-
1
-
-
0003467672
-
-
4th ed, Wiley, New York
-
J. March, Advanced Organic Chemistry, Reactions, Mechanisms and Structure, 4th ed., Wiley, New York, 1992, pp. 386-387.
-
(1992)
Advanced Organic Chemistry, Reactions, Mechanisms and Structure
, pp. 386-387
-
-
March, J.1
-
2
-
-
33846074291
-
-
4th ed, Wiley, New York
-
L. Karas, W. J. Piel, Encyclopedia of Chemical Technology (Kirk-Othmer), Vol. 9, 4th ed., Wiley, New York, 1992, pp. 860-876.
-
(1992)
Encyclopedia of Chemical Technology (Kirk-Othmer)
, vol.9
, pp. 860-876
-
-
Karas, L.1
Piel, W.J.2
-
3
-
-
33846097567
-
-
R. H. Clark, W. E. Graham, A. G. Winter, J. Am. Chem. Soc. 1925, 47, 2748-2754.
-
(1925)
J. Am. Chem. Soc
, vol.47
, pp. 2748-2754
-
-
Clark, R.H.1
Graham, W.E.2
Winter, A.G.3
-
4
-
-
0010523294
-
-
F. Figueras Roca, L. De Mourgues, Y. Trambouze, J. Catal. 1969, 14, 107-113.
-
(1969)
J. Catal
, vol.14
, pp. 107-113
-
-
Figueras Roca, F.1
De Mourgues, L.2
Trambouze, Y.3
-
5
-
-
0004061471
-
-
Ed, S. Patai, Interscience, London
-
H. Feuer, J. Hooz, The Chemistry of the Ether Linkage (Ed.: S. Patai), Interscience, London, 1967, pp. 457-460.
-
(1967)
The Chemistry of the Ether Linkage
, pp. 457-460
-
-
Feuer, H.1
Hooz, J.2
-
6
-
-
0003467672
-
-
4th ed, Wiley, New York
-
J. March, Advanced Organic Chemistry, Reactions, Mechanisms and Structure, 4th ed., Wiley, New York, 1992, pp. 389-390.
-
(1992)
Advanced Organic Chemistry, Reactions, Mechanisms and Structure
, pp. 389-390
-
-
March, J.1
-
7
-
-
0036566274
-
-
S. Assabumrungrat, W. Kiatkittipong, N. Sevitoon, P. Praserthdam, S. Goto, Int. J. Chem. Kinet. 2002, 34, 292-299.
-
(2002)
Int. J. Chem. Kinet
, vol.34
, pp. 292-299
-
-
Assabumrungrat, S.1
Kiatkittipong, W.2
Sevitoon, N.3
Praserthdam, P.4
Goto, S.5
-
12
-
-
0037131486
-
-
M. Renz, T. Blasco, A. Corma, V. Fornés, R. Jensen, L. Nemeth, Chem. Eur. J. 2002, 8, 4708-4717.
-
(2002)
Chem. Eur. J
, vol.8
, pp. 4708-4717
-
-
Renz, M.1
Blasco, T.2
Corma, A.3
Fornés, V.4
Jensen, R.5
Nemeth, L.6
-
13
-
-
25144492700
-
-
S. R. Bare, S. D. Kelly, W. Sinkler, J. J. Low, F. S. Modica, S. Valencia, A. Corma, L. T. Nemeth, J. Am. Chem. Soc. 2005, 127, 12 924-12 932.
-
(2005)
J. Am. Chem. Soc
, vol.127
-
-
Bare, S.R.1
Kelly, S.D.2
Sinkler, W.3
Low, J.J.4
Modica, F.S.5
Valencia, S.6
Corma, A.7
Nemeth, L.T.8
-
15
-
-
33748995120
-
-
M. Boronat, A. Corma, M. Renz, P. M. Viruela, Chem. Eur. J. 2006, 12, 7067-7077.
-
(2006)
Chem. Eur. J
, vol.12
, pp. 7067-7077
-
-
Boronat, M.1
Corma, A.2
Renz, M.3
Viruela, P.M.4
-
16
-
-
0031648789
-
-
T. Blasco, M. A. Camblor, A. Corma, P. Esteve, J. M. Guil, A. Martínez, J. A. Perdigón-Melón, S. Valencia, J. Phys. Chem. B 1998, 102, 75-88.
