tetraazapentacene. Adv. Funct. Mater., 13, pp. 531-540.
146. Yu, C. Z., Tian, B. Z. and Zhao, D. (2003) Recent advances in synthesis of non-siliceous mesoporous materials. Current Opinion Solid Mater. Sci., 7, pp. 191-197.
147. Tian, B. Z., Liu, X. Y., Solovyov, L. A., Yang, H. F., Zhang, Z. D., Xie, S. H., Zhang, F. Q., Tu, B., Yu, C. Z., Fan, J., Wang, L. M. and Zhao, D. (2004) Facile synthesis and characterization of novel mesoporous and mesorelief oxides with gyroidal structures. J. Am. Chem. Soc., 126, pp. 865-875.
148. Ryoo, R., Joo, S. H. and Jun, S. (1999) Synthesis of highly ordered carbon molecular sieves via template-mediated structural transformation. J. Phys. Chem. B, 103, pp. 7743-7746.
149. Jun, S., Joo, S. H., Ryoo, R., Kruk, M., Jaroniec, M., Lin, Z., Ohsune, T. and Terasaki, O. (2000) Synthesis of new, nanoporous carbon with hexagonally ordered mesostructure. J. Am. Chem. Soc., 122, pp. 10712-10713.
150. Schuth, F. (2003) Endo- and exotemplating to create high-surface-area inorganic materials. Angew. Chem. Int. Ed., 42, pp. 3604-3622.
151. Dautzenberg, F. M. and Angevine, P. J. (2004) Encouraging innovation in catalysis. Catal. Today, 93, pp. 3-16.
152. Auroux, A. (2002) Microcalorimetry methods to study the acidity and reactivity of zeolites, pillared clays and mesoporous materials. Top. Catal., 19, pp. 205-213.
153. Corma, A., Grande, M. S., Gonzalez-Alfaro, V. and Orchilles, A. V. (1996) Cracking activity and hydrothermal stability of MCM-41 and its comparison with amorphous silica-alumina and a USY zeolite. J. Catal., 159, pp. 375-382.
154. Pater, J. P.G., Jacobs, P. A. and Martens, J. A. (1999) Oligomerization of hex-1-ene over acidic aluminosilicate zeolites, MCM-41, and silica-alumina co-gel catalysts: A comparative study. J. Catal., 184, pp. 262-267.
155. Seo, G., Kim, N. H., Lee, Y. H. and Kim, J. H. (1999) Skeletal isomerization of 1-butene over mesoporous materials. Catal. Lett., 57, pp. 209-215.
156. Chuah, G. K., Hu, X., Zhan, P. and Jaenicke, S. (2002) Evidence for hypocage catalysis in FAU/EMT zeolites derived from isomerisation and hydrocracking of heptadecane. J. Mol. Catal. A, 181, pp. 25-31.
157. Cassiers, K., Linssen, T., Mathieu, M., Benjelloun, M., Schrijnemakers, K., Van Der Voort, P., Cool, P. and Vansant, E. F. (2002) A detailed study of thermal, hydrothermal, and mechanical stabilities of a wide range of surfactant assembled mesoporous silicas. Chem. Mater., 14, pp. 2317-2324.
158. Reddy, K. M. and Song, C. (1996) Synthesis of mesoporous zeolites and their application for catalytic conversion of polycyclic aromatic hydrocarbons. Catal. Today, 31, pp. 137-144.
159. Stucky, G. D., Zhao, D., Yang, P., Lukens, W., Melosh, N. and Chmelka, B. F. (1998) Using the organic-inorganic interface to define pore and macroscale structure. Stud. Surf. Sci. Catal., 117, pp. 1-12.
160. Corma, A., Fornes, V., Navarro, M. T. and Perez-Pariente, J. (1994) Acidity and stability of MCM-41 crystalline aluminosilicates. J. Catal., 148, pp. 569-574.
161. Reddy, K. M. and Song, C. (1996) Synthesis of mesoporous molecular sieves: Influence of aluminum source on Al incorporation in MCM-41. Catal. Lett., 36, pp. 103-109.
162. Borade, R. B. and Clearfield, A. (1996) Synthesis of beta zeolite with high levels of tetrahedral aluminium. Chem. Commun., 31, pp. 6275-6626.
163. Mokaya, R. and Jones, W. (1997) Physicochemical characterisation and catalytic activity of primary amine templated aluminosilicate mesoporous catalysts. J. Catal., 172, pp. 211-221.
164. n+-grafted MCM-41 catalysts: Probing the influence of temperature on the alumination process. J. Catal., 193, pp. 103-107.
165. Ryoo, R. (1998) Synthesis of MCM-48 single crystals. Chem. Commun., pp. 259-260.
166. Han, Y., Xiao, F-S., Wu, S., Sun, Y., Meng, X., Li, D., Lin, S., Deng, F. and Ai, X. (2001) A novel method for incorporation of heteroatoms into the framework of ordered mesoporous silica materials synthesized in strong acidic media. J. Phys. Chem. B, 105, pp. 7963-7966.
167. Zhao, D. Y., Nie, C., Zhou, Y. M., Xia, S. J., Huang, L. M. and Li, Q. Z. Comparison of disordered mesoporous aluminosilicates with highly ordered Al-MCM-41 on stability, acidity and catalytic activity. Catal. Today, 68, pp. 11-20.
168. Luan, Z., He, H., Zhou, W., Cheng, C.-F. and Klinnowski, J. (1995) Effect of structural aluminum on the mesoporous structure of MCM-41. J. Chem. Soc. Faraday Trans., 91, pp. 2955-2959.
169. Jana, S. K., Takahashi, H. T., Nakamura, M., Kaneko, M., Nishida, R., Shimizu, H., Kugita, T. and Namba, S. (2003) Aluminum incorporation in mesoporous MCM-41 molecular sieves and their catalytic performance in acid-catalyzed reactions. Appl. Catal. A, 245, pp. 33-41.
170. Chaudhari, K., Das, T. K., Chandwadkar, A. J. and Sivasanker, S. (1999) Mesoporous aluminosilicate of the MCM-41 type: Its catalytic activity in n-hexane isomerization. J. Catal., 186, pp. 81-90.
171. Fang, K., Wei, W., Ren, J. and Sun, Y. (2004) n-Dodecane hydroconversion over Ni/AlMCM-41 catalysts. Catal. Lett., 93, pp. 235-242.
172. Liu, Y., Zhang, W. and Pinnavaia, T. J. (2000) Steam-stable aluminosilicate mesostructures assembled from zeolite type Y seeds. J. Am. Chem. Soc., 122, pp. 8791-8792.
173. Liu, Y. and Pinnavaia, T. J. (2004) Metakaolin as a reagent for the assembly of mesoporous aluminosilicates with hexagonal, cubic and wormhole framework structures from proto-faujasitic nanoclusters. J. Mater. Chem., 12, pp. 3416-3420.
174. Liu, Y. and Pinnavaia, T. J. (2004) Assembly of wormhole aluminosilicate mesostructures from zeolite seeds. J. Mater. Chem., 14, pp. 1099-1103.
