Uniform catalytic site in Sn-β-zeolite determined using X-ray absorption fine structure

Journal of the American Chemical Society

Volumn 127, Issue 37, 2005, Pages 12924-12932

  Bare, Simon R ^a   Kelly, Shelly D ^b   Sinkler, Wharton ^a   Low, John J ^a   Modica, Frank S ^a   Valencia, Susana ^c   Corma, Avelino ^c   Nemeth, Laszlo T ^a  

^a UOP LLC   (United States)

^b EXAFS Analysis   (United States)

^c CSIC   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYST ACTIVITY; CRYSTALLOGRAPHY; OXIDATION; X RAY ANALYSIS; ZEOLITES;

BAEYER-VILLIGER OXIDATIONS; EXTENDED X-RAY ABSORPTION FINE STRUCTURE (EXAFS) DATA; ZEOLITE SYNTHESIS;

TIN;

TIN; ZEOLITE;

ARTICLE; BAEYER VILLIGER REACTION; CATALYST; CHEMICAL STRUCTURE; CRYSTALLOGRAPHY; RADIATION ABSORPTION; STRUCTURE ANALYSIS; SYNTHESIS; X RAY ANALYSIS;

ABSORPTION; CATALYSIS; MODELS, MOLECULAR; TIN; X-RAY DIFFRACTION; ZEOLITES;

EID: 25144492700     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja052543k     Document Type: Article

References (49)