-
(1998)
J. Phys. Chem. B
, vol.102
, pp. 75-88
-
-
Blasco, T.1
Camblor, M.A.2
Corma, A.3
Esteve, P.4
Guil, J.M.5
Martínez, A.6
Perdigón-Melón, J.A.7
Valencia, S.8
-
17
-
-
0034667419
-
-
D. Gleeson, G. Sankar, C. R. A. Catlow, J. M. Thomas, G. Spano, S. Bordiga, A. Zecchina, C. Lamberti, Phys. Chem. Chem. Phys. 2000, 2, 4812-4817.
-
(2000)
Phys. Chem. Chem. Phys
, vol.2
, pp. 4812-4817
-
-
Gleeson, D.1
Sankar, G.2
Catlow, C.R.A.3
Thomas, J.M.4
Spano, G.5
Bordiga, S.6
Zecchina, A.7
Lamberti, C.8
-
18
-
-
4344629645
-
-
Y. Zhu, G. Chuah, S. Jaenicke, J. Catal. 2004, 227, 1-10.
-
(2004)
J. Catal
, vol.227
, pp. 1-10
-
-
Zhu, Y.1
Chuah, G.2
Jaenicke, S.3
-
20
-
-
33846116513
-
-
In general, when Brønsted acid catalysis is employed for the ether synthesis from two alcohols, water has to be removed to achieve complete conversion, because also the back reaction, that is, the conversion of an ether into two alcohols in the presence of water, is catalyzed by Brønsted acids. In the case of the solid Lewis acids, this back reaction is not facilitated by the catalyst. The ether may coordinate to the Lewis acid center, however, it will not be activated for the ether hydrolysis as the alcoholate is not converted into a better leaving group
-
In general, when Brønsted acid catalysis is employed for the ether synthesis from two alcohols, water has to be removed to achieve complete conversion, because also the back reaction, that is, the conversion of an ether into two alcohols in the presence of water, is catalyzed by Brønsted acids. In the case of the solid Lewis acids, this back reaction is not facilitated by the catalyst. The ether may coordinate to the Lewis acid center, however, it will not be activated for the ether hydrolysis as the alcoholate is not converted into a better leaving group.
-
-
-
-
21
-
-
0035824022
-
-
A. Corma, M. T. Navarro, L. Nemeth, M. Renz, Chem. Commun. 2001, 2190-2191.
-
(2001)
Chem. Commun
, pp. 2190-2191
-
-
Corma, A.1
Navarro, M.T.2
Nemeth, L.3
Renz, M.4
-
22
-
-
23144453660
-
-
A. Corma, S. Iborra, M. Mifsud, M. Renz, J. Catal. 2005, 234, 96-100.
-
(2005)
J. Catal
, vol.234
, pp. 96-100
-
-
Corma, A.1
Iborra, S.2
Mifsud, M.3
Renz, M.4
-
23
-
-
0037970177
-
-
A. Corma, M. E. Domine, S. Valencia, J. Catal. 2003, 215, 294-304.
-
(2003)
J. Catal
, vol.215
, pp. 294-304
-
-
Corma, A.1
Domine, M.E.2
Valencia, S.3
-
25
-
-
33846063678
-
-
US Patent 4657700
-
P. A. Ochsner (Givaudan Corp.), US Patent 4657700, 1987.
-
(1987)
-
-
Ochsner, P.A.1
-
26
-
-
33846060612
-
-
Personal communication from Takasago Paris
-
Personal communication from Takasago Paris.
-
-
-
-
27
-
-
0003398242
-
-
Wiley-VCH, Weinheim
-
K. Bauer, D. Garbe, H. Suburg, Common Fragrance and Flavor Materials, Wiley-VCH, Weinheim, 1997, p. 128.
-
(1997)
Common Fragrance and Flavor Materials
, pp. 128
-
-
Bauer, K.1
Garbe, D.2
Suburg, H.3
|