175. Liu, Y., Zhang, W. and Pinnavaia, T. J. (2001) Steam-stable MSU-S aluminosilicate mesostructures assembled from zeolite ZSM-5 and zeolite beta seeds. Angew. Chem. Int. Ed., 40, pp. 1255-1258.
176. Zhang, Z. T., Han, Y., Zhu, L., Wang, R. W., Yu, Y., Qiu, S. L., Zhao, D. Y. and Xiao, F. S. (2001) Strongly acidic and high-temperature hydrothermally stable mesoporous aluminosilicates with ordered hexagonal structure. Angew. Chem. Int. Ed., 40, pp. 1258-1262.
177. Han, Y., Wu, S., Sun, Y. Y., Li, D. S., Xiao, F. S., Liu, J. and Zhang, Z. T. (2002) Hydrothermally stable ordered hexagonal mesoporous aluminosilicates assembled from a triblock copolymer and preformed aluminosilicate precursors in strongly acidic media. Chem. Mater., 14, pp. 1144-1148.
178. Zeng, S., Blanchard, J., Breysse, M., Shi, Y., Su, X., Nie, H. and Li, D. Mesoporous materials from zeolite seeds as supports for nickel tungsten sulfide active phases. Appl. Catal. A, 294, pp. 59-67.
179. Bishof, C. and Hartmann, M. (2001) Isomerization and hydrocracking of n-heptane and n-decane over bifunctional mesoporous molecular sieves. Stud. Surf. Sci. Catal., 135, pp. 4327-4335.
180. Elangovan, S. P., Bishof, C. and Hartmann, M. (2002) Isomerization and hydrocracking of n-decane over bimetallic Pt-Pd clusters supported on mesoporous MCM-41 catalysts. Catal. Lett., 80, pp. 35-40.
181. Lin, S., Wang, L. and Xiao, F.-S. (2004) and control of acidic strength in ordered mesoporous aluminosilicate by using preformed zeolite precursors. Stud. Surf. Sci. Catal., 154, pp. 1513-1518.
182. Zhao, D., Feng, J., Huo, Q., Melosh, N., Fredrickson, G. H., Chemelka, B. F. and Stucky, G. D. (1998) Triblock copolymer syntheses of mesoporous silica with periodic 50 to 300 angstrom pores. Science, 279, pp. 548-552.
183. Nie, C., Huang, L., Zhao, D. and Li, Q. (2001) Performance of Pt/ Al-SBA-15 catalysts in hydroconversion of n-dodecane. Catal. Letters, 71, pp. 117-125.
184. 3 catalyst. Appl. Catal. A, 190, pp. 207-218.
185. Bell, A. T. (2003) The impact of nanoscience on heterogeneous catalysis. Science, 299, pp. 1688-1691.
186. Du, H., Kalyanaraman, M., Camblor, M. A. and Olsson, D. H. Hydrocarbon sorption. Mesopor. Mater., 40, pp. 305-312.
187. Corma, A., Corell, C., Perez-Pariente, J., Guil, J. M., Guil-Lopez, R., Nicolopoulos, S., Calbet, J. G. and Vallet-Regi, M. (1996) Adsorption and catalytic properties of MCM-22: The influence of zeolite structure. Zeolites, 16, pp. 7-14.
188. 3+ in framework of aluminosilicate mordenite by hydrothermal synthesis. Micropor. Mesopor. Mater., 20, pp. 139-147.
189. Haag, W. O., Lago, R. M. and Weisz, P. B. (1981) Transport and reactivity of hydrocarbon molecules in a shape-selective zeolite. Faraday Discuss. Chem. Soc., 72, pp. 317-330.
190. Camblor, M. A., Mifsund, A. and Perez-Pariente, J. (1991) Influence of the synthesis conditions on the crystallization of zeolite Beta. Zeolites, 11, pp. 792-797.
191. Jacobsen, C. J.H., Madsen, C., Houzvicka, J., Smidt, I. and Carsson, A. (2000) Mesoporous zeolite single crystals. J. Am. Chem. Soc., 122, pp. 7116-7117.
192. Hu, G., Ma, D., Ding, L., Lin, M. C. and Bao, X. (2004) In situ assembly of zeolitic building blocks into high-order structures. Angew. Chem. Int. Ed., 43, pp. 3452-3455.
193. Tosheva, L., Valtchev, V. and Sterte, J. (2000) Amorphous very high surface area silica macrostructures. J. Mater. Chem., 10, pp. 2330-2336.
194. Mintova, S. and Valtchev, V. (1996) Deposition of zeolite an on vegetal fibers. Zeolites, 16, pp. 31-34.
195. Prokesova, P., Mintova, S., Cejka, J. and Bein, T. (2003) Preparation of nanosized micro/mesoporous composites via simultaneous synthesis of Beta/ MCM-48 phases. Micropor. Mesopor. Mater., 64, pp. 165-174.
196. Benjelloun, M., Der Voort, V., Cool, P., Vansant, E. F. and Collart, O. (2001) Reproducible synthesis of high quality MCM-48 by extraction and recuperation of the gemini surfactant. Phy. Chem. Chem. Phys., 3, pp. 127-131.
197. Xu, W., Dong, J., Li, J., Li, J. and Wu, F. (1990) Novel method for the synthesis of micro/meso mixed alterable structures. Chem. Commun., pp. 755-757.
198. Naik, S. P., Chiang, A. S.T. and Thopson, P. W. (2003) Synthesis of zeolitic mesoporous materials by dry gel conversion under controlled humidity. J. Phys. Chem. B, 107, pp. 7006-7014.
199. Rao, P. R. Hari Prashad, Ueyama, K. and Matsukata, M. (1998) Crystallization of high silica BEA by dry gel conversion. Appl. Catal. A, 166, pp. 97-103.
200. Matsukata, M., Osaki, T., Ogura, M. and Kikuchi, E. (2002) Crystallization behavior of zeolite beta during steam-assited crystallization of dry gel. Micropor. Mesopor. Mater., 56, pp. 1-10.
201. Gao, F., Lu, Q. and Zhao, D. (2003) Synthesis of crystalline mesoporous CdS semiconductor nanarrays through a SBA-15 silica template technique. Adv. Mater., 15, pp. 739-742.
202. Akhmedov, V. M. and Al-Khowaiter, S. H. (2002) Low-temperature conversion of saturated hydrocarbons. Catal. Rev., 44, pp. 455-498.
203. Taguchi, A. and Schuth, F. (2005) Odered mesoporous materials. Micropor., 77, pp. 1-45.
204. Schuth, F., Wingen, A. and Sauer, J. (2001) Oxide loaded ordered mesoporous oxides for catalytic applications. Microp. Mesop. Mater., 4445, pp. 465-470.
205. Majano, G., Mintova, S., Ovsitser, O., Mihailova, B. and Bein, T. (2005) Zeolite Beta nanosized assemblies. Microp. Mesop. Mater., 80, pp. 227-235.
