Direct α-hydroxylation of ketones catalyzed by organic-inorganic hybrid polymer

Chemistry Letters

Volumn 35, Issue 10, 2006, Pages 1094-1095

  Arai, Takayoshi ^a   Sato, Toru ^a   Noguchi, Hiroshi ^a   Kanoh, Hirofumi ^a   Kaneko, Katsumi ^a   Yanagisawa, Akira ^a  

^a CHIBA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 33846103973     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.2006.1094     Document Type: Article

References (22)

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20. 1 α-hydroxylation of 1 does not proceed without use of Cu-bpy catalyst.
21. n).
22. The catalysis using Cu-bpy for the kinetic trimethylsilyl enolate of 2-benzylcyclohexanone provided 2-benzyl-6-hydroxycyclohexan-1-one in ca. 3% yield under the reaction conditions similar to those reported in Ref. 3, while 2-benzyl-2-hydroxycyclohexan-1-one was not obtained at all.