Impregnation synthesis of a novel macroporous silica-based TODGA polymeric composite and its application in the adsorption of rare earths in nitric acid solution containing diethylenetriaminepentaacetic acid

European Polymer Journal

Volumn 43, Issue 2, 2007, Pages 529-539

  Zhang, Anyun ^a   Kuraoka, Etsushu ^b   Kumagai, Mikio ^b  

^a ZHEJIANG UNIVERSITY   (China)

^b INSTITUTE OF RESEARCH AND INNOVATION   (Japan)

Author keywords

Adsorption; Macroporous silica based polymeric composite; Rare earth; Synthesis

Indexed keywords

ADSORPTION; CONCENTRATION (PROCESS); NITRIC ACID; RARE EARTH COMPOUNDS; SILICA; SYNTHESIS (CHEMICAL);

DISASSOCIATION EQUILIBRIUM; IMPREGNATION SYNTHESIS; MACROPOROUS SILICA BASED POLYMERIC COMPOSITE; VACUUM SUCKING TECHNIQUES;

COPOLYMERS;

EID: 33846380711     PISSN: 00143057     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.eurpolymj.2006.10.034     Document Type: Article

References (30)

1. Collins ED, Renier, JP. Systems studies of actinide partitioning-transmutation recycle methods. In: Proceedings of international conference global 2005, Tsukuba, Japan, October 9-13, 2005. p. 235.
2. Oigawa H, Minato K, Kimura T, Morita, Y, Arai Y, Nakayama S, et al. Present status and future perspective of research and development on partitioning and transmutation technology at JAERI. In: Proceedings of international conference global 2005, Tsukuba, Japan, October 9-13, 2005. p. 207.
3. Madic C. Overview of the hydrometallurgical and pyrometallurgical processes studied world-wide for the partitioning of high active nuclear wastes. In: The 3rd international conference of NUCEF 2001, 31 October-02 November, 2001, Japan Atomic Energy Research Institute (JAERI), Tokai, Ibaraki, Japan; JAERI-conference 2002-004, March 2002. p. 27-7.
4. Choppin G.R., and Nash K.L. Actinide separation science. Radiochim Acta 70-71 (1995) 225-236
5. Kolarik Z. Extraction of selected mono- to tetravalent metal ions by 2,6-di(5,6-dialkyl-1,2,4,-triazin-3-yl)pyridines. Solvent Extr Ion Exc 21 3 (2003) 381-397
6. Tachimori S., Sasaki Y., and Suzuki S. Modification of TODGA-n-dodecane solvent with a monoamide for high loading of lanthanides(III) and actinides(III). Solvent Extr Ion Exc 20 (2002) 687-700
7. 3-n-dodecane system. Solvent Extr Ion Exc 19 (2001) 91-103
8. Apichaibukol A., Sasaki Y., and Morita Y. Effect of DTPA on the extraction of actinides (III) and lanthanides (III) from nitrate solution into TODGA/n-dodecane. Solvent Extr Ion Exc 22 6 (2004) 997-1011
9. Morita Y, Sasaki Y, Tachimori S. Actinides separation by TODGA extraction. In: The 3th international conference of NUCEF 2001, 31 October-02 November, 2001, Japan Atomic Energy Research Institute, Tokai-mura, Japan; JAERI-Conference 2002-004, 2002. p. 255-60.
10. Sasaki Y., and Tachimori S. Extraction of actinides (III), (IV), (VI), and (VI) and lanthanides (III) by structurally tailored diamides. Solvent Extr Ion Exc 20 1 (2002) 21-34
11. Narita H., Yaita T., Tamura K., and Tachimori S. Solvent extraction of trivalent lanthanides ions with N,N′-dimethyl-N,N′-diphenyl-3-oxapentanediamide. Radiochim Acta 81 (1998) 223-226
12. Kolarik Z., Müllich U., and Gassner F. Extraction of Am(III) and Eu(III) nitrates by 2,6-di(5,6-dipropyl-1,2,4-triazin-3-yl)pyridines. Solvent Extr Ion Exc 17 5 (1999) 1155-1170
13. Nash K.L., Gatrone R.C., Clark G.A., Rickert P.G., and Horwitz E.P. Hydrolytic and radiolytic degradation of OΦD(iB)CMPO: continuing studies. Separ Sci Technol 23 (1988) 1355-1372
14. Modolo G., and Seekamp S. Hydrolysis and radiation stability of the ALINA solvent for actinide(III)/lanthanide(III) separation during the partitioning of minor actinides. Solvent Extr Ion Exc 20 (2002) 195-210
15. Baybarz R.D. Dissociation constants of the transplutonium element chelates of diethylenetriaminepentaacetic acid (DTPA) and the application of DTPA chelates to solvent extraction separations of transplutonium elements from the lanthanide elements. J Inorg Nucl Chem 27 (1965) 1831-1839