206. Persson, A. E., Schoeman, B. J., Sterte, J. and Otterstedt, J. E. (1994) Synthesis of discrete colloidal particles of TPA-silicalite-1. Zeolites, 14, pp. 557-567.
207. Jacobsen, C. J.H., Madsen, C., Janssens, T. V.W., Jacobsen, H. J. and Skibsted, J. (2000) Zeolites by confined space synthesis - characterization of the acid sites in nanosized ZSM-5. Microp. Mesop. Mater., 39, pp. 393-401.
208. Martens, J. A. and Jacobs, P. A. (2001) Tailor-made structuring of zeolite materials. Adv. Funct. Mater., 11, pp. 337-338.
209. Aerts, A., Van Isacker, A., Kremer, S. P.B., Kirschhock, C. E.A., Collignon, F., Houthoofd, K., Denayer, J. F.M., Baron, G. V., Marin, G. B., Jacobs, P. A. and Martens, J. A. (2004) Decane hydroconversion on bifunctional Zeogrid and nano-zeolite assembled from aluminosilicate nanoslabs of MFI framework type. Appl. Catal. A, 257, pp. 7-17.
210. Christensen, C. H., Schmidt, I. and Christensen, Ch. H. (2004) Improved performance of mesoporous zeolite single crystals in catalytic cracking and isomerization of n-hexadecane. Catal. Commun., 5, pp. 543-546.
211. Zhang, Y., Shi, X., Kim, J. M., Wu, D., Sun, Y. and Peng, S. (2004) Synthesis and catalysis of nanometer-sized bimodal mesoporous aluminosilicate materials. Catal. Today, 93, pp. 615-618.
212. Holm, V. C.F. and Bailey, G. C. (1962) Sulfate-treated Zirconia-gel catalyst.
213. Jin, T., Yamaguchi, T. and Tanabe, K. (1986) Mechanism of acidity generation on sulfur-promoted metal oxides. J. Phys. Chem., 90, pp. 4794-4796.
214. Ebitani, K., Tsuji, J., Hattori, H. and Kita, H. (1992) Dynamic modification of surface acid properties with hydrogen molecule for zirconium oxide promoted by platinum and sulfate ions. J. Catal., 135, pp. 609-617.
215. Chen, F. R., Coudurier, G., Joly, J. F. and Vedrine, J. C. (1993) Superacid and catalytic properties of sulfated Zirconia. J. Catal., 143, pp. 616-626.
216. Sayari, A. and Dicko, J. (1994) The state of platinum in Pt on sulfated Zirconia superacid catalysts. J. Catal., 145, pp. 561-564.
217. Cheung, T. and Gates, B. C. (1997) Activation of ethane in the presence of solid acids: Sulfated Zirconia, iron- and manganese-promoted sulfated Zirconia, and Zeolites. J. Catal., 168, pp. 522-531.
218. Hino, M. and Arata, K. (1979) Reaction of butane to isobutane catalyzed by iron oxide treated with sulfate ion, solid superacid. Chem. Lett., 10, pp. 1259-1260.
219. Arata, K. (1996) Preparation of superacids by metal oxides for reactions of butanes and pentanes. Appl. Catal. A, 146, pp. 3-32.
220. Arata, K., Matsuhashi, H., Hino, M. and Nakamura, H. (2003) Synthesis of solid superacids and their activities for reactions of alkanes. Catal. Today, 81, pp. 17-30.
221. Hsu, C. Y. and Lin, C. H. (1992) Detection of superacidity on solid superacids; a new approach. Chem. Commun., pp. 1479-1480.
222. Srinivasan, R., Sparks, D. E. and Davis, B. H. (1994) State of platinum in Zirconia and sulfated zirconia catalysts. Catal. Lett., 40, pp. 167-173.
223. Sikabwe, E. S. and White, R. L. (1997) Effects of iron promoter on reactions of 1-butene adsorbed on sulfated zirconias. Catal. Lett., 44, pp. 177-183.
224. Occelli, M. L., Schiraldi, D. A., Auroux, A., Keogh, R. A. and Davis, B. H. (2001) Effects of copper on the activity of sulfated zirconia catalysts for n-pentane isomerization. Appl. Catal. A, 209, pp. 165-177.
225. 2 catalysts for n-butane isomerization role of transition metal cation promoters. Appl. Catal. A, 167, pp. 75-84.
226. Arata, K. (1990) Advances in Catalysis, 37, p. 165. Academic Press, New York
227. 7 paraffins on zeolite catalysts. Rev. Inst. Fr. Pet., 46, pp. 89-107.
228. Bouchenefa-Saib, N., Issaadi, R. and Grange, P. (2004) Hydroconversion of n-heptane: A comparative study of catalytic properties of Pd/Sulfated Zr-pillared montmorillonite, Pd/sulfated zirconia and Pd/ γ-alumina. Appl. Catal. A, 259, pp. 9-15.
229. 2: effect of Pt load on catalyst performance. Appl. Catal. A, 213, pp. 247-257.
230. Sassi, A. and Sommer, J. (1999) Isomerization and cracking reactions of branched octanes on sulfated Zirconia. Appl. Catal. A, 188, pp. 155-162.
231. Wen, M. Y., Wender, I. and Tierney, J. W. (1990) Hydroisomerization and hydrocracking of n-heptane and n-hexadecane on solid superacids. Energy Fuels, 4, pp. 372-379.
232. Davis, B. H., Keogh, R. A. and Srinivasan, R. (1994) Sulfated zirconia as a hydrocarbon conversion catalyst. Catal. Today, 20, pp. 219-256.
233. 2 catalysts for the hydrocracking and hydroisomerization of n-hexadecane. Appl. Catal. A, 140, pp. 47-57.
234. Keogh, R. A., Sparks, D., Hu, J., Wender, I., Tierney, J. W., Wang, W. and Davis, B. H. (1994) Hydroisomerization and hydrocracking of n-hexadecane over a platinum-promoted sulfated zirconia catalyst. Energy and Fuels, 8, pp. 755-762.
235. Keogh, R. A. and Davis, B. H. (1999) Hydroconversion of hexadecane with Pt-promoted monocyclic and/or tetragonal sulfated zirconia catalysts. Catal. Lett., 57, pp. 33-35.
236. Sullivan, R. F. and Scott, J. W. (1983) Heterogeneous Catalysis, 222, p. 294. Selected American Histories (ACS Symp. Ser.), Washington, D.C.
237. Zhou, Z., Zhang, Y., Tierney, J. W. and Wender, I. (2003) Hybrid zirconia catalysts for conversion of Fischer-Tropsch waxy products to transportation fuels. Fuel Processing Technol., 83, pp. 67-80.
238. Knozinger, H. (1998) Alkane isomerization over sulfated zirconia. Top. Catal., 6, pp. 10-21.
239. Hino, M. and Arata, K. (1979) Reactions of butane and isobutane catalyzed by zirconium oxide treated with sulfate ion. J. Am. Chem. Soc., 101, pp. 6439-6440.
240. Yori, J. C., Vera, C. R. and Parera, J. M. (1997) n-Butane isomerization on tungsten oxide supported on Zirconia. Appl. Catal. A, 163, pp. 165-175.
