메뉴 건너뛰기




Volumn 129, Issue 5, 2007, Pages 1327-1334

Six-fold oxygen-coordinated triplet (S = 1) palladium(II) moieties templated by tris(bipyridine)ruthenium(II) ions

Author keywords

[No Author keywords available]

Indexed keywords

GROUND STATE; IONS; PARAMAGNETIC MATERIALS; PROBABILITY DENSITY FUNCTION; RUTHENIUM COMPOUNDS; THERMAL EFFECTS; X RAY POWDER DIFFRACTION;

EID: 33846804273     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja066817v     Document Type: Article
Times cited : (28)

References (65)
  • 38
    • 33846800758 scopus 로고    scopus 로고
    • In Pd2, the ratio Pd/Ru is 2/1.23 (±0.2). In PdMn, the ratios Mn/Pd/Ru are 1/0.95/1.24 (±0.20). These results are in line with those obtained on comparable 3D oxalate-based compounds. The ratio of the metal(s) inserted in the anionic network to the ruthenium of the template cation is slightly the same for PdMn and Pd2. For PdMn, the Mn/Pd ratio is coherent with the nominal value of 1/1. Moreover, this ratio was confirmed by the absorbance of the sample measured at Pd and Mn K-edges. Finally, it should be noted that a Mn/Pd ratio significantly different from 1/1 would spoil the observed agreement between experimental and calculated percentages for C, H, and N, because of the important molar mass difference between palladium and manganese.
    • In Pd2, the ratio Pd/Ru is 2/1.23 (±0.2). In PdMn, the ratios Mn/Pd/Ru are 1/0.95/1.24 (±0.20). These results are in line with those obtained on comparable 3D oxalate-based compounds. The ratio of the metal(s) inserted in the anionic network to the ruthenium of the template cation is slightly the same for PdMn and Pd2. For PdMn, the Mn/Pd ratio is coherent with the nominal value of 1/1. Moreover, this ratio was confirmed by the absorbance of the sample measured at Pd and Mn K-edges. Finally, it should be noted that a Mn/Pd ratio significantly different from 1/1 would spoil the observed agreement between experimental and calculated percentages for C, H, and N, because of the important molar mass difference between palladium and manganese.
  • 39
    • 0004150157 scopus 로고    scopus 로고
    • University of Göttingen: Germany
    • Sheldrick, G. M. SHELXL97; University of Göttingen: Germany, 1997.
    • (1997) SHELXL97
    • Sheldrick, G.M.1
  • 45
    • 0003646268 scopus 로고
    • Société Française de Chimie: Paris, France
    • Michalowicz, A. EXAFS pour le MAC; Société Française de Chimie: Paris, France, 1991.
    • (1991) EXAFS pour le MAC
    • Michalowicz, A.1
  • 46
    • 33846843953 scopus 로고
    • CERN Computing Center, Program Library, CERNID Internal Report 75/20
    • James, F.; Roos, M. Round Midnight; CERN Computing Center, Program Library, CERNID Internal Report 75/20, 1976.
    • (1976) Round Midnight
    • James, F.1    Roos, M.2
  • 48
    • 33846793626 scopus 로고    scopus 로고
    • Frisch, M. J.; et al. Gaussian 98, revision A.11; Gaussian, Inc.: Pittsburgh, PA, 2001.
    • Frisch, M. J.; et al. Gaussian 98, revision A.11; Gaussian, Inc.: Pittsburgh, PA, 2001.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.