Assembled enantioselective catalysts for carbonyl-ene reactions

Tetrahedron Letters

Volumn 45, Issue 9, 2004, Pages 2009-2012

  Guo, Hongchao ^a   Wang, Xingwang ^a   Ding, Kuiling ^a  

^a SHANGHAI INSTITUTE OF ORGANIC CHEMISTRY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

CARBONYL DERIVATIVE; ESTER DERIVATIVE; LIGAND; POLYMER; TITANIUM DERIVATIVE;

ARTICLE; CATALYST; CHIRALITY; ENANTIOSELECTIVITY; METHODOLOGY; REACTION ANALYSIS; SUPRAMOLECULAR CHEMISTRY;

EID: 1242293796     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2003.12.143     Document Type: Article

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41. R =23.37 min (major), 30. 76 min (minor), respectively).
42. After the accomplishment of preparation of this manuscript, we noticed that a paper by Sasai and co-workers appeared at the upcoming Hot Paper, homepage of Angew. Chem. Int. Ed., where a similar strategy was employed for the synthesis of chiral Al-bridged and Ti-bridged polymers by a metal-mediated self-assembly of (R,R)-6,6′-bi(BINOL). These catalysts were found to promote asymmetric Michael addition and carbonyl-ene reaction with high enantioselectivity: Takizawa S., Somei H., Jayaprakash D., Sasai H. Angew. Chem., Int. Ed. 42:2003;5711-5714.