241. 2 and the relative acid activity compared with Zeolites. J. Catal., 168, pp. 431-441.
242. Hino, M. and Arata, K. (1996) Preparation of superacid of iron-supported Zirconia for reaction of butane to isobutene. Chem. Lett., 36, pp. 125-128.
243. Shon, J. R., King, H. W. and Kin, J. T. (1997) New syntheses of solid catalysts. J. Mol. Catal., 41, pp. 375-378.
244. 2 catalysts and their reactivity in the isomerization of hexane. J. Catal., 223, pp. 1-12.
245. 2: Effect of the Pt incorporation. Appl. Catal. A, 181, pp. 5-14.
246. Larsen, G., Lotero, E., Raghavan, S., Parra, R. D. and Querini, C. A. (1996) A study of platinum supported on tungstated zirconia catalysts. Appl. Catal. A, 139, pp. 201-211.
247. Larsen, G. and Petkovic, L. M. (1996) Effect of preparation method and selective poisoning on the performance of platinum supported on tungstated zirconia catalysts for alkane isomerization. Appl. Catal. A, 148, pp. 155-166.
248. Barton, G., Soled, S. L., Meitzner, G. D., Fuentes, G. A. and Iglesia, E. (1999) Structural and catalytic characterization of solid acids based on zirconia modified by tungsten oxide. J. Catal., 181, pp. 57-72.
249. Zhang, S., Zhang, Y., Tierney, J. W. and Wender, I. (2001) Anion-modified zirconia: Effect of metal promotion and hydrogen reduction on hydroisomerization of n-hexadecane and Fischer-Tropsch waxes. Fuel Processing Technology, 69, pp. 59-71.
250. Venkatesh, K. R., Hu, J., Wang, W., Holder, G. D., Tierney, J. W. and Wender, I. (1996) Hydrocracking and hydroisomerization of long-chain alkanes and polyolefins over metal-promoted anion-modified zirconium oxides. Energy & Fuels, 10, pp. 1163-1170.
251. Chen, C., Cheng, S., Lin, H., Wong, S. and Mou, C. (2001) Sulfated zirconia catalyst supported on MCM-41 mesoporous molecular sieve. Appl. Catal. A, 215, pp. 21-30.
252. 2. J. Mol. Catal. A, 170, pp. 195-202.
253. Sun, Y., Zhu, L., Lu, H., Wang, R., Lin, S., Jiang, D. and Xiao, F. (2002) Sulfated zirconia supported in mesoporous materials. Appl. Catal. A, 237, pp. 21-31.
254. 2 catalysts for n-heptane isomerization. Appl. Catal. A, 232, pp. 129-135.
255. Boudart, M. and Levy, R. (1973) Platinum-like behavior of Tungsten carbide in surface catalysis. Science, 181, pp. 547-549.
256. Ribeiro, F. H., Betta, R. A. Dalla, Boudart, M., Baumgartner, J. E. and Iglesia, E. (1991) Reactions of neopentane, methylcyclohexane, and 3,3-dimethylpentane on tungsten carbides: The effect of surface oxygen on reaction pathways. J. Catal., 130, pp. 86-105.
257. 2C and WC: The effect of surface oxygen on reaction pathways. J. Catal., 130, pp. 498-513.
258. Iglesia, E., Baumgartner, J. E., Ribeiro, F. H. and Boudart, M. (1991) Bifunctional reactions of alkanes on tungsten carbides modified by chemisorbed oxygen. J. Catal., 131, pp. 523-544.
259. Iglesia, E., Ribeiro, F. H., Baumgartner, J. E. and Boudart, M. (1992) Synthesis, characterization, and catalytic properties of clean and oxygen-modified tungsten carbides. Catal. Today, 15, pp. 307-337.
260. 2. J. Catal., 143, pp. 249-261.
261. Blekkan, E. A., Pham-Huu, C., Ledoux, M. and Guille, J. (1994) Isomerization of n-heptane on an oxygen-modified molybdenum. Ind. Eng. Chem. Res., 33, pp. 1657-1664.
262. Delporte, P., Meunier, F., Pham-Huu, C., Vennegues, P., Ledoux, M. and Guille, J. (1995) Physical characterization of molybdenum oxycarbide catalyst. TEM, XRD, and XPS. Catal. Today, 23, pp. 251-267.
263. Ledoux, M., Gallo, P. Del, Pham-Huu, C. and York, A. P.E. (1996) Molybdenum oxycarbide isomerization catalysts for cleaner fuel production. Catal. Today, 27, pp. 145-150.
264. York, A. P.E., Pham-Huu, C., Gallo, P. Del and Ledoux, M. (1997) Molybdenum oxycarbide hydrocarbon isomerization catalysts: Cleaner fuels for the future. Catal. Today, 35, pp. 51-57.
265. 2 as the active species in the reforming of hydrocarbons. Catal. Lett., 38, pp. 95-99.
266. Katrib, A., Logie, V., Saurel, N., Wehrer, P., Hilaire, L. and Maire, G. (1997) Surface electronic structure and isomerization reactions of alkanes on some transition metal oxides. Surf. Sci., 377, pp. 754-758.
267. 2 (X=Mo, W). Stud. Surf. Sci. Catal., 130, p. 2363.
268. Katrib, A., Urfels, L. and Maire, G. (2001) (X=Mo, W), as reforming catalysts for hydrocarbon compounds. Catal. Today, 65, pp. 179-183.
269. 3 for hexanes reforming. J. Catal., 189, pp. 269-280.
270. 2 for the hydroisomerization reactions of hexanes and 1-hexene. Appl. Catal. A, 242, pp. 31-40.
271. ac. catalysts. Appl. Catal. A, 251, pp. 93-105.
272. 3 -carbon-modified catalyst for the n-heptane isomerization. Appl. Catal., 156, pp. 131-149.
273. Matsuda, T., Shiro, H., Sakagami, H. and Takahasi, N. (1997) Isomerization of heptane on molybdenum oxides treated with hydrogen. Catal. Lett., 47, pp. 99-103.
274. 2 reduction on the catalytic properties of molybdenum oxides for the conversions of heptane and 2-propanol. Appl. Catal. A, 193, pp. 185-193.
275. x catalysts. Catal. Today, 93, pp. 135-140.
276. Matsuda, T., Uchijima, F., Endo, S. and Takahasi, N. (1999) Effect of Pd loading on the catalytic properties of molybdenum oxides for the isomerization of heptane. Appl. Catal. A, 176, pp. 91-99.
277. 3 as a selective catalyst for heptane isomerization. Catal. Today, 81, pp. 31-42.
278. 3 and of Pt/zeolites for the conversions of pentane and heptane. Appl. Catal. A, 248, pp. 269-278.
279. 3 and Pt/ zeolites for the isomerization of pentane, hexane, and heptane. Appl. Catal. A, 242, pp. 267-274.
280. Leglise, J., Quotbi, M. El, Goupil, J. M. and Cornet, D. (1991) Competitive reactions catalyzed by NiMo-containing zeolites. Catal. Lett., 10, pp. 103-109.
