One-pot synthesis of fatty acid epoxides from triacylglycerols using enzymes present in oat seeds

JAOCS, Journal of the American Oil Chemists' Society

Volumn 83, Issue 12, 2006, Pages 1021-1025

  Piazza, George J ^a,b   Foglia, Thomas A ^a  

^a EASTERN REGIONAL RESEARCH CENTER   (United States)

^b AGRICULTURAL RESEARCH SERVICE   (United States)

Author keywords

Avena saliva; Fatty acid; Fatty epoxide; Hydroperoxide; Lipase; Oat seed; Oxidation; Peroxygenase

Indexed keywords

AVENA SALIVA; FATTY EPOXIDE; LIPASE; OAT SEED; PEROXYGENASE;

ENZYMES; FATTY ACIDS; GLYCEROL; SYNTHESIS (CHEMICAL);

SEED;

ENZYMES; FATTY ACIDS; OATS; OXIDATION; PEROXIDES; SEEDS; SYNTHESIS;

AVENA SATIVA; GLYCINE MAX;

EID: 33846418327     PISSN: 0003021X     EISSN: None     Source Type: Journal    
DOI: 10.1007/s11746-006-5157-0     Document Type: Article

References (10)

1. Piazza, G.J., A. Bilyk, D.P. Brower, and M.J. Haas, The Positional and Fatty Acid Selectivity of Oat Seed Lipase in Aqueous Emulsions, J. Am. Oil Chem. Soc. 59:978-981 (1992).
2. Piazza, G.J., A. Bilyk, D.P. Schwartz, and M.J. Haas, Lipolysis of Olive Oil and Tallow in an Emulsifier-Free Two-Phase System by the Lipase from Oat Seeds (Avena sativa L.), Biotechnol Lett. 11:487-492 (1989).
3. Piazza, G.J., Generation of Polyunsaturated Fatty Acids from Vegetable Oils Using the Lipase from Ground Oat (Avena sativa L.) Seeds as a Catalyst, Ibid. 75:173-178 (1991).
4. Piazza, G.J., and H.M. Farrell, Jr., Generation of Ricinoleic Acid from Castor Oil Using the Lipase from Ground Oat (Avena sativa L.) Seeds as a Catalyst, Ibid. 13:179-184 (1991).
5. Piazza., G.J., T.A. Foglia, and A. Nun̈ez, Epoxidation of Fatty Acids, Fatty Methyl Esters, and Alkenes by Immobilized Oat Seed Peroxygenase, J. Mol. Cat. B: Enzymatic 27:143-151 (2003).
6. Piazza, G.J., A. Nunez, and T.A. Foglia, Isolation of Unsaturated Diols After Oxidation of Conjugated Linoleic Acid with Peroxygenase, Lipids 33:255-261 (2003).
7. Piazza, G.J., and T.A. Foglia, Synthesis of a Fatty Tetrahydroxyamide Using Peroxygenase from Oat Seeds, J. Am. Oil Chem. Soc. 87:933-937 (2004).
8. Piazza, G.J., and T.A. Foglia, Preparation of Fatty Amide Polyols via Epoxidation of Vegetable Oil Amides by Oat Seed Peroxygenase, Ibid. 82:481-485 (2005).
9. Piazza, G.J., T.A. Foglia, and A. Nunez, Soybean Lipoxygenase-Promoted Oxidation of Free and Esterified Linoleic Acid in the Presence of Deoxycholate, Ibid. 73:1045-1049 (2004).
10. Piazza, G.J., T.A. Foglia, and A. Nunez, Optimizing Reaction Parameters for the Enzymatic Synthesis of Epoxidized Oleic Acid with Oat Seed Peroxygenase, Ibid. 78:589-592 (2001).