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Volumn 55, Issue 1, 2007, Pages 156-158

Photo-oxidation of aldehydes with molecular oxygen in the presence of catalytic bromine or hydrobromic acid

Author keywords

Aldehyde; Bromine; Hydrobromic acid; Molecular oxygen; Photo oxidation

Indexed keywords

ALDEHYDE DERIVATIVE; BROMINE; CARBOXYLIC ACID; HYDROBROMIC ACID; OXYGEN;

EID: 33846104413     PISSN: 00092363     EISSN: 13475223     Source Type: Journal    
DOI: 10.1248/cpb.55.156     Document Type: Article
Times cited : (13)

References (28)
  • 23
    • 33846116271 scopus 로고    scopus 로고
    • We exclusively used anhydrous solvents for this study since the solvents are purer than other grades of general solvents
    • We exclusively used anhydrous solvents for this study since the solvents are purer than other grades of general solvents.
  • 24
    • 33846072644 scopus 로고    scopus 로고
    • The corresponding carboxylic acids were obtained in moderate yields when using 0.07 eq of bromine
    • The corresponding carboxylic acids were obtained in moderate yields when using 0.07 eq of bromine.
  • 25
    • 33846081170 scopus 로고    scopus 로고
    • Since the boiling point of 15 is not so high, remained 15 in the crude product was thought to be evaporated under reduced pressure with a vacuum pump.
    • Since the boiling point of 15 is not so high, remained 15 in the crude product was thought to be evaporated under reduced pressure with a vacuum pump.
  • 26
    • 33846108872 scopus 로고    scopus 로고
    • The equivalent indicates the amount of hydrogen bromide in the hydrobromic acid
    • The equivalent indicates the amount of hydrogen bromide in the hydrobromic acid.
  • 27
    • 33846093154 scopus 로고    scopus 로고
    • Since the reaction mixture was tarry and the product 12 was obtained only in 33% yield when using 11 and 0.2 eq of hydrobromic acid, 0.1 eq of hydrobromic acid was exclusively used for aliphatic aldehydes.
    • Since the reaction mixture was tarry and the product 12 was obtained only in 33% yield when using 11 and 0.2 eq of hydrobromic acid, 0.1 eq of hydrobromic acid was exclusively used for aliphatic aldehydes.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.