281. Leglise, J., Quotbi, M. El and Cornet, D. (1992) Hydroconversion of n-heptane on NiW-sulfide. Czech. Chem. Comm., 57, p. 882.
282. Baudon, A., Lemberton, Y. L. and Guisnet, M. (1996) Hydrocracking of n-heptane on a sulfided NiMo-Y zeolite catalyst. Catal. Lett., 36, pp. 245-247.
283. Welters, W. J.J., Van Der Waerden, O. H., Zandbergen, H. W., De Beer, V. H.J. and Van Santen, R. A. (1995) Hydrocracking of n-decane over zeolite-supported metal sulfide catalysts. Ind. Eng. Chem. Res., 34, pp. 1156-1165.
284. Welters, W. J.J., Van Der Waerden, O. H., De Beer, V. H.J. and Van Santen, R. A. (1995) Hydrocracking of n-decane over zeolite-supported metal sulfide catalysts. 2. Zeolite Y-supported Ni and Ni-Mo Sulfides. Ind. Eng. Chem. Res., 34, pp. 1166-1171.
285. 3 catalysts. J. Catal., 172, pp. 137-145.
286. Roussel, M., Norsic, S., Lemberton, J. L., Guisnet, M., Cseri, T. and Benazzi, E. (2005) Hydrocracking of n-decane on a bifunctional sulfided NiW/silica-alumina catalyst: Effect of the operating conditions. Appl. Catal. A, 279, pp. 53-58.
287. Roussel, M., Lemberton, J. L., Guisnet, M., Cseri, T. and Benazzi, E. (2003) Mechanisms of n-decane hydrocracking on a sulfided NiW on silica-alumina catalyst. J. Catal., 218, pp. 427-443.
288. Perez-Romo, P., Potvin, C., Manoli, J. M. and Diega-Mariadassou, G. (2002) Phosphorus-doped Tungsten oxynitrides: Synthesis, characterization, and catalytic behavior in propene hydrogenation and n-heptane isomerization. J. Catal., 205, pp. 191-198.
289. Miyaji, A. and Okuhara, T. (2003) Skeletal isomerization of n-heptane and hydroisomerization of benzene over bifunctional heteropoly compounds. Catal. Today, 81, pp. 43-49.
290. Ono, Y., Taguchi, M., Suzuki, S. and Baba, T. (1985) Heteropolyacids as solid-acid catalysts. Stud. Catal., Surf. Sci., 20, pp. 167-176.
291. Okuhara, T., Mizuno, N. and Misono, M. (1996) Catalytic chemistry of heteropoly compounds. Adv. Catal., 41, p. 113. Academic Press, New York
292. 2: Comparative study with typical bifunctional catalysts. Appl. Catal. A, 262, pp. 143-148.
293. Dzikh, I. P., Lopes, J. M., Lemos, F. and Ribeiro, F. R. (1999) Mixing effect of USHY+HZSM-5 for different catalyst ratios on the n-heptane transformation. Appl. Catal. A, 176, pp. 239-250.
294. Zainudden, Z., Guerzoni, F. N. and Abbot, J. (1993) Cracking and isomerization of hydrocarbons with combinations of HY and HZSM-5 zeolites. J. Catal., 140, pp. 150-167.
295. Kinger, G., Majda, D. and Vinek, H. (2002) n-Heptane hydroisomerization over Pt-containing mixtures of zeolites with inert materials. Appl. Catal. A, pp. 301-312.
296. Elangovan, S. P. and Hartmann, M. (2003) Evaluation of Pt/MCM-41//MgAPO composite catalysts for isomerization and hydrocracking of n-decane. J. Catal., 217, pp. 388-395.
297. Klemt, A. and Reschetilowski, W. (2001) New hydrocracking catalysts based on mesoporous Al-MCM-41 materials. Chem. & Ind. Tech., 73, pp. 872-877.
298. Shan, Z., Giannoti, E., Jansen, J. C., Peters, J. A., Marchese, L. and Maschmeyer, Th. (2001) One-step synthesis of a highly active, mesoporous, titanium-containing silica by using bifunctional templating. Chem. Eur. J., 7, pp. 1437-1443.
299. Jansen, J. C., Shan, Z., Marchese, L., Zhou, W. V., Puil, N. and Maschmeyer, Th. (2001) A new templating method for three-dimensional mesopore networks. Chem. Commun., pp. 713-714.
300. Van Mao, R. Le, Al-Yassir, N. and Nguyen, D. T.T. (2005) Experimental evidence for the pore continue in hybrid catalysts used in the selective deep catalytic cracking of n-hexane and petroleum naphthas. Micropor. Mesopor. Mater., 85, pp. 176-182.
301. Zhou, Z., Zhang, Y., Tierney, J. W. and Wender, I. (2004) The refining, gas and petrochemicals processing. Catalysis
302. Iglesia, E., Barton, D. G., Soled, S. L., Miseo, S., Baumgartuer, J. H., Gates, W., Fuentes, G. A. and Meitzner, G. D. (1996) Selective isomerization of alkanes on supported tungsten oxide acids. Stud. Surf. Sci. Catal., 101, pp. 533-542.
303. Liers, J., Meusinger, J. and Reschetilowski, W. (1993) Comparison of cracking and hydrocracking of n-heptane on H-ZSM-5 catalysts. Chem. Eng. Technol., 16, pp. 422-428.
304. Zhang, S., Zhang, Y., Tierney, J. W. and Wender, I. (2000) Hydroisomerization of normal hexadecane with platinum-promoted tungstate-modified zirconia catalysts. Appl. Catal. A, 193, pp. 155-171.
305. Vazquez, M. I., Escardino, A. and Corma, A. (1987) Activity and selectivity of nickel-molybdenum/HY ultrastable zeolites for hydroisomerization and hydrocracking of alkanes. Ind. Eng. Chem. Res., 26, pp. 1495-1499.
306. Ward, J. M. (1993) Effect of second metal in hydrocracking of paraffins. Fuel Processing Technol., 32, pp. 55-58.
307. Jao, R. M., Lin, T. B. and Chang, J. R. (1996) Light Naphtha isomerization over mordenite-supported Ni-Pt Catalysts: Effects of Ni on the catalytic performance for pure feed and sulfur-containing feed. J. Catal., 161, pp. 222-229.
308. Eswaramoorthi, I. and Lingappan, N. (2003) Ni-Pt/H-Y zeolite catalysts for hydroisomerization of n-heptane. Catal. Lett., 87, pp. 133-142.
309. Eswaramoorthi, I., Bhavani, A. G. and Lingappan, N. (2003) Activity, selectivity and stability of Ni-Pt loaded zeolite-β and mordenite catalysts for hydroisomerisation of n-heptane. Appl. Catal. A, 253, pp. 469-486.
310. Eswaramoorthi, I. and Lingappan, N. (2003) Hydroisomerisation of n-hexane over bimetallic bifunctional silicoaluminophosphate based molecular sieves. Appl. Catal. A, 245, pp. 119-135.
