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One of the referees has commented that the less endothermic enthalpy and negative reaction entropy in isobutyl alcohol may indicate that there is H-bonding between the OH moiety of the solvent molecule with the hydride ligand of HCo(n-Bu3P)(CO)355
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p data are contained in Table 4 in the Supporting Information.
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The Co-Co bond energy is linked to the Co-H bond energy by the enthalpy change for the hydrogenation of the dimer. This latter quantity has been investigated independently by three groups with excellent agreement. 5,12,61 See ref 61 for a discussion of a fourth observation that is inconsistent with the other three, Accordingly, if the Co-H bond energy is 8 kcal/mol higher, then the Co-Co bond energy must be 16 kcal/mol higher, placing it at 35 kcal/mol. This 35 kcal/mol value is well outside the error range of either the NMR measurement, 19 ± 2 kcal/mol,6 or the latest mass spectroscopic value, 20 ± 7 kcal/mol.9 Furthermore, 35 kcal/mol is much higher than any of the measurements for the Co-Co bond energy, some of which were as low as 14.5 kcal/mol.65
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