The rate and mechanism of oxidative addition of H2 to the ·Cr(CO)3C5Me5 radical - Generation of a model for reaction of H2 with the ·Co(CO)4 radical

Journal of Organometallic Chemistry

Volumn 586, Issue 1, 1999, Pages 23-30

  Capps, Kenneth B ^a   Bauer, Andreas ^a   Kiss, Gabor ^b   Hoff, Carl D ^a  

^a University of Miami   (United States)

^b EXXONMOBIL UPSTREAM RESEARCH COMPANY   (United States)

Author keywords

Chromium; Cobalt; Free radicals; Hydrogen; Oxidative addition

Indexed keywords

KOBUS;

EID: 0001940147     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-328X(99)00194-1     Document Type: Article

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29. 4 radicals can react via a third-order mechanism with molecular hydrogen. The authors only became aware of this article following completion of the first draft of this manuscript. The ideas proposed in our article, and also that of Klingler and Rathke, cited above are not new in and of themselves. What is new is the degree of quantitative and qualitative support now generated for this type of mechanism being applicable to cobalt carbonyl.
30. 2.
31. K.B. Capps, A. Bauer, C.D. Hoff, in preparation.