311. Blomsma, E., Martens, J. A. and Jacobs, P. A. (1997) Isomerization and hydrocracking of heptane over bimetallic bifunctional PtPd/H-Beta and PtPd/USY zeolite catalysts. J. Catal., 165, pp. 241-248.
312. Liu, Y., Yu, Z., Yan, A. and Xu, Q. (1989) Synthesis and crystal morphology of SAPO-11. J. Inorg. Chem., 5, pp. 6-11.
313. Gianetto, G. E., Perot, G. R. and Guisnet, M. R. (1984) Hydrocracking of n-heptane on Pt-HZSM-5: Effevt of calcinations and reduction conditions. Stud. Surf. Sci. Catal., 20, pp. 265-272.
314. Maesen, T. L.M., Schenk, M., Vlugt, T. J.H., De Jonge, J. P. and Smit, B. J. (1999) The shape selectivity of paraffin hydroconversion on TON-, MTT-, and AEL-type sieves. J. Catal., 188, pp. 403-412.
315. 16 n-alkanes on Pt/ HZSM-5 zeolite. Appl. Catal., 8, pp. 123-141.
316. Gianetto, G. E., Perot, G. R. and Guisnet, M. R. (1986) Alkane hydroisomerization over solid acid catalysts. Ind. Eng. Chem. Prod. Res. Dev., 25, pp. 481-490.
317. Martens, J. A., Jacobs, P. A. and Weitkamp, J. (1986) Relative rates of primary hydrocracking modes of long chain paraffins in open zeolites. Appl. Catal., 20, pp. 283-303.
318. Martens, J. A., Tielen, M. and Jacobs, P. A. (1987) Attempts to rationalize the distribution of hydrocracked products. Catal. Today, 1, pp. 435-453.
319. Alvarez, F., Ribeiro, F. R., Perot, G., Thomazeau, C. and Guisnet, M. (1996) Influence of the balance between acid and hydrogenating functions on the transformation of n-decane on PtHY catalysts. J. Catal., 162, pp. 179-189.
320. Mills, G. A., Heinemann, H., Milliken, T. H. and Oblad, A. G. (1953) Catalytic mechanism. Ind. Eng. Chem., 45, pp. 134-137.
321. Weisz, P. B. and Swegler, E. W. (1957) Stepwise reaction on separate catalytic centers: Isomerization of saturated hydrocarbons. Science, 126, pp. 31-32.
322. Chu, H. Y., Rosynek, M. P. and Lunsford, J. H. (1998) Skeletal isomerization of hexane over Pt/H-Beta zeolites: Is the classical mechanism correct. J. Catal., 178, pp. 352-362.
323. Garin, F. and Gault, F. G. (1975) The mechanism of hydrogenolysis and isomerization of hydrocarbons on metals. J. Am. Chem. Soc., 97, pp. 4466-4476.
324. Alhumaizi, K. I., Akhmedov, V. M., Al-Zahrani, S. M. and Al-Khowaiter, S. H. (2001) Low temperature hydrocracking of n-heptane over Ni-supported catalysts: Study of global kinetics. Appl. Catal. A, 219, pp. 131-140.
325. 2. J. Am. Chem. Soc., 116, pp. 9585-9589.
326. Gozin, M., Weisman, A., Ben-David, Y. and Milstein, D. (1993) Activation of a carbon-carbon bond in solution by transition-metal insertion. Nature, 364, pp. 699-701.
327. Bromberg, S. E., Yang, H., Asplund, M. C., Lian, T., McNamara, B. K., Kotz, K. T., Yetson, J. S., Wilkens, M., Frei, H., Bergman, R. G. and Harris, C. B. (1997) The mechanism of a C-H bond activation reaction in room-temperature alkane solution. Science, 278, pp. 260-263.
328. Quignard, F., Lecuyer, C., Choplin, A., Olivier, D. and Basset, J. M. (1991) Surface organometallic chemistry on oxides: Selective catalytic low-temperature hydrogenolysis of alkanes by a highly electrophilic zirconium hydride complex supported on silica. Angew. Chem. Int. Ed. Engl., 30, pp. 1660-1661.
329. Condon, F. E. (1958) Stepwise reaction on separate catalytic centers. Catalysis, 6, p. 121. Reinhold, New York
330. Brouwer, D. M. and Hogeveen, H. (1972) Electrophilic substitutions at alkane and in alkylcarbonium ions. Prog. Phys. Org. Chem., 9, pp. 179-240.
331. Weitkamp, J. (1982) Isomerization of long-chain n-alkanes on a Pt/CaY zeolite catalyst. Ind. Eng. Chem. Prod. Res. Dev., 21, pp. 550-558.
332. Sie, S. T. (1992) Acid-catalyzed cracking of paraffinic hydrocarbons. Ind. Eng. Chem. Res., 31, pp. 1881-1889.
333. Sie, S. T. (1993) Evidence for the protonated cyclopropane mechanism from hydrocracking/hydroisomerization experiments. Ind. Eng. Chem. Res., 32, pp. 403-408.
334. 14-labeled norbornyl derivatives. J. Am. Chem. Soc., 76, pp. 4501-4510.
335. Weisser, O. and Landa, S. (1973) Sulphide Catalysts, Their Properties and Applications, Pergamon, Oxford/New York
336. Debrabandere, D. and Froment, G. F. (1997) Influence of the hydrocarbon chain length on the kinetics of the hydroisomerzation and hydrocracking of n-paraffins. Hydrotreatment and Hydrocracking of Oil Fractions, pp. 379-389. Elsevier, Amsterdam
337. Akhmedov, V. M. and Al-Khowaiter, S. H. (2004) A new class of highly active catalysts for conversion of alkanes. Proc. of 13th ICC, pp. 1-24. Paris
338. Fiaux, A., Smith, D. L. and Futrell, J. H. (1977) Thermodynamic properties of protonated molecules in the gas phase. Int. J. Mass. Spectrom. Ion. Phys., 25, p. 281.
339. Carvajal, R., Chu, P.-J. and Lansford, J. H. (1990) The role of polyvalent cations in developing strong acidity: A study of lanthanum-exchanged zeolites. J. Catal., 125, pp. 123-131.
340. 2. J. Catal., 202, pp. 25-33.
341. 2 solid acid catalysts. Langmuir, 14, pp. 3019-3029.
342. Song, X. and Sayari, A. (1996) Sulfated zirconia-based strong solid-acid catalysts: Recent progress. Catal. Rev.-Sci. Eng., 38, pp. 329-412.
343. Gutierrez-Alejandre, A., Castillo, A., Ramirez, P., Ramis, G. and Busca, G. (2001) Redox and acid reactivity of wolframyl centers on oxide carriers: Brønsted, Lewis and redox sites. Appl. Catal. A, 216, pp. 181-194.
344. Bursian, N. R., Botutsky, P. N., Georgiesky, V. Yu., Gruver, V. Sh., Krasii, B. V., Lastakin, G. A., Martynova, G. B., Orlov, D. S. and Brovko, V. N. (1991) Scientific foundations for synthesis of hydrocarbon isomerization catalysts. Prep. Am. Chem. Soc. Div. Pet. Chem., 36, p. 893.