16. Moeller T., and Thompson L.C. Observations on the rare earths LXXV. The stabilities of diethylenetriaminepentaacetic acid chelates. J Inorg Nucl Chem 24 (1962) 499-510
17. Zhang A., Wei Y., Kumagai M., and Koma Y. A new partitioning process for high level liquid waste by extraction chromatography using silica-substrate chelating agent impregnated adsorbents. J Alloy Compd 390 1-2 (2005) 275-281
18. Zhang A, Wei Y, Kumagai M, Koma Y. A new partitioning process for high level liquid waste by extraction chromatography using impregnated adsorbents. In: 2003 ANS/ENS international winter meeting, global 2003, New Orleans, Louisiana, American, November 16-20 2003.
19. Wei Y, Zhang A, Kumagai M, Watanabe M, Hayashi N. Development of the MAREC process for HLLW partitioning using a novel silica-based CMPO extraction resin. In: The 11th international conference on nuclear engineering, Shinjuku, Tokyo, Japan, April 20-23, 2003. Number 03-209, CD-ROM-ICONE-11-36084.
20. Wei Y., Zhang A., Kumagai M., Watanabe M., and Hayashi N. Development of the MAREC process for HLLW partitioning using a novel silica-based CMPO extraction resin. J Nucl Sci Technol 41 3 (2004) 315-322
21. Zhang A., Wei Y., and Kumagai M. Properties and mechanism of molybdenum and zirconium adsorption by a macroporous silica-based extraction resin in the MAREC process. Solvent Extr Ion Exc 21 4 (2003) 591-611
22. Zhang A., Wei Y., and Kumagai M. Synthesis of a novel silica-based macroporous polymeric adsorption material containing 4,4′,(5′)-di(tert-butylcyclohexano)-18-crown-6 functional group and its adsorption mechanism for strontium. React Funct Polym 61 2 (2004) 191-202
23. Zhang A., Wei Y., Kumagai M., and Koyama T. Kinetic of the adsorption of strontium (II) by a novel silica-based 4,4′,(5′)-di-(tert-butylcyclohexano)-18-crown-6 extraction resin in nitric acid medium. J Radioanal Nucl Ch 262 3 (2004) 739-744
24. Zhang A., Wei Y., Hoshi H., and Kumagai M. Chromatographic separation of strontium(II) from a nitric acid solution containing some typically simulated elements by a novel silica-based impregnated polymeric composite in MAREC process. Solvent Extr Ion Exc 23 2 (2005) 231-247
25. Zhang A., Wei Y., Kumagai M., Koma Y., and Koyama T. Resistant behavior of a novel silica- based octyl(phenyl)-N,N-diisobutylcarbamoylmethylphoshine oxide extraction resin against nitric acid, temperature and γ-irradiation. Radiat Phys Chem 72 4 (2005) 455-463
26. Zhang A., Kuraoka E., Hoshi H., and Kumagai M. Synthesis of two novel macroporous silica-based impregnated polymeric composites and their application in high level activity liquid waste partitioning by extraction chromatography. J Chromatogr A 1061 2 (2004) 175-182
27. Zhang A., Wei Y., Hoshi H., and Kumagai M. Synthesis of a novel silica-based macroporous polymer containing TODGA chelating agent and its application in the chromatographic separation of Mo(VI) and Zr(IV) from diethylenetriaminepentaacetic acid. Separ Sci Technol 40 4 (2005) 811-827
28. Zhang A., Kuraoka E., and Kumagai M. Removal of Pd(II), Zr(IV), Sr(II), Fe(III), and Mo(VI) from simulated high level liquid waste by extraction chromatography utilizing the macroporous silica-based polymeric materials. Sep Purif Technol 50 1 (2006) 35-44
29. Zhang A., Kuraoka E., Kumagai M., Koma Y., and Koyama T. Synthesis and application of a macroporous silica-based octyl(phenyl)-N,N-diiso-butylcarbamoylmethylphoshine oxide polymeric composite in chromatographic partitioning of high level liquid waste. J Radioanal Nucl Ch 269 1 (2006) 118-128
30. Zhang A., Wei Y., Hoshi H., Kumagai M., and Koma Y. Leakage of octyl(phenyl)-N,N-diiso-butylcarbamoylmethylphoshine oxide from a macroporous silica-based chelating polymeric adsorption material and its recovery by some selected porous adsorbents. Adsorpt Sci Technol 23 9 (2005) 721-737