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33846931801
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note
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sCOO).
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14
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33846907522
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note
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TGA-DTA curves for 1 showed a first weight loss of 11.2% (calculated 11.3%) over 35-88 °C with an endothermic processes centered at 80 °C, corresponding to the loss of lattice water molecules. On further heating, three consecutive weight losses were observed in 298-587 °C range with the loss of oxalate and macrocyclic ligands. Finally, the ZnO residue (observed 15.1%, calculated 15.3%) was remained above 587 °C.
-
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15
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33846935461
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note
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2 = 0.1256 (all data).
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16
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G.M. Sheldrick, SHELXTL{minus 45 degree rule}PC V6.1, Bruker Analytical X-ray Systems, Madison, WI, 2001.
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