345. Sohn, R., DeCanio, S. J., Fritz, P. O. and Lansford, J. H. (1986) Acid catalysis by dealuminated zeolite Y. 2. The roles of aluminum. J. Phys. Chem., 90, pp. 4847-4851.
346. Hong, Y. Y., Gruver, V. and Fripiat, J. J. (1994) Role of Lewis acidity in the isomerization of n-pentane and o-xylene on dealuminated H-Mordenites. J. Catal., 150, pp. 421-429.
347. Kuehne, M. A., Babitz, S. M., Kung, H. H. and Miller, J. T. (1998) Effect of framework Al content on HY acidity and cracking activity. Appl. Catal. A, 166, pp. 293-299.
348. Wang, Q. L., Glannetto, G. and Guisnet, M. (1991) Effect of extra-framework aluminum species on the activity, selectivity, and stability of Y zeolites in n-heptane cracking. J. Catal., 130, pp. 471-482.
349. Bamwenda, G. R., Zhao, Y. X., Groten, W. A. and Wojciechowski, B. W. (1995) The effects of efal extraction on 2-methylpentane cracking over steamed HY. J. Catal., 157, pp. 209-221.
350. Thubaut, J. W., Marin, G. B., Baron, G. V., Jacobs, P. A. and Martens, J. A. (2001) Alkene protonation enthalpy determination from fundamental kinetic modeling of alkane hydroconversion on Pt/H-(US)Y-zeolite. J. Catal., 202, pp. 324-339.
351. Kuba, S., Lukinskas, P., Grasseli, R. K., Gates, B. C. and Knozinger, H. (2003) Structure and properties of tungstated zirconia catalysts for alkane conversion. J. Catal., 216, pp. 353-361.
352. Bouchy, C., Pham-Huu, C., Heinrich, B., Chaumont, C. and Ledoux, M. J. (2000) Microstructure and characterization of a highly selective catalyst for the isomerization of alkanes: A molybdenum oxycarbide. J. Catal., 190, pp. 92-103.
353. Ebitani, K., Tsuji, J. and Hattori, H. (1991) Skeletal isomerization of hydrocarbons over zirconium oxide promoted by platinum and sulfate ion. J. Catal., 130, pp. 257-267.
354. Farcasju, D., Ghencin, A. and Li, J. Q. (1996) The mechanism of conversion of saturated hydrocarbons catalyzed by sulfated metal oxides: reaction of adamantane on sulfated Zirconia. J. Catal., 158, pp. 116-127.
355. Wan, K. T., Khouw, C. B. and Davis, M. E. (1996) Studies on the catalytic activity of zirconia promoted with sulfate, iron, and manganese. J. Catal., 158, pp. 311-326.
356. Kazansky, V. B., Frash, M. V. and Van Santen, R. A. (1994) A quantum-chemical study of hydride transfer in catalytic transformations of paraffins on zeolites. Pathways through adsorbed nonclassical carbonium ions. Catal. Lett., 48, pp. 61-67.
357. Frash, M. U., Van Santen, R. A. and Vinek, H. (1999) Quantum-chemical modeling of the hydrocarbon transformations in acid zeolite catalysts. Top. Catal., 9, pp. 191-205.
358. Rigby, A. M., Kramer, G. J. and Van Santen, R. A. (1997) Mechanisms of hydrocarbon conversion in zeolites: A quantum mechanical study. J. Catal., 170, pp. 1-10.
359. Weisz, P. B., Frilette, V. J., Maatman, R. W. and Mower, E. B. (1962) Catalysis by crystalline aluminosilicates II. Molecular-shape selective reactions. J. Catal., 1, pp. 307-312.
360. Weisz, P. B. (1980) Molecular shapeselective catalysis. Pure Appl. Chem., 52, pp. 2091-2103.
361. Csicsery, S. M. (1970) Selective disproportionation of alkylbenzenes over mordenite molecular sieve catalyst. J. Catal., 19, pp. 394-397.
362. Csicsery, S. M. (1971) The cause of shape selectivity of transalkylation in mordenite. J. Catal., 23, pp. 124-130.
363. Degnan, T. F. (2003) The implications of the fundamentals of shape selectivity for the development of catalysts for the petroleum and petrochemical industries. J. Catal., 216, pp. 32-46.
364. Webb III, E. B. and Grest, G. S. (1998) Influence of intracrystalline diffusion in shape selective catalytic test reactions. Catal. Letters, 56, pp. 95-104.
365. Ernst, S., Weitkamp, J., Martens, J. A. and Jacobs, P. A. (1989) Synthesis and shape-selective properties of ZSM-22. Appl. Catal., 48, pp. 137-148.
366. Derouane, E. G. and Gabelica, Z. (1980) A novel effect of shape selectivity: Molecular traffic control in zeolite ZSM-5. J. Catal., 65, pp. 486-489.
367. Martens, J. A., Parton, R., Uytterhoeven, L. and Jacobs, P. A. (1991) Selective conversion of decane into branched isomers. Appl. Catal., 76, pp. 95-116.
368. Denayer, J. F.M., Baron, G. V., Jacobs, P. A. and Martens, J. A. (1998) Chromatographic study of adsorption of n-alkanes on zeolites at high temperatures. J. Phys. Chem. B, 102, pp. 3077-3081.
369. 8 Alkanes on Zeolite Beta, ZSM-5, ZSM-22, Zeolite Y, and Mordenite. J. Phys. Chem. B, 102, pp. 4588-4597.
370. Narasimhan, C. S. Laxmi, Thybaut, J. W., Marin, G. B., Martens, J. A., Denayer, J. F.M. and Baron, G. V. (2003) Pore mouth physisorption of alkanes on ZSM-22: Estimation of physisorption enthalpies and entropies by additivity method. J. Catal., 218, pp. 135-147.
371. Pieterse, J. A.Z., Reyes, S., Seshan, K. and Lercher, J. A. (2000) Sorption and ordering of dibranched alkanes on medium-pore zeolites ferrierite and TON. J. Phys. Chem. B, 104, pp. 5715-5723.
372. Gorring, R. L. (1973) Diffusion of normal paraffins in zeolite T: occurrence of window effect. J. Catal., 31, pp. 13-26.
373. Santilli, D. S., Harris, T. V. and Zones, S. I. (1993) Inverse shape selectivity in molecular sieves: Observations, modelling, and predictions. Micropor. Mater., 1, pp. 329-341.
374. Shenk, M., Calero, S., Maesen, T. L.M., Van Benthem, L. L., Verbeek, M. G. and Smit, B. (2002) Understanding zeolite catalysis: Inverse shape selectivity revised. Angew. Chem. Int. Ed. Eng., 41, pp. 2499-2502.
375. International Zeolite Association (2000)
376. Frillette, V. J., Haag, W. O. and Lago, R. M. (1981) Catalysis by crystalline aluminosilicates: Characterization of intermediate pore-size zeolites by the "Constraint Index". J. Catal., 67, pp. 218-222.
