Oxidation of the Methyl Group at the Aromatic Nucleus with Molecular Oxygen in the Presence of N-Bromosuccinimide under Photoirradiation

Synthesis

Volumn , Issue 15, 2003, Pages 2289-2291

  Itoh, Akichika ^a   Kodama, Tomohiro ^a   Hashimoto, Shouei ^a   Masaki, Yukio ^a  

^a GIFU PHARMACEUTICAL UNIVERSITY   (Japan)

Author keywords

Methyl group; Molecular oxygen; N bromosuccinimide; Oxidations; Photoirradiation

Indexed keywords

CARBOXYLIC ACIDS; CATALYSIS; FREE RADICALS; IRRADIATION; OXIDATION;

AEROBIC OXIDATION; AROMATIC NUCLEUS;

AROMATIC COMPOUNDS;

N BROMOSUCCINIMIDE; OXYGEN;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; IRRADIATION; OXIDATION; PHOTOIRRADIATION;

EID: 0242571996     PISSN: 00397881     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2003-41077     Document Type: Article

References (11)

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10. The corresponding aldehydes (6-7%) and inseparable products were formed, respectively.
11. 4-tert-Butylbenzaldehyde was oxidized to 2 in 93% yield under the same reaction conditions.