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(a) Kinsho, T.; Shimizu, T.; Ogihara, T.; Kaneko, T.; Nakashima, M. 1995, EP 682,031; Chem. Abstr. 1996, 124, 161201k.
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(b) Kinsho, T.; Shimizu, T.; T. Ogihara, R. S.; Asakura, K.; Nakashima, M. 1995, EP 673,942; Chem. Abstr. 1996, 124, 72665x.
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Ogihara, T.; Shimizu, T.; Kinsho, T.; Kaneko, T.; Saito, R.; Kurihara, H. 1995, EP 650,969; Chem. Abstr. 1995, 123, 270895q.
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(c) Ogihara, T.; Shimizu, T.; Kinsho, T.; Kaneko, T.; Saito, R.; Kurihara, H. 1995, EP 650,969; Chem. Abstr. 1995, 123, 270895q.
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1,1,4,4-Tetrafluoro-1,4-disilacyclohexane was reportedly utilized in the study of fluoride ion donor-acceptor system. (a) Hoshi, T.; Takahashi, M.; Kira, M. Chem. Lett. 1996, 683.
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1,1,4,4-Tetrafluoro-1,4-disilacyclohexane was reportedly utilized in the study of fluoride ion donor-acceptor system. (a) Hoshi, T.; Takahashi, M.; Kira, M. Chem. Lett. 1996, 683.
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1,4-Disilacyclohexanes with no substituent on the ring carbons were often obtained as minor products (∼30%) in the polymerization of diorganovinylsilane via hydrosilylation. (b) Curry, J. W. J. Am. Chem. Soc. 1956, 78, 1686.
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Reviews on the synthesis of polysilacycloalkanes: (a) Barton, T. J. In Comprehensive Organometallic Chemistry. The Synthesis, Reactions and Structures of Organometallic Compounds; Ed.; Wilkinson, G.; Stone, F. G. A.; Abel, E. W., Ed.; Pergamon Press: Oxford, 1982; Vol. 2; pp 205-303;
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(c) Aylett, B. J.; Sullivan, A. C. In Comprehensive Organometallic Chemistry II; Abel, E. W.; Stone, F. G. A.; Wilkinson, G., Ed.; Pergamon Press: Oxford, 1995; Vol. 2; pp 45-75.
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This dianionic methodology was often applied to the synthesis of carbocycles. For example, see Molander, G. A, Shubert, D. C. J. Am. Chem. Soc. 1987, 109, 6877
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This dianionic methodology was often applied to the synthesis of carbocycles. For example, see Molander, G. A.; Shubert, D. C. J. Am. Chem. Soc. 1987, 109, 6877.
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Bis(methylthio)(trimethylsilyl)methyllithium was reported to undergo 1,4-addition to cyclic enones in good yields. Seebach, D.; Bürstinghaus, R. Angew. Chem. Int. Ed. 1975, 14, 57.
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Bis(methylthio)(trimethylsilyl)methyllithium was reported to undergo 1,4-addition to cyclic enones in good yields. Seebach, D.; Bürstinghaus, R. Angew. Chem. Int. Ed. 1975, 14, 57.
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Preliminary reports: (a) Shimizu, M.; Iwakubo, M.; Nishihara, Y.; Hiyama, T. Tetrahedron Lett. 1998, 39, 3193.
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(d) Chuang, T.-H.; Fang, J.-M.; Jiaang, W.-T.; Tsai, Y.-M. J. Org. Chem. 1996, 61, 1794.
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39
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85085631836
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2O to obtain the deutrated 5b in 81% yield (98% d).
-
2O to obtain the deutrated 5b in 81% yield (98% d).
-
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40
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0010688057
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Academic Press: London, Chapter 2, pp
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41
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85069253783
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Crystals of 8a suitable for X-ray structure determination were obtained as colorless prisms by recrystallization from dichloromethane/hexane (1:1, Crystal data for 8a: C24H32Si2S4, M, 504.93, triclinic, space group P1, 2, a, 10.505(2, b, 14.898(2, c, 10.077(2) Å, α, 102.35(1, β, 116.88(1, γ, 69.65(1)°, V, 1315.9(5) Å3, Z, 2, ρCalcd, 1.274 g cm-3, F(000, 536.00, 2θmax, 55.0°, MoKα (λ, 0.71069 Å, μ(MoKα, 4.62 cm-1, T, 296 K; Of the 6363 reflections which were collected, 6032 were unique Rint, 0.012, The structure was solved by heavy-atom Patterson methods and expanded using Fourier techniques. The non-hydrogen atoms were refined anisotropically. Hydrogen atoms were included but not refined. The final cycle of full-matrix least-squares refinement was based on 4272 observed reflec
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-1, T = 296 K; Of the 6363 reflections which were collected, 6032 were unique (Rint = 0.012). The structure was solved by heavy-atom Patterson methods and expanded using Fourier techniques. The non-hydrogen atoms were refined anisotropically. Hydrogen atoms were included but not refined. The final cycle of full-matrix least-squares refinement was based on 4272 observed reflections {I > 3.00s(I)} and 271 variable parameters and converged with unweighted and weighted agreement factors of R = 0.038 and Rw = 0.034. All calculations were performed using the teXsan crystallographic software package of Molecular Structure Corporation. Crystallographic data have been deposited with Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-100558.
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42
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0004204702
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Emsley, J. The Elements; Oxford University Press: Oxford, 2000.
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Emsley, J.1
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β-Donor interaction between silicon and nitrogen atoms in the solid state of dichlorobis(dimethylaminoxy)silane was reported. (a) Mitzel, N. W., Losehand, U. Angew. Chem. Int. Ed. Engl. 1997, 36, 2807.
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β-Donor interaction between silicon and nitrogen atoms in the solid state of dichlorobis(dimethylaminoxy)silane was reported. (a) Mitzel, N. W., Losehand, U. Angew. Chem. Int. Ed. Engl. 1997, 36, 2807.
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See also, c
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See also, (c) Mitzel, N. W. Chem. Eur. J. 1998, 4, 692.
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