377. Weitkamp, J. and Ernst, S. (1994) Test reactions for probing the pore width of large and super-large pore molecular sieves. Catal. Today, 19, pp. 107-150.
378. Martens, J. A., Perez-Pariente, J. and Jacobs, P. A. (1984) Factors affecting the synthesis efficiency of zeolite Beta from aluminosilicate gels containing alkali and tetraethylammonium ions. Zeolites, 4, pp. 98-107.
379. Weitkamp, J., Ernst, S. and Kumai, R. (1986) A novel test reaction for characterizing the effective pore width of bifunctional zeolite catalysts. Appl. Catal., 27, pp. 207-210.
380. Stangeland, B. E. (1974) Ind. Eng. Chem. Process. Des. Dev., 13, p. 72.
381. Quann, R. J. and Jaffe, S. B. (1992) Structure-oriented lumping: describing the chemistry of complex hydrocarbon mixtures. Ind. Eng. Chem. Res., 31, pp. 2483-2497.
382. Browarzik, D. and Kehlen, H. (1994) Hydrocracking process of n-alkanes by continuous kinetics. Chem. Eng. Sci., 49, p. 923.
383. Narasimhan, C. S. Laxmi, Thybaut, J. W., Marin, G. B., Jacobs, P. A., Martens, J. A., Denayer, J. F.M. and Baron, G. V. (2003) Kinetic modeling of pore mouth catalysis in the hydroconversion of n-octane on Pt-H-ZSM-22. J. Catal., 220, pp. 135-147.
384. Baltanas, M. A., Van Raemdonck, K. K., Froment, G. F. and Mohedas, S. R. (1989) Rate parameters for Hydroisomerization. Ind. Eng. Chem. Res., 28, pp. 899-910.
385. 12 alkanes on Pt/US-Y zeolites. J. Catal., 195, pp. 253-267.
386. Choudharu, V. R. and Akolekai, D. B. (1989) Shuttlecock-shuttlebox model for shape selectivity of medium-pore zeolites in sorption and diffusion. J. Catal., 117, pp. 542-548.
387. 7-hydroconversion selectivities on Y, β, ZSM-22, ZSM-23, and EU-1 Zeolites. J. Catal., 197, pp. 98-112.
388. Sastre, G., Chica, A. and Corma, A. (2000) On the mechanism of alkane isomerisation (isodewaxing) with unidirectional 10-member ring zeolites. J. Catal., 195, pp. 227-236.
389. Shenk, M., Calero, S., Maesen, T. L.M., Vlugt, T. J.H., Van Benthem, L., Verbeek, M. G., Schnell, B. and Smit, B. (2003) Shape selectivity through Entropy. J. Catal., 214, pp. 88-99.
390. Natal-Santiago, M. A., Alcala, R. and Dumesic, J. A. (1999) DFT study of the isomerization of hexyl species involved in the acid-catalyzed conversion of 2-methylpentene-2. J. Catal., 181, pp. 124-144.
391. Frash, M. V., Kazansky, V. B., Rigby, A. M. and Van Santen, R. A. (1997) Density functional and hartree-fock calculations on the cyclopropane ring intermediates involved in the zeolite-catalyzed skeletal isomerization of hydrocarbons. J. Phys. Chem. B, 101, pp. 5346-5351.
392. 5 cations. J. Am. Chem. Soc., 95, pp. 6531-6544.
393. De Pablo, L., Chavez, M. L., Sum, A. K. and De Pablo, J. J. (2004) Monte Carlo molecular simulation of the hydration of Na-montmorillonite at reservoir conditions. J. Chem. Phys., 120, pp. 939-946.
394. Frenkel, D., Silvestrelli, P. L., Alavi, A. and Parrinello, M. (1996) Nonmetal-metal transition in metal-molten-salt solutions. Condens. Matter. Mater. Phys., 53, pp. 12750-12760.
395. Van de Runstraat, A., Van Grondelle, J. and Van Santen, R. A. (1997) On the temperature dependence of the Arrhenius activation energy for hydroisomerization catalyzed by Pt/mordenite. J. Catal., 167, pp. 460-463.
396. Van de Runstraat, A., Van Grondelle, J. and Van Santen, R. A. (1997) Microkinetics modeling of the hydroisomerization of n-hexane. Ind. Eng. Chem. Res., 36, pp. 3116-3125.
397. Van de Runstraat, A., Kamp, J. A., Stobbelaat, P. J., Van Grondelle, J., Krijnen, S. and Van Santen, R. A. (1997) Kinetics of hydro-isomerization of n-hexane over platinum containing zeolites. J. Catal., 171, pp. 77-84.
398. Ernst, S., Kokotailo, G. T., Kumar, R. and Weitkamp, J. (1988) Proc. 9th Inter. Cong. on Catalysis, 1, pp. 388-395. Calgary
399. Meriaudeau, P., Tuan, Vu. A., Sapaly, G., Nghiem, Vu. T. and Naccache, C. (1999) Proc. 12th Int. Zeolite Conference, 3, p. 2913. PA
400. Ernst, S., Kumar, R. and Weitkamp, J. (1988) Synthesis and catalytic properties of zeolite ZSM-23. Catal. Today, 3, pp. 1-10.
401. Souverijns, W., Martens, J. A., Uytterhoeven, L., Froment, G. F. and Jacobs, P. A. (1997) Progress in Zeolite and Microporous Materials, 105, p. 1285. Elsevier, Amsterdam
402. Schuring, D., Jansen, A. P.J. and Van Santen, R. A. (2000) Concentration and chainlength dependence of the diffusivity of alkanes in zeolites studied with MD simulations. J. Phys. Chem. B, 104, pp. 941-948.
403. Stull, D. R., Westrum Jr., E. F. and Sinke, G. C. (1987) The Chemical Thermodynamics of Organic Compounds, pp. 249-252. Krieger, Malabar, FL
404. Maesen, T. L.M., Schenk, M., Vlugt, T. J.H. and Smit, B. (2001) Differences between MFI- and MEL-type zeolites in paraffin hydrocracking. J. Catal., 203, pp. 281-291.
405. Bond, G. C., Keane, M. A., Kral, H. and Lercher, J. A. (2000) Compensation phenomena in heterogeneous catalysis: General principles and possible explanation. Catal. Rew., 42, pp. 323-383.
406. Dubbeldam, D., Calero, S., Maesen, T. L.M. and Smit, B. (2003) Understanding the window effect in zeolite catalysis. Angew. Chem. Int. Ed., 42, pp. 3624-3626.
407. Maesen, T. L.M., Calero, S., Schenk, M. and Smit, B. (2004) Alkane hydrocracking: Shape selectivity or kinetics?. J. Catal., 221, pp. 241-251.
408. Martens, J. A. and Jacobs, P. A. (1990) Theoretical Aspects of Heterogeneous Catalysis, p. 52. Van Nostrand Reinhold, New York
409. Akhmedov, V. M. and Al-Khowaiter, S. H. (2004) Novel catalysts for selective conversion of paraffins to the lower liquid branched alkanes. Proc. of the 6th Int. Conf. Chemistry in Industry, Bahrain