1. Krow, G. R. Org. React. 1993, 43, 251.
2. Corma, A.; Nemeth, L. T.; Renz, M.; Valencia, S. Nature 2001, 412, 423-425.
3. Renz, M.; Blasco, T.; Corma, A.; Fornes, V.; Jensen, R.; Nemeth, L. Chem. Eur. J. 2002, 8, 4708-4716.
4. Corma, A.; Nemeth, L. T.; Moscoso, J. G. U.S. Patent 6,344,583, 2002.
5. Nemeth, L. T.; Corma, A.; Valencia, S.; Moscoso, S. U.S. Patent 6,191,323, 2001.
6. Kamata, K.; Yonehara, K.; Sumida, Y.; Yamaguchi, K.; Hikichi, S.; Mizuno, N. Science 2003, 300, 964-966.
7. Gagnon, R.; Grogan, G.; Levit, M. S.; Roberts, S. M.; Wan, P. W. H.; Wiletts, A. J. J. Chem. Soc., Perkin Trans 1. 1994, 18, 2537-2543.
8. Taramasso, M.; Perego, G.; Norati, B. U.S. Patent 4,410,501, 1993.
9. Kharitonov, A. S.; Fenelonov, V. B.; Voskresenskaya, T. P.; Rudina, N. A.; Molchanov, V. V.; Plyasova, G. I. Zeolites 1995, 15, 253.
10. Sobolev, V. I.; Panov, G. I.; Kharitonov, A. S.; Rommanikov, V. N.; Volodin, A. M.; Ione, K. G. J. Catal. 1993, 139, 435.
11. Yogo, K.; Tanaka, S.; Ono, T.; Mikami, T.; Kikuchi, E. Microporous Mater. 1994, 3, 39.
12. Inui, T.; matsuda, H.; Yamase, O.; Nagata, H.; Fukuda, K.; Ukawa, T.; Miyamoto, A. J. Catal. 1986, 98, 491.
13. Handreck, G. P.; Smith, T. D. J. Chem. Soc., Faraday Trans. 1 1989, 85, 3195.
14. Lamberti, C.; Bordiga, S.; Zecchina, A.; Carati, A.; Fitch, A. N.; Artoli, G.; Petrini, G.; Salvalaggio, M.; Marra, G. L. J. Catal. 1999, 183, 222-231.
15. Jentys, A.; Catlow, C. R. A. Catal. Lett. 1993, 22, 251.
16. Sastre, G.; Corma, A. Chem. Phys. Lett. 1999, 302, 447.
17. Millini, R.; Perego, G.; Seiti, K. In Zeolites and Related Microporous Materials: State of the Art 1994, Studies in Surface Science and Catalysis', Elsevier: Amsterdam and New York, 1994; Vol. 84, p 2123.
18. Oumi, Y.; Matsuba, K.; Kubo, M.; INRI, T.; Miyamoto, A. Microporous Mater. 1995, 4, 53-57.
19. Njo, S. L.; van Koningsveld, H.; van de Graaf, B. J. Phys. Chem. B 1997, 101, 10065-10068.
20. Ricchiardi, G.; de Man, A.; Sauer, J. Phys. Chem. Chem. Phys. 2000, 2, 2195-2204.
21. Marra, G. L.; Artolit, G.; Fitch, A. N.; Milanesio, M.: Lamberti, C. Microporous Mesoporous Mater. 2000, 40, 85-94.
22. Hijar, C. A.; Jacubinas, R. M.; Eckert, J.; Henson, N. J.; Hay, P. J.; Ott, K. C. J. Phys. Chem. B 2000, 104, 12157-12164.
23. Henry, P. F.; Weller, M. T.; Wilson, C. C. J. Phys. Chem. B 2001, 105, 7452-7458.
24. Lamberti, C.; Bordiga.; Zecchina, A.; Artoli, G.; Marra, G.; Spano. G. J. Am. Chem. Soc. 2001, 123, 2204-2212.
25. Artoli, G.; Lamberti, C.; Marra, G. Acta Crystallogr. Sec. B 2000, B56, 2-10.
26. Milanesio, M.; Lamberti, C.; Aiello, R.; Testa, F.; Piana, M.; Viterbo, D. J. Phys. Chem. B 2000, 104, 9951-9953.
27. Palin, L.; Lamberti, C.; Kvick, A.; Testa, F.; Aiello, R.; Milanesio, M.; Viterbo, D. J. Phys. Chem. B 2003, 107, 4034-4042.
28. Lewis, D. W.; Catlow, C. R. A.; Sankar, G.; Carr, S. W. J. Phys. Chem. 1995, 99, 2377-2383.
29. Matsubayashi, N.; Shimada, H.; Imamura, M.; Sato, T.; Okabe, K.; Yoshimura, Y.; Nishijima, A. Catal. Today 1996, 29, 273-277.
30. Newsham, J. M.; Treacy, M. M. J.; Koetsier, W. T.; DeGruyter, C. B. Proc. R. Soc. London A 1988, 420, 375-405. Both the A and B polymorphs of β-zeolite are constructed of the same centrosymmetric building units that are arranged in layers that interconnect in either a left- (L) or right- handed (R) fashion. Polymorph A is RRRR or LLLL layers, while polymorph B has alternating RLRL stacking.
31. Wright, P. A.; Zhou, W.; Perez-Pariente, J.; Arranz, M. J. Am. Chem. Soc. 2005, 127, 494.
32. Bare, S. R.; Mickelson, G. E.; Modica, F. S.; Yang, N.; Ringwelski, A. Z. Rev. Sci. Instrum., to be submitted.
33. Newville, M.; Ravel., B. J. Synchrotron Radiat. 2005, 12, 537-541.
34. Rehr, J. J.; Mustre de Leon, J.; Zabinsky, S. I.; Albers, R. C. J. Am. Client. Soc. 1991, 113, 5135.
35. Treacy, M. M. J.; Newsam, J. M.; Deam, M. W. Proc. R. Soc. London A 1991, 433, 499.
36. The EXAFS spectrum is a sum of signals, each with a distinct frequency that is related to the distance between the Sn atoms and the neighboring atoms surrounding the Sn atoms in the sample. A Fourier transform (FT) of the EXAFS spectra separates the signals from each frequency, giving a peak with an amplitude related to the type and number of neighboring atoms and position related to the distance between the Sn atoms and the neighboring atoms. All the atoms with the same bond length, in a shell about the Sn atoms, are represented by a single peak in the FT of the data.
37. Brunner, G. O.; Laves, F. Wiss, Z. Techn. Univsers. Dresden 1971, 20, 387.
38. Meier, W. M.; Moeck, H. J. J. Sol. State Chem. 1979, 27, 349-355.
39. These distances have been rounded to the nearest hundredth angstrom and then grouped to the nearest tenth of an angstrom; therefore, an accuracy of ±0.05 Å is understood, and well within the resolution of our measurements.
40. 2 structure in the Sn-β sample.
41. 2 value are √(2/ν) + 1 = 1.8, where √(2/ν) is one standard deviation and ν = 18 is the degrees of freedom in the fit.
42. These distances are the same in both polymorphs of β-zeolite.
43. (4l) Corma, A. Personal communication and to be published.
44. Vanderbilt, D. Phys. Rev. B 1990, 41, 7892-7895.
45. (a) Kresse, G.; Hafner, J. Phys. Rev. B 1993, 47, 558-561.
46. (b) Kresse, G.; Hafner, J. Phys. Rev. B 1994, 49, 14251-14269.
47. (c) Kresse, G.; Furthmuller, J. Phys. Rev. B 1996, 54, 11169-11186.
48. Ceperly, D. M.; Alder, B. J. Phys. Rev. Lett. 1980, 45, 566-569.
49. Perdew, J.; Zunger, A. Phys. Rev. B 1981, 23, 5048-5079.